• Title/Summary/Keyword: Alkaline series

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Deinking efficiency of ONP with enzyme blended deinking agent (복합탈묵제의 ONP 탈묵 적성)

  • Yun, Kyong-Dong;Park, Heon-Sin;Eom, Tae-Jin
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.04a
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    • pp.167-173
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    • 2006
  • Deinking is a series of unit operations designed to detach ink from cellulose fibers and separate the dispersed ink from the pulp slurry. Deinking chemicals are process aids that enable expensive mill equipment used in these unit operations to operate more efficiently - often much more efficiently. We propose the blended deinking agent with cellulolutic enzymes and synthetic collector in deinking pulp of conventional alkaline method. The deinking efficiency of old news print in alkaline pH was enhanced with enzyme treatments. The brightness of deinked pulp was increased with less residual ink particles and yield of enzymatic deinked pulp was improved compared to the deinked pulp of conventional alkaline method. Enzymes in biomass were use to Chemical Deinking for reduce environment pollution through surfactant and improve surfactants. examining into compatibility Enzymes and surfactants, these new materials are studied efficiency of deinking efficiency.

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Construction and Characterization of Poly (Phenylene Oxide)-Based Organic/Inorganic Composite Membranes Containing Graphene Oxide for the Development of an Anion Exchange Membrane with Extended Ion Cluster (확장된 이온 클러스터를 갖는 음이온 교환막 개발을 위한 그래핀 옥사이드를 함유한 폴리(페닐렌 옥사이드) 기반 유·무기 복합막의 제조 및 특성분석)

  • CHU, JI YOUNG;YOO, DONG JIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.6
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    • pp.524-533
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    • 2021
  • In this study, a series of anion conductive organic/inorganic composite membranes with excellent ionic conductivity and chemical stability were prepared by introducing graphene oxide (GO) inorganic nanofiller into the quaternized poly(phenylen oxide (Q-PPO) polymer matrix. The fabricated organic/inorganic composite membranes showed higher ionic conductivity than the pristine membrane. In particular, Q-PPO/GO 0.7 showed the highest ionic conductivity value of 143.2 mS/cm at 90℃, which was 1.56 times higher than the pristine membrane Q-PPO (91.5 mS/cm). In addition, the organic/inorganic composite membrane showed superior dimensional stability and alkaline stability compared to the pristine membrane, and the physicochemical stability was improved as the content of inorganic fillers increased. Therefore, we suggest that the as-prepared organic/inorganic composite membranes are very promising materials for anion exchange membrane applications with high conductivity and alkaline stability.

Geochemistry and Petrogenesis of Pliocene Alkaline Volcanic Rocks of Dok Island, Korea

  • Wee, Soo Meen
    • Journal of the Korean earth science society
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    • v.36 no.5
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    • pp.447-459
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    • 2015
  • Dok island comprises Pliocene volcanic products such as a series of volcanoclastic rocks and lavas ranging in composition from alkali basalts, and trachyandesites to trachytes. Compositional variation of the basaltic rocks can be attributed to fractional crystallization of olivine, clinopyroxene, plagioclase, and magnetite. Chemical variations among the trachyandesites are caused by fractionation of clinopyroxene, plagioclase, and magnetite with minor amphibole, while trachytes are controlled mainly by feldspar fractionation. Incompatible element abundance ratios and chondrite normalized LREE/HREE ratios (e.g., (La/Yb)c: 24.8 to 32.8 for basalts, 15.6 to 31.2 for trachyandesites) suggest that the origins of the basalts and trachyandesites involve both different degrees of partial melting and subsequent fractional crystallization processes. Trace element ratios of the basalts from Dok island are characterized by high Ba/Nb, La/Nb, Ba/Th and Th/U and isotopic ratios (Tasumoto and Nakamura, 1991) that are similar to the EM 1 type of oceanic island basalts such as Gough and Tristan da Cunha basalts.

Effects of Colostrum Basic Protein from Colostrum Whey Protein: Increases in Osteoblast Proliferation and Bone Metabolism

  • Lee, Jeong-Rai;Kim, Hyun-Mi;Choi, Hee-Sun;Hong, Jeong-Hwa
    • Preventive Nutrition and Food Science
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    • v.12 no.1
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    • pp.1-6
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    • 2007
  • Colostrum basic proteins (CBP) (MW 1$\sim$30 kDa) were isolated from bovine colostrum using a series of ultrafiltration processes and their effects on osteoblast cell proliferation and bone metabolism were investigated in cell line and animal models. Treatments with CBP (1, 10, 100 $\mu$g/mL) dose-dependently increased cell proliferation of osteoblastic MC3T3 cells. Alkaline phosphatase activity, a marker of osteoblastic phenotype, in the cells was also increased after treatments with CBP in a dose-dependent manner. Significant increases in bone density were observed in femur of ovariectomized rats which were fed a diet with 1% and 10% CBP, compared to rats fed a normal diet. These results suggest that CBP may increase bone mass and density and be useful for the prevention of bone-related diseases.

Melt Properties of Plasma Display Panel Substrate Glasses Based on Float Process (Float 공법을 고려한 Plasma Display Panel용 기판유리 용융체의 특성)

  • Kim, Ki-Dong;Jung, Woo-Man;Jung, Hyun-Su;Kwon, Sung-Ku;Choi, Se-Young
    • Journal of the Korean Ceramic Society
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    • v.43 no.7 s.290
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    • pp.433-438
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    • 2006
  • In order to examine the working condition of melts in tin bath of float process it was investigated Sn diffusion behavior and solidification rate of melts for alkali-alkaline earth-silica PDP substrate glasses such as commercial CaO rich CS-77 glass, commercial $Al_2O_3$ rich PD-200 glass and self developed $SiO_2$ rich T-series (T-2, T-4, T-6) glasses. In the case of Sn depth and concentration created in glass surface by ion exchange between Sn and alkali, T-series showed lower value than CS-77, especially T-2 is more excellent than PD-200. The solidification rate of melts expressed by cooling time between $log{\eta}=4\;and\;7.6dPa{\cdot}s$ was low for T-series comparing with CS-77 and PD-200. Therefore, it was concluded that T-series is desirable considering forming condition in the tin bath of the float process.

Geology of the Kualkulun in the Middle Kalimantan, Indonesia: II. Mineralogy and Geochemistry (인도네시아 중부 칼리만탄 쿠알라쿠룬 지역의 지질: II. 광물 및 지구화학)

  • Kim In-Joon;Lee Gyoo Ho;Cho Deung-Lyong;Lee Seung-Ryeol;Lee Sa-Ro
    • Economic and Environmental Geology
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    • v.37 no.5
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    • pp.459-475
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    • 2004
  • The geology of the Kualakulun area in Middle Kalimantan, Indonesia comprises Permian to Carboniferous Pinoh Metamorphic Rocks and Cretaceous Sepauk Plutonics of the Sunda Shield, late Eocene Tanjung Formation, Oligocene Malasan Volcanics, Oligocene to early Miocene Sintang Intrusives and Quaternary alluvium. Sepauk Plutonic rocks are classified as the calc-alkaline series and the S-type granite. Sintang Intrusive rocks are basic-intermediate and intermediate rocks, and consists of basalt, basaltic andesite, basaltic trachyandesite and trachyandesite. The Malasan Volcanics are characterized by intermediate dacitic pyroclasticl and minor lavas and belong to the subalkaline (calc-alkaline and tholeiitic) series. The whole-rock K-Ar ages of the fine-grained biotite granites and medium-grained granitoids were determined to be 100.5-106.5 Ma and 91.9-102.6 Ma, respectively. The whole-rock K-Ar age of the diorite is 89.1 Ma. K-Ar ages of the Malasan Volcanics and Shintang intrusives show 31.5-36.8 Ma and 24.6-34.5 Ma, respectively, and correspond to the Tertiary time.

Kinetics and Mechanism of Alkaline Hydrolysis of [(Methoxy)(p-substituted styryl)-carbene] Pentacarbonyl Chromium(0) Complexes in Aqueous Acetonitrile

  • Shin, Gap-Cheol;Hwang, Jae-Young;Yang, Ki-Yull;Koo, In-Sun;Lee, Ik-Choon
    • Bulletin of the Korean Chemical Society
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    • v.26 no.12
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    • pp.1981-1985
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    • 2005
  • Kinetic studies have been performed for alkaline hydrolysis of a series of [(methoxy)(p-substituted styryl)carbene]pentacarbonyl chromium(0) complexes ($(CO)_5$Cr=$C(OCH_3)CH=CHC_6H_4X$, X = p-$OCH_3$, p-$CH_3$, H, p-Cl, p-$NO_2$). Second-order rate constants $(k_{{OH}^-})$ for the alkaline hydrolysis in 50% acetonitrile-water(v/v) were determined spectrophotometrically at various temperatures. At a low pH region (pH < 7.5), the observed rate constant $(k_{obs})$ remained constant with a small value, while in a high pH region (pH > 9.5), $k_{obs}$ increases linearly with increasing the pH of the medium. The second-order rate constants $(k_{{OH}^-})$ increase as the substituent X changes from a strong electron donating group to a strong electron withdrawing group. The Hammett plot obtained for the alkaline hydrolysis is consisted of two intersecting straight lines. The nonlinear Hammett plot might be interpreted as a change in the rate-determining step. However, the fact that the corresponding Yukawa-Tsuno plot is linear with $\rho$ and r values of 0.71 and 1.14, respectively indicates that the nonlinear Hammett plot is not due to a change in the rate-determing step but is due to ground-state stabilization through resonance interaction. The positive $\rho$ value suggests that nucleophilic attack by $OH^-$ to form a tetrahedral addition intermediate is the rate-determining step. The large negative ${\Delta}S^\neq$ value determined in the present system is consistent with the proposed mechanism.

Petrology of the Cretaceous Volcanic Rocks in the Gyemyeong peak and Janggun peak area, Mt. Geumjeung, Busan (부산 금정산의 계명봉과 장군봉 일대 백악기 화산암류에 관한 암석학적 연구)

  • Kim, Hye-Sook;Kim, Jin-Seop;Moon, Ki-Hoon
    • The Journal of the Petrological Society of Korea
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    • v.18 no.1
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    • pp.1-17
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    • 2009
  • This article carried studies of the petrographical and petrochemical characteristics on the Cretaceous volcanic rocks in the area of Janggun peak and Gyemyeong peak which is located at the northeastern area of Mt. Geumjeong, Busan. The areas are composed of andesitic rock, sedimentary rock, rhyolitic rock, and intrusive hornblende, biotite granites, in ascending order. According to petrochemistry, the major elements show the calc-alkaline rock series ranged medium-K to high-K. With increasing $SiO_2$, $Al_{2}O_{3}$, $Fe_{2}O_{3}$, $TiO_2$ CaO, MgO MnO and $P_{2}O_{5}$ are decreased and $K_{2}O$ and $Na_{2}O$ are increased in the volcanic rocks. The trace element compositions show high LILE/HFSE ratios and negative anomaly of Nb, and REE patterns show enrichments in LREE and (-) anomaly values increase of Eu from the basaltic andesite to andesite facies, therefore the volcanic rocks have typical characteristics of continental margin arc calc-alkaline volcanic rocks, produced in the subduction environment. The volcanic rock show nearly the same patterns in spider and REE diagram. Fractional crystallization of the basaltic magma would have produced the calc-alkaline andesitic magma. And the rhyolitic magma seems to have been evolved from the basaltic andesitic magma with fractional crystallization of plagioclase, pyroxene, hornblende, biotite.

Studies the Carotenoids in the Viscera of the Brine Schrimp(Penaeus Orientalis Kishinouye) (새우의 Carotenoid 성분에 관한 고찰)

  • Lee, In Kil
    • Journal of Environmental Health Sciences
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    • v.11 no.1
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    • pp.29-34
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    • 1985
  • The studies on the carotenoids in the viscera the brine shrimp(Penaeus Orientalis Kishinouye) have been carried out. The brine shrimps were caught around the western coastal area of Korea from Aug. to Oct. The individual carotenoids in the acetone extracts were separated and purified by the silica gel TLC. Two isolated carotenoids were investigated and identified by epoxide test, partition test, alkaline hydrolysis, reduction with sodium borohydride and visible absorption spectrophqtometry. As the results of the series of experiments, esterified Astaxanthin was discovered as one of main pigments of Penaeus Orientalis Kishinouye.

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Petrology of the Cretaceous volcanic rocks in northern Yucheon Minor Basin, Korea (북부 유천소분지에 분포하는 백악기 화산암류에 대한 암석학적 연구)

  • Sang Wook Kim;Sang Koo Hwang;Yoon Jong Lee;Jae Young Lee;In Seok Koh
    • The Journal of the Petrological Society of Korea
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    • v.7 no.1
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    • pp.27-36
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    • 1998
  • The volcanic piles in the northern Yucheon Minor Basin area are the Hagbong basaltic rocks, the Chaeyaksan basaltic rocks, the Jusasan andesitic rocks, the Unmunsa rhyolitic rocks, and the Tertiary voicanics. Stratigraphically, from the lowermost, (1) the Hagbong basaltic rocks are composed mainly of basaltic tuff with two olivine basalt flows intercalated, (2) the Chaeyagsan basaltic rocks are predominantly in tuffs and agglomerate with 3 basaltic flow interlayers, (3) the Jusasan andesitic rocks consist of thick piles of alternated sequences of 4 andesite flows and 5 andesitic tuffs and tuffaceous sediments and (4) the Unmunsa rhyolitic rocks which embed some rhyolite and obsidian are dominant in tuffs such as ash flow and crystal welded tuff. These volcanics reveal distinguishable characteristics in petrochemistry. In discriminating by major elements, the Hagbong and the Chaeyagsan basaltic rocks are alkaline, whereas the latter is also spilitic. In comparison, the volcanic rocks of the Jusasan andesitic rocks and the Tertiary sequences are characteristically calc-alkaline although their distribution is spatially separated. On the other hand, the variations in immobile trace elements indicate that the Hagbong basaltic rocks range from alkaline to calc-alkaline and from WPB/VAB transition to VAB, whereas the Chaeyagsan basaltic rocks are calc-alkaline WPB/VAB transition type and the two others calc-alkaline VAB. In order to show such a variety in their rock series of the volcanic rocks, the environment during their magma generation, magma rising, and post-eruption alteration could be positively considered.

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