• 제목/요약/키워드: Air-Water Interface

검색결과 282건 처리시간 0.026초

BAM을 이용한 L막의 상전이 현상과 유기초박막의 미세구조에 관한 연구 (A Study on the Microstructure of Organic Ultra Thin Films and Phase Transition of Langmuir Films in BAM)

  • 김병근;전동규;김영근;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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    • pp.938-941
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    • 2003
  • It is well known that the state of existence of molecules on the surface of water changes during compression of the molecules. Electric methods, such as measurement of the surface potential or displacement current are also useful for investigating dynamic changes of molecular state on the water surface during compression and Transformation of molecular film occurs only usually in air-water interface, 2 dimensions domain's growth and crash are achieved. Organic thin film that consist of growth of domain can understand correct special quality of accumulation film supplying information about fine structure and properties of matter of device observing information and so on that is surface forward player and optic enemy using AFM one of SPM application by nano electronics. In this paper Langmuir (L) that is one of basis technology to manufacture of organic matter device using biology material PBDG that is kind of polypeptide that have biology adaptedness. The Experiment method used ${\pi}-A$ isotherm and BAM(Brewster Angle Microscopy), using the BAM, we can to the molecular orientation of monolayer on the water surface and directly see the morphology of the films on water subphase as well as that of the films.

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변위전류 측정에 의한 수면상 단분자막의 배향변화 관찰 (Investigation of the orientational changes of monolayer on the water surface by measuring the displacement current.)

  • 박태곤;송경호;박근호;권영수;강도열
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1994년도 하계학술대회 논문집 C
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    • pp.1320-1322
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    • 1994
  • Photoisomerization characteristics of 4-octyl-4'-(5-carboxy-pentamethyleneoxy) azobenzene molecules (8A5H) were attained by measurement of absorbtion spectra. 8A5H in chroloform($6.0{\times}10^{-5}[M/l]$) shows trans to cis and cis to trans isomerization by irradiation of lights of 360[nm] and 450[nm] wavelength. From LB monolayer films of 8A5H, also the cis/trans photoisomerization was obtained and it has reversibility and memory characteristics. We are now trying to detect these properties of 8A5H electrically. On this paper, we investigated the structural changes of monolayer on the water surface by measuring the displacement current as a preliminary experiment. The measuring system was constructed at home-made Kuhn type LB(Langmuir-Blodgett) deposition apparatus. 8A5H solution was spreaded at the air-water interface and the currents induced by the dynamic behavior of molecules were measured when the molecules were pressed by barrier. The reversibility of displacement currents by compression and expansion was obtained from 8A5H molecules, which shows the compressed molecules have a tendency to disperse after the compression. From this experiment, we conclude that the behavior of molecules on water surface can be monitored electrically by using this current measuring method, and this method can also be applied to detect the photoisomerization of monolayers on water surface.

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승온조건의 SEAS(surfactant-enhanced air sparging) 기술을 이용한 대수층 NAPL(n-decane)의 휘발제거 (Removal of NAPL from Aquifer Using Surfactant-enhanced Air Sparging at Elevated Temperature)

  • 송영수;권한준;김헌기
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제14권6호
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    • pp.87-94
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    • 2009
  • 대수층에 존재하는 휘발성 오염물질을 제거하는 새로운 공법으로서 Surfactant-enhanced air sparging(SEAS)은 지하수의 표면장력을 감소함으로써 지하수 폭기효율의 증대를 도모한다. 그러나 SEAS기술도 기본적으로 오염물질의 휘발에 의한 물질이동에 의존함으로써 휘발성이 낮은 오염물질의 제거에는 매우 제한적이다. 본 연구는 승온된 조건에서 SEAS기술을 준휘발성 물질인 n-decane에 대하여 적용함으로써 SEAS기술의 확장여부를 시험하였다. 지하수 폭기실험은 내경 5 cm, 길이 80 cm의 1차원 토양(모래)컬럼을 사용하여 실시하였다. 실험은 총 3회 실시하였으며, 상온에서 증류수로 포화된 조건에서 1회, 상온($23^{\circ}C$)에서 음이온계 계면활성제(sodium dodecylbenzene sulfonate, SDBS) 수용액으로 포화된 조건에서 1회(상온 SEAS), 그리고 승온상태($73^{\circ}C$)에서 SDBS수용액으로 포화된 조건에서 1회(승온 SEAS) 실시하였다. 계면활성제가 적용된 경우의 폭기에 의한 공기포화율(57%)은 증류수로 포화된 조건의 공기포화율(10%)보다 높게 측정되었다. 승온 및 상온조건에서의 공기포화율은 거의 차이가 없었으나 n-decane의 제거속도는 현저한 차이를 나타내었다. 토양유출 가스에 포함된 n-decane의 농도는 상온조건에 비하여 승온조건에서 10배 이상 높았으며, 따라서 제거속도도 10배 이상의 차이를 나타내었다. 본 연구 결과에 따라 상온에서 휘발성이 낮으나 수 십도의 온도상승으로 증기압이 획기적으로 늘어날 수 있는 준휘발성 물질에 대하여 SEAS 기술이 효과적으로 응용될 수 있을 것으로 보인다.

Atmospheric correction by Spectral Shape Matching Method (SSMM): Accounting for horizontal inhomogeneity of the atmosphere

  • ;안유환
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2006년도 춘계학술대회 논문집
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    • pp.341-343
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    • 2006
  • The current spectral shape matching method (SSMM), developed by Ahn and Shanmugam (2004), relies on the assumption that the path radiance resulting from scattered photons due to air molecules and aerosols and possibly direct-reflected light from the air-sea interface is spatially homogeneous over the sub-scene of interest, enabling the retrieval of water-leaving radiances ($L_w$) from the satellite ocean color image data. This assumption remains valid for the clear atmospheric conditions, but when the distribution of aerosol loadings varies dramatically the above postulation of spatial homogeneity will be violated. In this study, we present the second version of SSMM which will take into account the horizontal variations of aerosol loading in the correction of atmospheric effects in SeaWiFS ocean color image data. The new version includes models for the correction of the effects of aerosols and Raleigh particles and a method fur computation of diffuse transmittance ($t_{os}$) as similar to SeaWiFS. We tested this method over the different optical environments and compared its effectiveness with the results of standard atmospheric correction (SAC) algorithm (Gordon and Wang, 1994) and those from in-situ observations. Findings revealed that the SAC algorithm appeared to distort the spectral shape of water-leaving radiance spectra in suspended sediments (SS) and algal bloom dominated-areas and frequently yielded underestimated or often negative values in the lower green and blue part of the electromagnetic spectrum. Retrieval of water-leaving radiances in coastal waters with very high sediments, for instance = > 8g $m^{-3}$, was not possible with the SAC algorithm. As the current SAC algorithm does not include models for the Asian aerosols, the water-leaving radiances over the aerosol-dominated areas could not be retrieved from the image and large errors often resulted from an inappropriate extrapolation of the estimated aerosol radiance from two IR bands to visible spectrum. In contrast to the above results, the new SSMM enabled accurate retrieval of water-leaving radiances in a various range of turbid waters with SS concentrations from 1 to 100 g $m^{-3}$ that closely matched with those from the in-situ observations. Regardless of the spectral band, the RMS error deviation was minimum of 0.003 and maximum of 0.46, in contrast with those of 0.26 and 0.81, respectively, for SAC algorithm. The new SSMM also remove all aerosol effects excluding areas for which the signal-to-noise ratio is much lower than the water signal.

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표면 처리방법에 따른 복합레진의 미세누출에 관한 실험적 연구 (A STUDY ON MICROLEAKAGE OF COMPOSITE RESIN AFTER SURFACE TREATMENT)

  • 이창우;김정욱;이상훈
    • 대한소아치과학회지
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    • 제25권1호
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    • pp.103-115
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    • 1998
  • Adhesion of composite resin to tooth structure has been of tremendous signgicance in clinical dentistry. Due to the lack of adhesion between composite restorative resins and enamel and dentin, microleakage occurs at the tooth/restoration interface. This may lead to discoloration, secondary caries, marginal breakdown, postoperative sensitivity, and even pulpal pathology. According to extensive use of composite resin, every effort on improving bonding strength and reducing microleakage between a tooth and composite resin has been continued. This study was conducted to determine the difference in microleakage in enamel and dentin treated with air-abrasion, acid etching and combination when restored with composite resin. Class V cavities were prepared on 30 premolars. The specimens were divided into following groups. group 1:air-abrasion+Scotchbond Multi-purpose group 4 :air-abrasion+All-Bond 2 group 2:acid etching+Scotchbond Multi-purpose group 5 :acid etching+All-Bond 2 group 3:combination+Scotchbond Multi-purpose group 6 :combination+All-Bond 2 #combination:air-abrasion + acid etching The specimens were filled with Z-100 after application of Scotchbond Multi-purpose and All-Bond 2. Thermocycling was conducted by alternately dipping the specimens in $5^{\circ}C$ and $55^{\circ}C$ water for 30 seconds 500 times. 1% methylene blue was applied and the specimens were left for 24 hours at $37^{\circ}C$. After washing out the dye, the tooth was sectioned buccolingually along the axis. The sectioned surface was observed with stereoscope for dye penetration. The author has measured the microleakage in teeth prepared with air-abrasion, acid ethching and combination to study the difference in microleakage following different methods of tooth surface treatment and has come to following results. 1. In comparing microleakage between groups, group 1 and 4 showed statistically significant difference from group 2, 3, 5 and 6(p<0.05). There was no significant difference among group 2, 3, 5, 6(p>0.05) nor between group 1 and 4(p>0.05). 2. In comparing microleakage among tooth surface treatment methods, Air-abrasion group showed significantly more microleakage than acid etching group and combination(airabrasion + acid etching) group(p<0.05). Combination(acid etching+air-abrasion)group tended to show lesser microleakage than acid etching group, but this was not statistically significant(p>0.05). 3. In comparing microleakage between bonding agents, there was no statistically significant difference between Scotch bond Multi-purpose and All-Bond 2(p>0.05).

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OpenFOAM을 활용한 포말대 이중 댐-붕괴 수치모형실험 (Numerical investigation of swash-swash interaction driven by double dam-break using OpenFOAM)

  • 옥주희;김열우
    • 한국수자원학회논문집
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    • 제56권10호
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    • pp.603-617
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    • 2023
  • 본 연구는 포말대 흐름의 난류특성에 대한 이해를 목표로 한다. 포말대 흐름을 재현하기 위해 이중 댐-붕괴 파랑생성법이 제시되었다. 기존 단일 댐-붕괴 실험과 비교하여 이중 댐-붕괴 실험은 두 개의 수문의 개방 시간을 조절하여 처오름과 처내림의 다양한 상호작용을 구현할 수 있다. 수치모형으로는 OpenFOAM의 overInterDyMFoam이 활용되었다. overInterDyMFoam은 밀도가 다른 두 유체(i.e., 공기, 물)의 경계면 추적기법과 동격자 및 중첩 격자 기법을 결합한 모형이다. 질량보존 및 운동량 방정식으로는 𝜅-𝜖 난류모형이 결합된 이차원 Reynolds-Averaged Navier-Stokes 모형이 채택되었다. 수치모형실험 결과는 수리모형실험의 수심 및 흐름 방향 유속 시계열과 비교하여 정확도가 검증되었다. 난류 운동 에너지 분포특성을 확인하여 각 흐름 단계(i.e., 처오름, 처내림, 흐름의 상호작용)의 난류 진화 특성을 고찰하였다.

경상북도 안강 행주 기씨 묘 출토 직금단 치마와 저고리 보존처리 - 직금단 편금사의 금박 재접착을 중심으로 - (Conservation of Golden Decorative(Jikgeumdan) Jeogori and Chima of Costumes Excavated from Hangju Gi' Tomb of Angang, Kyungsangbukdo Province - Re-adhesion of Gold Leaves in Gilt Paper Strips -)

  • 오준석;노수정
    • 복식
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    • 제57권9호
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    • pp.67-75
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    • 2007
  • The purpose of this research is to conserve of golden decoration(Jikgeumdan) of Chima(skirt) and Jeogori(Korean jacket) of the costumes excavated from Hangju Gi' tomb(17th Century) of Joseon dynasty$(1392{\sim}1910)$ and to focus on the development of conservation skill to prevent flakings of gold leaves in gilt paper strips. Up to the present, in case of golden decorations of costumes excavated from tombs of Joseon dynasty, some of gold leaves in gilt paper strips of costumes were flaked away by deterioration of adhesives in tombs. However, most of gold leaves were flaked away and totally lost by wet cleaning for eliminating contaminants after excavation. In order to prevent flaking, preliminary experiments for re-adhesion of gold leaves have been carried out. Firstly, simulation was performed using gold leaf which was available in the market. Adhesives used in this research were water-soluble adhesives(hide glue(cow, rabbit), glue made from air bladders of sciaenoid fish and Primal AC-3444 of acrylic emulsion) and solvent-soluble adhesives(acrylic adhesive Paraloid B-67 and B-72). Because of difficulty in wetting and spreading of adhesive solutions into the interface between gold leaf and Korean paper, water-soluble adhesives were not proper for adhesion of gold leaf and Korean paper. Solvent-soluble adhesives were easily infiltrated into interface between gold leaf and Korean paper and the adhesive force was also satisfied. From this result, the researchers chose more flexible Paraloid B-72$(Tg\;40^{\circ}C)$ 1% solution than Paraloid B-67$(Tg\;50^{\circ}C)$ for adhesion of gold leaf and Korean paper. Secondly, using Paraloid B-72 1% solution, the estimations of re-adhesions of gold leaves in gilt paper strips of Jeogori were carried out. When Paraloid B-72 1% solution was injected three times into the interface between gold leaf and Korean paper, the re-adhesion was most effective. On the basis of the results in these preliminary experiments, re-adhesions of gold leaves in gilt paper strips of Chima and Jeogori were carried out on condition of three times injections of Paraloid B-72 1% solution before wet cleaning. After wet cleaning, the most of the gold leaves were survived, which was confirmed by both the examination with the naked eye and the microscopic examination.

물-공기 수평 성층류 유동조건에서 액적이탈 현상에 대한 실험연구 (Experimental Investigation on the Droplet Entrainment in the Air-Water Horizontal Stratified Flow)

  • 배병건;윤병조;김경두;배병언
    • 에너지공학
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    • 제24권1호
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    • pp.114-122
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    • 2015
  • 수평 성층류 2상 유동에서 기체의 속도가 액체의 속도보다 상대적으로 큰 고유속 유동조건에서는 불규칙한 파형들이 생성되고 이때 상 경계면에서는 액적이탈이 발생한다. 한국원자력연구원(KAERI)에서는 이러한 상 경계면에서의 액적이탈 현상을 기구학적으로 예측하기 위하여 전단력, 표면장력, 그리고 중력 항으로 구성되는 새로운 액적이탈 모델을 제시하였다. 그러나 이 액적이탈 모델 내부에는 아직 결정되지 않은 모델 계수가 존재한다. 모델 계수를 결정하기 위해서는 두 상 사이의 계면파 특성과 관련되는 물리변수들에 대한 실험데이터의 확보가 필요하다. 주요 물리변수들에는 파의 기울기, 파의 빗변길이, 파의 속도, 파의 주파수, 그리고 파장이 있다. 본 연구에서는 계면파 특성과 관련된 주요 물리변수들을 측정하기 위하여 폭 40 mm, 높이 50 mm, 길이 4.2 m의 수평사각유로에서 가시화실험을 수행하였다. 실험은 1기압의 물-공기 성층류 유동에서 액적이탈이 발생되는 조건에서 수행되었다. 본 실험에서 계면 형상을 2차원적으로 가시화하고 계면파에서 국소적인 물속도 분포를 측정하기 위하여 유로 측면에서 PIV기법을 적용하였다. 추가적으로, 가시화실험을 통해 획득한 계면 이미지로부터 측정된 계면 높이를 검증하기 위하여 평행 와이어 전도도 센서를 개발하였다. 가시화방법과 센서를 통해 측정된 수위를 비교한 결과, 두 가지 방법론에 의해 측정된 수위결과가 잘 일치함을 확인하였다. 최종적으로 개발된 측정기법을 적용하여 액적이탈 조건에서 계면파 특성과 관련된 주요 물리변수들을 측정하였다.

증발하는 물방울의 계면활성제에 의한 열모세관 유동 억제 (Surfactant-Induced Suppression of the Thermocapillary Flow in Evaporating Water Droplets)

  • 윤성찬;김태권;임희창;강관형;임근배
    • 대한기계학회논문집B
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    • 제37권7호
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    • pp.695-701
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    • 2013
  • 본 논문은 비이온의 계면 활성제에 의해 증발하는 물방울의 열모세관 유동(마랑고니 유동)이 억제되는 것을 실험적으로 검증한다. 물방울이 소수성 표면 위에서 증발할 때, 액적 내부의 마랑고니 유동을 관찰하였고, 계면 활성제 농도에 따라 이 유동이 억제되는 것을 조사하였다. 초기 계면 활성제 농도가 증가하면, 마랑고니 유동의 속도와 수명이 감소한다. 이 결과는 계면 활성제에 의해 액적 계면에서 점착 경계 조건이 성립됨을 보여주는데, 이것은 계면 점착 현상과 관련된 기존의 모델에 기초하여 설명되었다. 또한 액적의 초기 계면 활성제 농도가 임계 농도 이하일 때, 증발 초기 접촉선 비고정 현상을 발견했는데, 이것은 마랑고니 유동이 접촉각의 이력 현상을 감소시키기 때문이다.

구강내에서 임플랜트 지대주 형성 시 내부연결방식과 외부연결방식간의 열전달 효과 비교 (THE COMPARATIVE STUDY OF THERMAL INDUCTIVE EFFECT BETWEEN INTERNAL CONNECTION AND EXTERNAL CONNECTION IMPLANT IN ABUTMENT PREPARATION)

  • 허중보;고석민
    • 대한치과보철학회지
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    • 제45권1호
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    • pp.60-70
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    • 2007
  • Statement of problem: The cement-type abutment would be needed for the reduction of its body in order to correct the axis and to assure occlusal clearance. In the case of intraoral preparation, there is a potential risk that generated heat could be transmitted into the bone-implant interface, where it can cause deterioration of tissues around the implant and failed osseointegration. Purpose: The purpose of this study was to assess the difference of the heat transmitting effect on external and internal connection implant types under various conditions. Material and method: For evaluating the effects of alternating temperature, the thermocoupling wires were attached on 3 areas of the implant fixture surface corresponding to the cervical, middle, and apex. The abutments were removed 1mm in depth horizontally with diamond burs and were polished for 30 seconds at low speed with silicone points using pressure as applied in routine clinical practice. Obtained data were analyzed using Mann-Whitney rank-sum test and Wilcoxon / Kruskal-Wallis Tests. Result: Increased temperature on bone-implant interface was evident without air-water spray coolant both at high speed reduction and low speed polishing (p<.05). But, the difference between connection types was not shown. Conclusion: The reduction procedure of abutment without using proper coolant leads to serious damage of oral tissues around the implant irrespective of external and internal connection type.