• Title/Summary/Keyword: AnCE

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Preparation of Ce0.8Gd0.2O1.9 Powder by Milling of CeO2 Slurry and Oxalate Precipitation (CeO2 슬러리 분쇄와 옥살산 침전을 이용한 Ce0.8Gd0.2O1.9 분말의 합성)

  • Sim, Soo-Man
    • Journal of the Korean Ceramic Society
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    • v.47 no.2
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    • pp.183-188
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    • 2010
  • $Ce_{0.8}Gd_{0.2}O_{1.9}$(GDC20) powder was synthesized by milling of $CeO_2$ slurry and Gd oxalate precipitation. The mixture of $CeO_2$ powder and Gd precipitates calcined at $600^{\circ}C$ for 2 h showed the particle size distribution similar to that of $CeO_2$ powder, which had been milled during the synthesis process. Attrition milling of the calcined powder with an average particle size of $0.36\;{\mu}m$ for 2 h resulted in a decrease in the particle size to $0.24\;{\mu}m$. Although the milled powder consisted of small particles(<$1\;{\mu}m$), a small amount of fine platy $Gd_2O_3$ particles, which had been survived in the milling process, was observed. Sintering of the powder compacts for 4 h showed relative densities of 80.7% at $1300^{\circ}C$ and 97% at $1400^{\circ}C$, respectively. Densification was found to almost complete at $1500^{\circ}C$, resulting in a dense and homogeneous microstructure with a relative density of 99.5%.

Improvement of dielectric and interface properties of Al/CeO$_2$/Si capacitor by using the metal seed layer and $N_2$ plasma treatment (금속씨앗층과 $N_2$ 플라즈마 처리를 통한 Al/CeO$_2$/Si 커패시터의 유전 및 계면특성 개선)

  • 임동건;곽동주;이준신
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.326-329
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    • 2002
  • In this paper, we investigated a feasibility of cerium oxide(CeO$_2$) films as a buffer layer of MFIS(metal ferroelectric insulator semiconductor) type capacitor. CeO$_2$ layer were Prepared by two step process of a low temperature film growth and subsequent RTA (rapid thermal annealing) treatment. By app1ying an ultra thin Ce metal seed layer and N$_2$ Plasma treatment, dielectric and interface properties were improved. It means that unwanted SiO$_2$ layer generation was successfully suppressed at the interface between He buffer layer and Si substrate. The lowest lattice mismatch of CeO$_2$ film was as low as 1.76% and average surface roughness was less than 0.7 m. The Al/CeO$_2$/Si structure shows breakdown electric field of 1.2 MV/cm, dielectric constant of more than 15.1 and interface state densities as low as 1.84${\times}$10$\^$11/ cm$\^$-1/eV$\^$-1/. After N$_2$ plasma treatment, the leakage current was reduced with about 2-order.

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The Effect of Ce Addition on Corrosion Behavior of Permanent Mold Casting Mg-4Al-2Sn-1Ca alloy (금형 주조한 Mg-4Al-2Sn-1Ca 합금의 부식 거동에 미치는 Ce 첨가의 영향)

  • Park, Kyung Chul;Kim, Byeong Ho;Jung, Jae Woong;Cho, Dae Hyun;Park, Ik Min
    • Journal of Korea Foundry Society
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    • v.34 no.6
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    • pp.187-193
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    • 2014
  • In the present work, the effect of adding Ce on the corrosion behavior of Mg-4Al-2Sn-1Ca alloy was investigated. The studied alloys were fabricated by gravity casting method and a potentiodynamic polarization, A.C. impedance and hydrogen evolution tests were carried out in a 3.5% NaCl solution with pH 7.2 at room temperature to measure the corrosion properties of Mg-4Al-2Sn-1Ca-xCe alloys. The microstructure of the Mg-4Al-2Sn-1Ca alloy was composed of ${\alpha}$-Mg, Mg17Al12, Mg2Sn and CaMgSn phase. Also, a $Al_{11}Ce_3$ phase was newly formed by the addition of Ce. With an increase of the Ce contents, the microstructure became refined and the corrosion resistance improved.

Ecotoxicological Effects of $CeO_2$ Nanoparticles on Soil Nematode Caenorhabditis elegans (토양선충 Caenorhabditis elegans를 이용한 세리아($CeO_2$) 독성연구)

  • Roh, Ji-Yeon;Park, Young-Kwon;Choi, Jin-Hee
    • Environmental Analysis Health and Toxicology
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    • v.23 no.2
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    • pp.87-91
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    • 2008
  • In this study, three different sizes of cerium oxide ($CeO_2$) nanoparticles were synthesized and exposed to Caenorhabditis elegans to investigate the potential harmful effect of $CeO_2$ nanoparticles on the environment. The effects of the $CeO_2$ nanoparticles on C. elegans were assessed at multiple levels, such as with respect to stress response gene expression, growth, reproduction and mortality. Moreover, to test the ecotoxicological relevance of $CeO_2$-induced gene expression. The overall results suggest that $CeO_2$ nanoparticles may provoke ecotoxicity in C. elegans especially with respect to gene expression, reproduction and survival, which can comprise an important contribution to knowledge on the ecotoxicity of $CeO_2$ nanoparticles, about which little data are available. This is particularly valuable in the biomarker research on ecotoxicology, as ecological relevance is a crucial criterion for the applicability of the biomarker in field biomonitoring and ecological risk assessment.

The Characteristics of YAG:Ce Phosphor Powder Prepared Using a NO3--Malonic Acid-NH4NO3-NH3·H2O System

  • Jeong, Jin-An;Park, Kyung-Hwan;Lee, Dong-Hoon;Kim, Hong-Gun;Kim, Yoo-Young
    • Bulletin of the Korean Chemical Society
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    • v.33 no.4
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    • pp.1141-1146
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    • 2012
  • Ce-doped $Y_3Al_5O_{12}$ (YAG:Ce) phosphor powder was prepared using a ${NO_3}^-$-malonic acid-$NH_4NO_3-NH_3{\cdot}H_2O$ system. The YAG:Ce precursor was ignited at $240^{\circ}C$ and the resulting powder contained YAG:Ce crystallites (42%) - active in the visible region at 460 nm - amorphous particles (53%) - inactive at visible wavelengths - and less than 3% oxide (3%) crystallite impurities. The impurities transformed to acitive YAG:Ce crystallites at above $800^{\circ}C$. At above $1000^{\circ}C$, the amorphous phase became YAG phase and isolated $Ce_2O$ crystallites emerged. The powder particles comprised < $4{\mu}m$ secondary aggregates of 20 nm primary particles. The thermal dusting of the secondary particles coincided with the aggregation of the secondary particles at above $900^{\circ}C$.

Formation of Cerium Conversion Coatings on AZ31 Magnesium Alloy

  • Fazal, Basit Raza;Moon, Sungmo
    • Journal of the Korean institute of surface engineering
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    • v.49 no.1
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    • pp.1-13
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    • 2016
  • This review deals with one of the surface modification techniques, chemical conversion coating and particularly cerium-based conversion coatings (CeCC) as a promising substitute for chromium and phosphate conversion coating on magnesium and its alloys. The CeCCs are commonly considered environmentally friendly. The effects of surface preparation, coating thickness, bath composition, and e-paint on the corrosion behavior of CeCCs have been studied on the AZ31 magnesium alloy. This review also correlates the coating microstructural, morphological, and chemical characteristics with the processing parameters and corrosion protection. Results showed that the as-deposited coating system consists of a three layer structure (1) a nanocrystalline MgO transition layer in contact with the Mg substrate, (2) a nanocrystalline CeCC layer, and (3) an outer amorphous CeCC layer. The nanocrystalline CeCC layer thickness is a function of immersion time and cerium salt used. The overall corrosion protection was crucially dependent on the presence of coating defects. The corrosion resistance of AZ31 magnesium alloy was better for thinner CeCCs, which can be explained by the presence of fewer and smaller cracks. On the other hand, maximum corrosion protection was achieved when AZ31 magnesium samples with thin CeCCs are e-painted. The e-paint layer further restricts and hinders the movement of chloride and other aggressive ions present in the environment from reaching the magnesium surface.

The Cathodoluminance Properties of $Y_2SiO_5$:Ce Blue Phosphor with Surface Coatings ($Y_2SiO_5$:Ce 청색 형광체의 표면 코팅에 따른 음극선 발광특성)

  • 음현중;김성우;이임렬
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.590-593
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    • 1999
  • $Y_2SiO_5$:Ce was considered as blue phosphor for field emission display because it had an excellent resistance against brightness saturation. But unfortunately It hadn't a sufficient brightness to be applied to FED. In this experiment It-$In_2O_3$, MgO and $SiO_2$ were coated onto $Y_2SiO_5$:Ce phosphor in order to improve the cathodoluminance(CL properties. The coating structures were identified to be the crystalline phases of $In_2O_3$ and MgO respectively. They had fine particle-like shape and were distributed on the surface of $Y_2SiO_5$:Ce phosphor. It was found that the CL efficiency of $Y_2SiO_5$:Ce phosphors were decreased after coatings with In20:j and MgO in voltage range from 500 V to 5 kV. But the brightness of $Y_2SiO_5$:Ce phosphor was increased after coating of 5 0 2 . And also the aging test showed that $In_2O_3$ coating improved the life time of $Y_2SiO_5$:Ce phosphor.

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Growth optimization of CeCoIn5 thin films via pulsed laser deposition

  • Rivasto, Elmeri;Kim, Jihyun;Tien, Le Minh;Kang, Ji-Hoon;Park, Sungmin;Choi, Woo Seok;Kang, Won Nam;Park, Tuson
    • Progress in Superconductivity and Cryogenics
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    • v.23 no.3
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    • pp.41-44
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    • 2021
  • We developed an optimization process of the pulsed laser deposition method to grow epitaxial CeCoIn5 thin films on MgF2 substrates. The effects of different deposition parameters on film growth were extensively studied by analyzing the measured X-ray diffraction patterns. All the deposited films contained small amounts of CeIn3 impurity phase and misoriented CeCoIn5, for which the c-axis of the unit cell is perpendicular to the normal vector of the substrate surface. The deposition temperature, target composition, laser energy density, and repetition rate were found effective in the formation of (00l)-oriented CeCoIn5 as well as the undesired phases such as CeIn3, misoriented CeCoIn5 along the (112) and (h00). Our results provide a set of deposition parameters that produce high-quality epitaxial CeCoIn5 thin films with sufficiently low amounts of impurity phases and can serve as a reference for future studies to optimize the deposition process further.

CO Oxidation Over Pt Supported on Al-Ce Mixed Oxide Catalysts with Different Mole Ratios of Al/(Al+Ce) (서로 다른 몰비의 Al/(Al+Ce)를 가진 Al-Ce 혼합산화물에 담지된 Pt 촉매 상에서의 일산화탄소 산화반응)

  • Park, Jung-Hyun;Cho, Kyung-Ho;Kim, Yun-Jung;Shin, Chae-Ho
    • Clean Technology
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    • v.17 no.2
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    • pp.166-174
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    • 2011
  • The xAl-yCe oxide catalysts with different mol ratios of Al/(Al+Ce) were prepared by a co-precipitation method and Pt supported on xAl-yCe oxide catalysts were synthesized by an incipient wetness impregnation method. The catalysts were characterized by X-ray Diffraction (XRD), $N_2$ sorption, and $H_2$/CO-temperature programmed reduction ($H_2$/CO-TPR) to correlate with catalytic activities in co oxidation. Among the catalysts studied here, Pt/1Al-9Ce oxide catalyst showed the highest activity in dry and wet reaction conditions and the catalytic activity showed a typical volcano-shape curve with respect to Al/(Al+Ce) mol ratio. When the presence of 5% water vapor in the feed, the temperature of $T_{50%}$ was shifted ca. $30^{\circ}C$ to lower temperature region than that in dry condition. From CO-TPR, the desorption peak of $CO_2$ on Pt/1Al-9Ce oxide catalyst showed the highest value and well correlated the catalytic performance. It indicates that the Pt/1Al-9Ce oxide catalyst has a large amount of active sites which can be adsorbed by co and easy to supplies the needed oxygen. In addition, the amount of pentacoordinated $Al^{3+}$ sites obtained through $^{27}Al$ NMR analysis is well correlated the catalytic performance.

Porting Window CE Operating System to Arm based board device

  • An, Byung-Chan;Ham, Woon-Chul
    • 제어로봇시스템학회:학술대회논문집
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    • 2003.10a
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    • pp.2159-2163
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    • 2003
  • Hand carried computing machinery and tools have been developed into an embedded system which the small footprint operating system is contained internally. Windows CE which is one of imbedded operating system is a lightweight, multithreaded operating system with an optional graphical user interface. Its strength lies in its small size, its Win32 subset API, and its multiplatform support. Therefore we choose to port this OS on Arm based board that is provided high performance, low cost, and low power consumption. In this paper, we describe the architecture of ARM based board, the feature of Windows CE, techniques and steps involved in this porting process.

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