• Title/Summary/Keyword: Air-Water Interface

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A Study on the Microstructure of Organic Ultra Thin Films and Phase Transition of Langmuir Films in BAM (BAM을 이용한 L막의 상전이 현상과 유기초박막의 미세구조에 관한 연구)

  • Kim, Byung-Geun;Chon, Dong-Kue;Kim, Young-Keun;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.938-941
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    • 2003
  • It is well known that the state of existence of molecules on the surface of water changes during compression of the molecules. Electric methods, such as measurement of the surface potential or displacement current are also useful for investigating dynamic changes of molecular state on the water surface during compression and Transformation of molecular film occurs only usually in air-water interface, 2 dimensions domain's growth and crash are achieved. Organic thin film that consist of growth of domain can understand correct special quality of accumulation film supplying information about fine structure and properties of matter of device observing information and so on that is surface forward player and optic enemy using AFM one of SPM application by nano electronics. In this paper Langmuir (L) that is one of basis technology to manufacture of organic matter device using biology material PBDG that is kind of polypeptide that have biology adaptedness. The Experiment method used ${\pi}-A$ isotherm and BAM(Brewster Angle Microscopy), using the BAM, we can to the molecular orientation of monolayer on the water surface and directly see the morphology of the films on water subphase as well as that of the films.

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Investigation of the orientational changes of monolayer on the water surface by measuring the displacement current. (변위전류 측정에 의한 수면상 단분자막의 배향변화 관찰)

  • Park, Tae-Gone;Song, Kyung-Ho;Park, Keun-Ho;Kwon, Young-Soo;Kang, Dou-Yol
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1320-1322
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    • 1994
  • Photoisomerization characteristics of 4-octyl-4'-(5-carboxy-pentamethyleneoxy) azobenzene molecules (8A5H) were attained by measurement of absorbtion spectra. 8A5H in chroloform($6.0{\times}10^{-5}[M/l]$) shows trans to cis and cis to trans isomerization by irradiation of lights of 360[nm] and 450[nm] wavelength. From LB monolayer films of 8A5H, also the cis/trans photoisomerization was obtained and it has reversibility and memory characteristics. We are now trying to detect these properties of 8A5H electrically. On this paper, we investigated the structural changes of monolayer on the water surface by measuring the displacement current as a preliminary experiment. The measuring system was constructed at home-made Kuhn type LB(Langmuir-Blodgett) deposition apparatus. 8A5H solution was spreaded at the air-water interface and the currents induced by the dynamic behavior of molecules were measured when the molecules were pressed by barrier. The reversibility of displacement currents by compression and expansion was obtained from 8A5H molecules, which shows the compressed molecules have a tendency to disperse after the compression. From this experiment, we conclude that the behavior of molecules on water surface can be monitored electrically by using this current measuring method, and this method can also be applied to detect the photoisomerization of monolayers on water surface.

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Removal of NAPL from Aquifer Using Surfactant-enhanced Air Sparging at Elevated Temperature (승온조건의 SEAS(surfactant-enhanced air sparging) 기술을 이용한 대수층 NAPL(n-decane)의 휘발제거)

  • Song, Young-Su;Kwon, Han-Joon;Kim, Heon-Ki
    • Journal of Soil and Groundwater Environment
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    • v.14 no.6
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    • pp.87-94
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    • 2009
  • Surfactant-enhanced air sparging (SEAS) was developed to suppress the surface tension of groundwater prior to air sparging resulting in higher air saturation and larger contact area between NAPL and gas during air sparging. Larger contacting interface between NAPL and gas means faster mass transfer of contaminants from NAPL to gas phase. This new technique, however, is limited to relatively volatile contaminants because vaporization is its basic mechanism of mass transfer. In this study, SEAS was tested at an elevated temperature for a semi-volatile n-decane, which is expected not to be a good candidate of SEAS application due to its low vapor pressure at ambient temperature. Three sparging experiments were conducted using 1-dimensional column (5 cm id, 80 cm length) packed with sand; (1) ambient temperature ($23^{\circ}C$), column saturated with distilled water, (2) SEAS at ambient temperature ($23^{\circ}C$), for n-decane contaminated sand, (3) SEAS at elevated temperature ($73^{\circ}C$), for n-decane contaminated sand. Higher air saturation was achieved by SEAS compared to that by air sparging without surfactant application. The n-decane removal efficiency of SEAS at elevated temperature was significantly higher(> 10 times) than that of ambient SEAS. The n-decane concentrations in the gas effluent from column during SEAS at $73^{\circ}C$ are found to be 10 times of those measured at ambient temperature. Thus, SEAS technique can be applied for removal of semi-volatile contaminants provided that an appropriate technique for elevating aquifer temperature is available.

Atmospheric correction by Spectral Shape Matching Method (SSMM): Accounting for horizontal inhomogeneity of the atmosphere

  • Shanmugam Palanisamy;Ahn Yu-Hwan
    • Proceedings of the KSRS Conference
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    • 2006.03a
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    • pp.341-343
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    • 2006
  • The current spectral shape matching method (SSMM), developed by Ahn and Shanmugam (2004), relies on the assumption that the path radiance resulting from scattered photons due to air molecules and aerosols and possibly direct-reflected light from the air-sea interface is spatially homogeneous over the sub-scene of interest, enabling the retrieval of water-leaving radiances ($L_w$) from the satellite ocean color image data. This assumption remains valid for the clear atmospheric conditions, but when the distribution of aerosol loadings varies dramatically the above postulation of spatial homogeneity will be violated. In this study, we present the second version of SSMM which will take into account the horizontal variations of aerosol loading in the correction of atmospheric effects in SeaWiFS ocean color image data. The new version includes models for the correction of the effects of aerosols and Raleigh particles and a method fur computation of diffuse transmittance ($t_{os}$) as similar to SeaWiFS. We tested this method over the different optical environments and compared its effectiveness with the results of standard atmospheric correction (SAC) algorithm (Gordon and Wang, 1994) and those from in-situ observations. Findings revealed that the SAC algorithm appeared to distort the spectral shape of water-leaving radiance spectra in suspended sediments (SS) and algal bloom dominated-areas and frequently yielded underestimated or often negative values in the lower green and blue part of the electromagnetic spectrum. Retrieval of water-leaving radiances in coastal waters with very high sediments, for instance = > 8g $m^{-3}$, was not possible with the SAC algorithm. As the current SAC algorithm does not include models for the Asian aerosols, the water-leaving radiances over the aerosol-dominated areas could not be retrieved from the image and large errors often resulted from an inappropriate extrapolation of the estimated aerosol radiance from two IR bands to visible spectrum. In contrast to the above results, the new SSMM enabled accurate retrieval of water-leaving radiances in a various range of turbid waters with SS concentrations from 1 to 100 g $m^{-3}$ that closely matched with those from the in-situ observations. Regardless of the spectral band, the RMS error deviation was minimum of 0.003 and maximum of 0.46, in contrast with those of 0.26 and 0.81, respectively, for SAC algorithm. The new SSMM also remove all aerosol effects excluding areas for which the signal-to-noise ratio is much lower than the water signal.

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A STUDY ON MICROLEAKAGE OF COMPOSITE RESIN AFTER SURFACE TREATMENT (표면 처리방법에 따른 복합레진의 미세누출에 관한 실험적 연구)

  • Lee, Chang-Woo;Kim, Jung-Wook;Lee, Sang-Hoon
    • Journal of the korean academy of Pediatric Dentistry
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    • v.25 no.1
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    • pp.103-115
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    • 1998
  • Adhesion of composite resin to tooth structure has been of tremendous signgicance in clinical dentistry. Due to the lack of adhesion between composite restorative resins and enamel and dentin, microleakage occurs at the tooth/restoration interface. This may lead to discoloration, secondary caries, marginal breakdown, postoperative sensitivity, and even pulpal pathology. According to extensive use of composite resin, every effort on improving bonding strength and reducing microleakage between a tooth and composite resin has been continued. This study was conducted to determine the difference in microleakage in enamel and dentin treated with air-abrasion, acid etching and combination when restored with composite resin. Class V cavities were prepared on 30 premolars. The specimens were divided into following groups. group 1:air-abrasion+Scotchbond Multi-purpose group 4 :air-abrasion+All-Bond 2 group 2:acid etching+Scotchbond Multi-purpose group 5 :acid etching+All-Bond 2 group 3:combination+Scotchbond Multi-purpose group 6 :combination+All-Bond 2 #combination:air-abrasion + acid etching The specimens were filled with Z-100 after application of Scotchbond Multi-purpose and All-Bond 2. Thermocycling was conducted by alternately dipping the specimens in $5^{\circ}C$ and $55^{\circ}C$ water for 30 seconds 500 times. 1% methylene blue was applied and the specimens were left for 24 hours at $37^{\circ}C$. After washing out the dye, the tooth was sectioned buccolingually along the axis. The sectioned surface was observed with stereoscope for dye penetration. The author has measured the microleakage in teeth prepared with air-abrasion, acid ethching and combination to study the difference in microleakage following different methods of tooth surface treatment and has come to following results. 1. In comparing microleakage between groups, group 1 and 4 showed statistically significant difference from group 2, 3, 5 and 6(p<0.05). There was no significant difference among group 2, 3, 5, 6(p>0.05) nor between group 1 and 4(p>0.05). 2. In comparing microleakage among tooth surface treatment methods, Air-abrasion group showed significantly more microleakage than acid etching group and combination(airabrasion + acid etching) group(p<0.05). Combination(acid etching+air-abrasion)group tended to show lesser microleakage than acid etching group, but this was not statistically significant(p>0.05). 3. In comparing microleakage between bonding agents, there was no statistically significant difference between Scotch bond Multi-purpose and All-Bond 2(p>0.05).

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Numerical investigation of swash-swash interaction driven by double dam-break using OpenFOAM (OpenFOAM을 활용한 포말대 이중 댐-붕괴 수치모형실험)

  • Ok, Juhee;Kim, Yeulwoo;Marie-Pierre C. Delislec
    • Journal of Korea Water Resources Association
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    • v.56 no.10
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    • pp.603-617
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    • 2023
  • This study aims to provide a better understanding of the turbulent flow characteristics in swash zone. A double dam-break method is employed to generate the swash zone flow. Comparing with the conventional single dam-break method, a delay between two gate opening can be controlled to reproduce various interactions between uprush and backwash. For numerical simulations, overInterDyMFoam based on OpenFOAM is adopted. Using overInterDyMFoam, interface between two immiscible fluids having different densities (i.e., air and water phases) can be tracked in a moving mesh with multiple layers. Two-dimensional Reynolds-Averaged Navier-Stokes equations are solved with a standard 𝜅-𝜖 turbulence model for momentum and continuity. Numerical model results are validated with laboratory experiment data for the time series of water depth and streamwise velocity. Turbulent kinetic energy distribution is further investigated to identify the turbulence evolution for each flow regime (i.e., uprush, backwash, and swash-swash interaction).

Conservation of Golden Decorative(Jikgeumdan) Jeogori and Chima of Costumes Excavated from Hangju Gi' Tomb of Angang, Kyungsangbukdo Province - Re-adhesion of Gold Leaves in Gilt Paper Strips - (경상북도 안강 행주 기씨 묘 출토 직금단 치마와 저고리 보존처리 - 직금단 편금사의 금박 재접착을 중심으로 -)

  • Oh, Joon-Suk;Noh, Soo-Jung
    • Journal of the Korean Society of Costume
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    • v.57 no.9
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    • pp.67-75
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    • 2007
  • The purpose of this research is to conserve of golden decoration(Jikgeumdan) of Chima(skirt) and Jeogori(Korean jacket) of the costumes excavated from Hangju Gi' tomb(17th Century) of Joseon dynasty$(1392{\sim}1910)$ and to focus on the development of conservation skill to prevent flakings of gold leaves in gilt paper strips. Up to the present, in case of golden decorations of costumes excavated from tombs of Joseon dynasty, some of gold leaves in gilt paper strips of costumes were flaked away by deterioration of adhesives in tombs. However, most of gold leaves were flaked away and totally lost by wet cleaning for eliminating contaminants after excavation. In order to prevent flaking, preliminary experiments for re-adhesion of gold leaves have been carried out. Firstly, simulation was performed using gold leaf which was available in the market. Adhesives used in this research were water-soluble adhesives(hide glue(cow, rabbit), glue made from air bladders of sciaenoid fish and Primal AC-3444 of acrylic emulsion) and solvent-soluble adhesives(acrylic adhesive Paraloid B-67 and B-72). Because of difficulty in wetting and spreading of adhesive solutions into the interface between gold leaf and Korean paper, water-soluble adhesives were not proper for adhesion of gold leaf and Korean paper. Solvent-soluble adhesives were easily infiltrated into interface between gold leaf and Korean paper and the adhesive force was also satisfied. From this result, the researchers chose more flexible Paraloid B-72$(Tg\;40^{\circ}C)$ 1% solution than Paraloid B-67$(Tg\;50^{\circ}C)$ for adhesion of gold leaf and Korean paper. Secondly, using Paraloid B-72 1% solution, the estimations of re-adhesions of gold leaves in gilt paper strips of Jeogori were carried out. When Paraloid B-72 1% solution was injected three times into the interface between gold leaf and Korean paper, the re-adhesion was most effective. On the basis of the results in these preliminary experiments, re-adhesions of gold leaves in gilt paper strips of Chima and Jeogori were carried out on condition of three times injections of Paraloid B-72 1% solution before wet cleaning. After wet cleaning, the most of the gold leaves were survived, which was confirmed by both the examination with the naked eye and the microscopic examination.

Experimental Investigation on the Droplet Entrainment in the Air-Water Horizontal Stratified Flow (물-공기 수평 성층류 유동조건에서 액적이탈 현상에 대한 실험연구)

  • Bae, Byeong Geon;Yun, Byong Jo;Kim, Kyoung Doo;Bae, Byoung Uhn
    • Journal of Energy Engineering
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    • v.24 no.1
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    • pp.114-122
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    • 2015
  • In the high convective gas flow condition, irregular shaped water waves from which droplet entrainment occurs are generated under horizontally stratified two-phase flow condition. KAERI proposed a new mechanistic droplet entrainment model based on the momentum balance equation consisting of the shear stress, surface tension, and gravity forces. However, this model requires correlation or experimental data of several physical parameters related to the wave characteristics. In the present study, we tried to measure the physical parameters such as wave slope, wave hypotenuse length, wave velocity, wave frequency, and wavelength experimentally. For this, an experiment was conducted in the horizontal rectangular channel of which width, height, and length are, respectively, 40 mm, 50 mm, and 4.2 m. In the present test, the working fluids are chosen as air and water. The PIV technique was applied not only to obtain images for phase interface waves but also to measure the velocity field of the water flow. Additionally, we developed the parallel wire conductance probe for the confirmation of wave height from PIV image. Finally, we measured the physical parameters to be used in the validation of new droplet entrainment model.

Surfactant-Induced Suppression of the Thermocapillary Flow in Evaporating Water Droplets (증발하는 물방울의 계면활성제에 의한 열모세관 유동 억제)

  • Yun, Sungchan;Kim, Tae Kwon;Lim, Hee Chang;Kang, Kwan Hyoung;Lim, Geunbae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.7
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    • pp.695-701
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    • 2013
  • The suppression of a thermocapillary flow (Marangoni flow) by a nonionic surfactant is experimentally investigated for evaporating pure water droplets on hydrophobic substrates. The experiment shows that as the initial concentration of the surfactant increases, the velocity and lifetime of the flow monotonically decrease. The result confirms the no-slip boundary condition at a liquid-air interface, which is explained on the basis of the previous model regarding the effect of surfactants on the no-slip condition. Interestingly, at an initial concentration much less than a critical value, it is found that depinning of the contact line occurs during the early stage of evaporation, which is ascribed to a reduction in the contact angle hysteresis owing to the presence of the Marangoni flow.

THE COMPARATIVE STUDY OF THERMAL INDUCTIVE EFFECT BETWEEN INTERNAL CONNECTION AND EXTERNAL CONNECTION IMPLANT IN ABUTMENT PREPARATION (구강내에서 임플랜트 지대주 형성 시 내부연결방식과 외부연결방식간의 열전달 효과 비교)

  • Huh, Jung-Bo;Ko, Sok-Min
    • The Journal of Korean Academy of Prosthodontics
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    • v.45 no.1
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    • pp.60-70
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    • 2007
  • Statement of problem: The cement-type abutment would be needed for the reduction of its body in order to correct the axis and to assure occlusal clearance. In the case of intraoral preparation, there is a potential risk that generated heat could be transmitted into the bone-implant interface, where it can cause deterioration of tissues around the implant and failed osseointegration. Purpose: The purpose of this study was to assess the difference of the heat transmitting effect on external and internal connection implant types under various conditions. Material and method: For evaluating the effects of alternating temperature, the thermocoupling wires were attached on 3 areas of the implant fixture surface corresponding to the cervical, middle, and apex. The abutments were removed 1mm in depth horizontally with diamond burs and were polished for 30 seconds at low speed with silicone points using pressure as applied in routine clinical practice. Obtained data were analyzed using Mann-Whitney rank-sum test and Wilcoxon / Kruskal-Wallis Tests. Result: Increased temperature on bone-implant interface was evident without air-water spray coolant both at high speed reduction and low speed polishing (p<.05). But, the difference between connection types was not shown. Conclusion: The reduction procedure of abutment without using proper coolant leads to serious damage of oral tissues around the implant irrespective of external and internal connection type.