• Title/Summary/Keyword: Amorphous

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Structure evolution of Pt doped amorphous $V_{2}O_{5}$ cathode film for thin film battery (Pt이 도핑된 박막 전지용 비정질 산화바나듐 박막의 구조적 변화)

  • 김한기;전은정;옥영우;성태연;조원일;윤영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.889-892
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    • 2000
  • We have investigated the Pt doping effect on structural and electrochemical properties of amorphous vanadium oxide film, grown by radio frequency magnetron sputtering. Room temperature charge-discharge measurements based on a half-cell with a constant current clearly indicated that the Pt doping could improve the cyclibility of V$_2$O$_{5}$ cathode film. Using glancing angle x-ray diffraction (GXRD) and high resolution transmission electron microscopy (HRTEM) analysis, we found that the Pt doping with l0W r.f. power induce more random amorphous structure than undoped V$_2$O$_{5}$ film. As the r.f. power of Pt increases, large amount of Pt incorporates into amorphous V$_2$O$_{5}$ and makes PtOx microcrystalline phase in amorphous matrix. This result suggests that the semicondcuting PtOx microcrystalline phase in amorphous matrix lead to a drastically faded cyclibility of 50W Pt doped V$_2$O$_{5}$ cathode film. Possible explanations are given to describe the Pt doping effect on cyclibility of vanadium oxide cathode film.de film.

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Microstructure and Mechanical Properties of Tantalum-Continuous-Fiber-Reinforced Amorphous Matrix Composites Fabricated by Liquid Pressing Process (액상가압공정으로 제조된 탄탈륨 연속섬유 강화 비정질 복합재료의 미세조직과 기계적 성질)

  • Lee, Kyuhong;Lee, Sang-Bok;Lee, Sang-Kwan;Lee, Sunghak
    • Korean Journal of Metals and Materials
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    • v.46 no.7
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    • pp.403-411
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    • 2008
  • Zr-based amorphous alloy matrix composites reinforced with tantalum continuous fibers were fabricated by liquid pressing process, and their microstructures and mechanical properties were investigated. About 60 vol.% of tantalum fibers were homogeneously distributed inside the amorphous matrix, which contained a small amount of polygonal crystalline particles. The ductility of the tantalum-continuous-fiber-reinforced composite under tensile or compressive loading was dramatically improved over that of the monolithic amorphous alloy, while maintaining high strength. The consequential observation of the tensile deformation and fracture behavior of the composite showed the formation of multiple shear bands and multiple necking, crack deflection in the amorphous matrix, and obstruction of crack propagation by ductile fibers, thereby resulting in very high tensile elongation of 7.2%. These findings suggested that the liquid pressing process was useful for the development of amorphous matrix composites with improved ductility.

Enhanced Crystallization of Amorphous Silicon using Electric Field

  • Song, Kyung-Sub;Jun, Seung-Ik;Park, Sang-Hyun;Park, Duck-Kyun
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1997.06a
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    • pp.243-246
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    • 1997
  • A new technique for low temperature crystallization of amorphous silicon, called field aided lateral crystallization(FALC) was attempted. To demonstrate the concept of FALC, thin layer of nickel(30${\AA}$) was deposited on top of amorphous silicon film and the electric field was applied during the crystallization. The effects of electric field on the crystallization behavior of amorphous silicon film were investigated.

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Thickness-dependent morphology of ZnO films and amorphous ZnO Transparent TFT

  • Hsieh, Hsing-Hung;Wu, Chung-Chih
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1677-1679
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    • 2007
  • Thickness dependent morphology of ZnO films was studied, and ZnO can be intentionally grown into amorphous phase by reducing the thickness. The top-gate amorphous ZnO TTFTs with rather high field-effect mobilities and on/off current ratios were effectively fabricated.

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Absorption Characteristics of Amorphous Metal during Processing with Nd:YAG laser (Nd:YAG 레이저를 이용한 비결정질 재료의 용접 시 레이저의 흡수 거동)

  • 이건상
    • Laser Solutions
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    • v.2 no.1
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    • pp.43-50
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    • 1999
  • For the conventional welding method. the high heat transfer makes the crystallized zone of the work material unavoidable. Whereas the laser is able to weld the amorphous metal without a crystallized zone, because heat transfer is limited within a very small restricted volume. In this paper, the possibilities and the limits of the laser welding were studied to utilize the advantageous properties of amorphous metal foils.

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Fabrication and consolidation of amorphous Cu55Ti45 powders by mechanical alloying (기계적 합금화에 의한 비정질 Cu55Ti45 분말의 제조 및 성형)

  • 김도용
    • Journal of Powder Materials
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    • v.7 no.2
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    • pp.85-92
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    • 2000
  • The Cu55Ti45 system was effectively mechanically-alloyed using a pulverizer. Noncrystallinities of the powders were characterized by TEM, X-ray and DSC. The amorphous powders were consolidated without losing their noncrystallinities. The consolidating conditions keeping a non-crystalline were obtained by building a TTT diagram of the amorphous powders. The microhardness of the crystallite and bulk amorphous alloys are also compared.

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Amorphous Diamond for Generating Cold Cathode Fluorescence Light

  • Sung, James-C.;Kan, Ming-Chi;Hu, Shao-Chung
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.913-914
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    • 2006
  • Amorphous diamond has a very low work function (1 eV) at modest temperature ($150^{\circ}C$). It has been coat coated on electron emitting electrodes. Such electrodes are used for cold cathode fluorescence lamps (CCFL) that illuminate liquid crystal displays (LCD) for rnote books and television sets. Amorphous diamond can dramatically reduce the turn-on voltage to lit CCFL so the lamp life can be greatly extended. Moreover, the electrical current can be increased to enhance the brightness of the light.

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Preparation and Magnetic Properties of Amorphous Spinel Ferrite (비정질 Spinel Ferrite의 제조와 그 자기적 특성)

  • 김태옥;김창곤
    • Journal of the Korean Magnetics Society
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    • v.2 no.1
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    • pp.29-36
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    • 1992
  • The fundamental research about the amorphous ferrite, which is expected as the important material for electronic and information imdustry in future, was carried out in this work. Because the ferromagnetic amorphous ferrites reported recently are very inferior in magnetic properties than the crystalline ferrites, the development of the more ferromagnetic amorphous ferrites is required. In order to obtain the fundamental data for the preparation of amorphous ferrites, the hand-made twin-roller quenching apparatus was used for rapid quenching. Investigation on amorphous ferrite in the system $CaO-Bi_{2}O_{3}-Fe_{2}O_{3}$ has been carried out in the composition of 10-50 mole% CaO, 10-50 mole% $Bi_{2}O_{3}$, 40-70 mole% $Fe_{2}O_{3}$. Large magnetization values were obtained near the composition of the mixture of $BiFeO_{3}$ and $CaFe_{4}O_{7}$. Especially, an amorphous ${(CaO)}_{20}{(Bi_{2}O_{3})_{15}{(Fe_{2}O_{3})}_{65}$ specimen has a magmetization value of about 21.84 emu/g at 0K(10 kOe). Fe $M\"{o}ssbauer$ absorption spectrum indicates that this specimen is compsed of two amorphous phases, antiferromagnetic phase($\alpha$-phase) and ferromagnetic phase($\beta$-phase). Crystallization of this amorphous ferrite was happened in steps-$550^{\circ}C$ and $775^{\circ}C$, then observed crystal phases were perovskite phase of $BiFeO_{3}$ and $Fe_{2}O_{3}$ phase.

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Production of Fe Amorphous Powders by Gas-atomization Process and Subsequent Spark Plasma Sintering of Fe Amorphous-ductile Cu Composite Powders Produced by Ball-milling Process (I) - I. Gas Atomization and Production of Composite Powders - (가스분무법에 의한 Fe계 비정질 분말의 제조와 볼밀링공정에 의한 연질 Cu 분말과의 복합화 및 SPS 거동 (I) - I. 가스분무 및 복합화 -)

  • Ryu, Ho-Jin;Lim, Jae-Hyun;Kim, Ji-Soon;Kim, Jin-Chun;Kim, H.J.
    • Journal of Powder Materials
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    • v.16 no.5
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    • pp.316-325
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    • 2009
  • Fe based (Fe$_{68.2}$C$_{5.9}$Si$_{3.5}$B$_{6.7}$P$_{9.6}$Cr$_{2.1}$Mo$_{2.0}$Al$_{2.0}$) amorphous powder, which is a composition of iron blast cast slag, were produced by a gas atomization process, and sequently mixed with ductile Cu powder by a mechanical ball milling process. The experiment results show that the as-prepared Fe amorphous powders less than 90 $\mu$m in size has a fully amorphous phase and its weight fraction was about 73.7%. The as-atomized amorphous Fe powders had a complete spherical shape with very clean surface. Differential scanning calorimetric results of the as-atomized Fe powders less than 90 $\mu$m showed that the glass transition, T$_g$, onset crystallization, T$_x$, and super-cooled liquid range $\Delta$T=T$_x$-T$_g$ were 512, 548 and 36$^{\circ}C$, respectively. Fe amorphous powders were mixed and deformed well with 10 wt.% Cu by using AGO-2 high energy ball mill under 500 rpm.