• Title/Summary/Keyword: Alkaloids

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The Insecticide Constituents of Several Celastraceae Plants

  • Wang, MingAn;Wu, WenJun
    • The Korean Journal of Pesticide Science
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    • v.6 no.1
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    • pp.9-15
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    • 2002
  • The insecticide constituents of several Celastraceae family plants including Celastrus angulatus, Celastrus orbiculatus, Celastrus flagellaris, Euonymus verrucosides, Euonymus forunei and Euonymus phellomana were studied by bioassay-guided fractionation. All structures of sesquiterpene polyol esters and alkaloids have been elucidated by UV, IR, MS, NMR and x-ray diffraction evidences. These compounds exhibited insecticidal, antifeedant and narcotic activities against Mythimna separata.

Approaches to the Syntheses of Partially Reduced Imidazo[1,2-a]pyridines

  • Shin, Jun-Hwa;Nho, Young-Chang;Howard, Arthur S.
    • Bulletin of the Korean Chemical Society
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    • v.29 no.10
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    • pp.1998-2004
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    • 2008
  • Two synthetic pathways to substituted hexahydroimidazo[1,2-a]pyridines, which may serve as precursors of aza-alkaloids, were investigated. The first involves the condensation of a bisnucleophilic enediaminoester and a biselectrophile. The second involves attachment to nitrogen of the carbon chain skeleton required to form the six-memberd ring, before formation of the enediaminoester. Several substituted hexahydroimidazo[1,2- a]pyridines were synthesized via these two approaches.

NMR Techniques for the Structure Elucidation and Conformational Analysis of Natural Products

  • Cordell, Geoffrey A.
    • Korean Journal of Pharmacognosy
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    • v.19 no.3
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    • pp.153-169
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    • 1988
  • The combined use of the J-modulated selective INEPT and CSCM 1DNMR techniques is described for the structure elucidation of several new classes of compound including prionitin, the loureirins and larreantin, and for the regiosubstitution of the furanonaphthoquinones. Spectroscopic studies on the conformation of the cytotoxic agent savinin are also described, together with the NMR assignments and preliminary biosynthetic experiments on the antitumor antibiotic staurosporine.

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Studies on Korean Aconitum Species ( III ). -Alkaloids of Aconitum uchiyamai- (한국산(韓國産) 부자류(附子類) 생약(生藥)에 관한 연구( III ). -그늘돌쩌귀(Aconitum uchiyamai)의 diterpene alkaloid에 대하여-)

  • Chung, Bo-Sup;Lee, Hyeong-Kyu;Lee, Hyun-Sun
    • Korean Journal of Pharmacognosy
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    • v.19 no.3
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    • pp.177-180
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    • 1988
  • A diterpene alkaloid and a disaccharide were isolated from root of Aconitum uchiyamai, and identified as mesaconitine and sucrose respectively by UV, IR, MS, and NMR data.

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Isolation and Identification of Phenolic Tertiary and Quaternary Alkaloids from Thalictrum uchiyamai (한국산 Thalictrum속 식물의 성분연구(II) 자주꿩의 다리 뿌리의 성분)

  • 이인란
    • YAKHAK HOEJI
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    • v.28 no.3
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    • pp.185-190
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    • 1984
  • Protothalipine colorless needle crystal, mp $195-6^{\circ}$, $C_{21}H_{25}NO_{5}$) and jatrorrhizine chloride (Base A, orange needle crystal, mp $198^{\circ}$) are identified by chemical, spectral analysis, and comparison with authentic sample. Base B (reddish crystal, mp $192-4^{\circ}$) might be a artifact substance, which was changed from the jatrorrhizine chloride. Base C (yellowish needle crystal, mp $228~230^{\circ}$) and Base D (reddish needle crystal, mp $211~213^{\circ}$) were assumed to be thalifendine chloride, desoxythalidastine chloride by phytochemical and spectral analysis respectively.

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One-Pot Synthesis of 2H-Pyrans by Indium(III) Chloride-Catalyzed Reactions.Efficient Synthesis of Pyranocoumarins, Pyranophenalenones, and Pyranoquinolinones

  • Lee, Yong-Rok;Kim, Do-Hoon;Shim, Jae-Jin;Kim, Seog K.;Park, Jung-Hag;Cha, Jin-Soon;Lee, Chong-Soon
    • Bulletin of the Korean Chemical Society
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    • v.23 no.7
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    • pp.998-1002
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    • 2002
  • An efficient synthesis of 2H-pyrans is achieved by indium (III) chloride-catalyzed reactions of 1,3-dicarbonyl compounds with a variety of $\alpha\beta-unsaturated$, aldehydes in moderate yields. This method has been applied to the synthesis of pyranocoumar ins, pyranophenalenones, and pyranoquinolinone alkaloids.