• 대한금속재료학회지
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• 제49권12호
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• pp.1001-1004
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• 2011

The formation of TiC and $Al_2O_3$ particles based on the self-combustion reaction of the $Al-TiO_2-C-CuO$ system in an Al alloy melt was investigated. With an adequate amount of CuO in the system, a spontaneous reaction occurred within the Al alloy melt at $850^{\circ}C$ and thereafter was self-maintained, producing an Al matrix composite reinforced with thermodynamically stable TiC and $Al_2O_3$ particles. TiC and $Al_2O_3$ particles contributed to a considerable increase in the strength and stiffness, demonstrating the feasibility of this method as a practical application for structural parts.

• 수산해양기술연구
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• 제24권4호
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• pp.164-171
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• 1988

Recently with the rapid development in marine and shipbuilding industries such as marine structures, ships and chemical plants, it takes much interest in the study of corrosion fatigue characteristics that was close up an important role in mechanical design. In this study, characteristics of corner crack propagation on the base metal and heat affected zone of 5086 Al-Alloy was tested by using of a rotary bending fatigue tester and was investigated under the environments of specific resistance, $\rho$=25$\Omega$ cm and air. The corrosion fatigue crack initiation and corrosion fatigue life sensitivity were quantitatively inspected for 5086 Al-Alloy in the specific resistance, $\rho$=25$\Omega$ cm. Main results obtained are as follows: (1) The corrosion sensitivity of heat affected zone under specific resistance, $\rho$=25$\Omega$cm shows approximately 1.69~2.22 and corrosion sensitivity of base metal is more susceptible than that of heat affected zone. (2) The corrosion fatigue life sensitivity on heat affected zone decreases eminently than that of initial corrosion fatigue crack. (3) The characteristics of quarter elliptical corner crack propagation shows that depth crack is more grown than surface crack at crack initiation, but the surface crack is more propagated than depth crack as the crack propagation is increased. (4) The surface crack and depth crack growth on heat affected zone by softness show delayed phenomenon than that of base metal.

• Journal of Welding and Joining
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• 제18권2호
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• pp.86-94
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• 2000

This study was performed to investigate types and formation mechanism of cracks in two Al alloy welds, A5083 and A7N01 spot-welded by pulse Nd : YAG laser, using SEM, EPMA and Micro-XRD. In the weld zone, three types of crack were observed : center line crack({TEX}$C_{C}${/TEX}), diagonal crack({TEX}$C_{D}${/TEX}), and U shape crack({TEX}$C_{U}${/TEX}). Also, HAZ crack({TEX}$C_{H}${/TEX}) was observed in the HAZ region, furthermore, mixing crack({TEX}$C_{M}${/TEX}) consisting of diagonal crack and HAZ crack was observed. White film was formed at th hot crack region in the fractured surface after it was immersed to 10% NaOH water. In the case of A5083 alloy, white films in {TEX}$C_{C}${/TEX} crack and {TEX}$C_{D}${/TEX} crack region were composed of low melting phases, {TEX}$Fe_{2}SiAl_{8}${/TEX} and eutectic phases, $Mg_2$Al$_3$ and $Mg_2$Si. Such films observed $CuAl_2$, {TEX}$Mg_{32}(Al,Zn)_{3}${/TEX}, MgZn$_2$, $Al_2$CuMg and $Mg_2$Si were observed in the whitely etched films near {TEX}$C_{C}${/TEX} crack and {TEX}$C_{D}${/TEX} crack regions. The formation of liquid films was due to the segregation of Mg, Si, Fe in the case of A5083 alloy and Zn, Mg, Cu, Sim in the case of A7N01 alloy, respectively. The {TEX}$C_{C}${/TEX} and {TEX}$C_{D}${/TEX} cracks were regarded as a result of the occurrence of tensile strain during the welding process. The formation of {TEX}$C_{M}${/TEX} crack is likely to be due to the presence of liquid film at the grain boundary near the fusion line in the base metal as well as in the weld fusion zone during solidification. The {TEX}$C_{U}${/TEX} crack is considered a result of the collapsed keyhole through incomplete closure during rapid solidification.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.759-760
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• 2006

Ti-6Al-4V has low specific gravity, high corrosion resistance and superior mechanical properties but it is very difficult to control oxygen content in MIM process. It is necessary to use powders with coarse particle size to decrease oxygen content of powders, so feedstocks with poor fluidity and sintered bodies with lower density are obtained in such cases. Fine titanium hydride-dehydride powders were blended with atomized powders to accomplish higher fluidity and sintered density. Sintered bodies had higher sintered density and mechanical properties equivalent to those of wrought materials by controlling oxygen content less than 0.35mass%.

• 한국추진공학회지
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• 제26권1호
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• pp.12-19
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• 2022

덕티드 로켓의 가스발생기에 사용되는 추진제는 연료과농 추진제로서, 일반적인 고체 로켓 추진제에 비하여 과량의 금속연료와 소량의 산화제를 포함한다. 본 논문에서는 연료과농 추진제를 제조하기 위하여 보론 분말과 MgAl(Magnesium-Aluminium Alloy)를 적용하였다. 이 금속연료를 적용한 추진제의 특성을 분석하였고, 이를 통하여 최적의 조성을 연구하였다. 추진제의 연소생성물 분석을 통하여 보론 비드가 아닌 미립의 보론 분말로도 가스발생기용 연료과농 추진제가 가능함을 확인하였다.

• 한국응용과학기술학회지
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• 제33권3호
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• pp.441-448
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• 2016

본 연구는 구리 아연 금속합금의 산화 환원 반응과 합성 알루미늄 실리케이트의 흡착 반응을 이용한 폐수 중 중금속 처리에 관한 연구이다. 극세사 형태로 제조된 구리 아연 금속합금이 수용액 중에서 산화 환원반응에 의해 아연보다 이온화 경향이 작은 중금속은 환원 처리되고, 이온화 된 아연 및 미반응 중금속은 흡착 처리하여 제거하는 연구이다. 극세사 형태로 제조된 금속합금 물질은 표면적이 커서 1회 처리만으로도 반응 평형에 도달하게 하여 효율이 높은 것으로 나타났다. 크롬($Cr^{+3}$)은 redox 반응 1회 처리만으로도 100.0 % 제거 되었으며, 수은은 98.0 %, 주석 92.0 %, 구리는 91.4 % 정도 제거되었다. 카드뮴, 니켈, 납도 각각 40.0 %, 50.0 %, 58.0 %가 제거 되었다. 크롬($Cr^{+3}$)은 아연과 이온화 경향 차이가 거의 없지만 제거 효율이 높은 것으로 나타났는데 이는 3가 크롬은 이온 상태로 존재하면 redox 반응에서 발생한 $OH^-$ 이온과 결합하여 수산화물 침전을 형성하는 것으로 판단된다. Redox 반응 후 증가한 아연 및 미반응 중금속 농도를 알루미늄실리케이트를 1회 통과하여 거의 100.0 % 제거할 수 있었다. 이는 합성 알루미늄 실리케이트의 비표면적이 크고 금속 이온의 흡착능력이 우수한 것으로 나타났으며, 반응 후 알루미늄 이온은 증가하지 않는 것으로 보아 이온 교환이 아닌 흡착으로 아연 및 중금속 이온들을 제거할 수 있는 것으로 나타났다.

• 대한기계학회논문집A
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• 제21권2호
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• pp.346-351
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• 1997

The creep characteristics of an Al-5wt.% Ag alloy including the stress exponent, the activation energy for creep and the shape of the creep curve were investigated at a normalized shear stress extending from $ 10^{-5}{\;}to{\;}3{\times}10^{-4}$ and in the temperature range of 640-873 K, where silver is in solid solution. The experimental results shows that the stress exponent is 4.6, the activation energy is 141 kJ/mole, and the stacking fault energy is $180{\;}mJ/m^2$, suggesting that the creep behavior of Al-5 wt.% Ag is similiar to that reported for pure aluminum, and that under the current experimental conditions, the alloy behaves as a class II(metal class). The above creep characteristics obtained for Al-5 wt.% Ag are discussed in the light of prediction regarding deformation mechanisms in solid solution alloys.

• 청정기술
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• 제9권2호
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• pp.57-61
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• 2003

금속가공 공정에서 알루미늄 합금소재의 알칼리 에칭 후 표면에 발생한 스머트(Smut) 를 제거하기 위해 무질산 디스머트(Nitric acid-free desmut) 용액을 개발하였다. 과산화수소(2%), 불산(0.5%) 및 황산(10%)을 혼합한 산용액이 NaOH 수용액에 처리한 A16061 및 A15052 규격의 알루미늄 합금 소재에 대한 스머트 제거효과가 5% 질산수용액의 사용할 경우와 유사하게 관찰되었다. 스머트 제거를 위한 혼합 산용액 처리 전 후 소재 표면을 SEM-EPMA 분석을 통해 확인하였다.

• 조명전기설비학회논문지
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• 제20권2호
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• pp.24-28
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• 2006

본 논문은 마이크로 전극 측정 시스템을 사용하여 차세대 신동력 산업인 HEV(Hybrid Electric Vehicle) 및 수소연료전지(PEMFC) 차량용 니켈 수소전지의 전극소재로 사용되고 있는 수소저장합금(Mm : misch metal, $MmNi_{3.55}Co_{0.75}Mn_{0.4}Al_{0.3}$)의 단일 입자에 대해 전기화학적 수소 흡방출 특성 평가를 수행 하였다. 즉 Carbon fiber 마이크로 전극을 합금 입자 한개 위에 전기적인 접촉을 이루도록 조정하고, Cyclic Voltammetry 및 Galvanostatic 충방전 실험을 수행하였다. 그 결과 단일 입자의 방전용량은 약 280[mAh/g]로 이론용량의 약 90[%]의 특성을 보여 주었다. 데이터는. 실제 Ni-MH전지를 구성하는 합금입자 그리고 폴리머 바인더로 구성된 Composite film 전극과 비교 하였다. 추가적으로 합금의 단일 입자에 있어 in situ 미분화 현상을 관찰하였다. 마이크로 전극 측정 시스템에 의한 단일 입자의 전기화학적 평가는 기존의 Composite Film 전극에 비해 수소저장합금에 대해 보다 상세하고 정확한 정보를 쉽게 얻을 수 있었다.

• Design & Manufacturing
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• 제14권1호
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• pp.42-48
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• 2020

Titanium alloy has been in the spotlight as a core material in high-tech industries that require high strength and light weight because it has excellent strength and corrosion resistance and strength is higher than that of steel. Therefore, in various industries, existing steel products are intended to be replaced with titanium alloys. Titanium alloys can cause cutting tool breakage during cutting, and heat generated during cutting does not dissipate, accumulates in tools and workpieces, resulting in large wear and tear on thin workpieces. In addition, since titanium alloy is a metal with high chemical activity, the wear of the tool becomes more severe when the cutting speed is high, so machining of titanium bolt through cutting is very disadvantageous in terms of productivity. Therefore, the production of bolts using titanium alloys is being produced through a forging process to improve productivity and product quality. In this paper, hot forging molding analysis was performed on bolts used for fastening automobile parts using Ti-6Al-4V alloy, which is the most commonly used titanium alloy.