• Korean Chemical Engineering Research
• /
• v.43 no.2
• /
• pp.324-329
• /
• 2005

The efficiency of reducing nitric oxide using urea combined with alkali salt additives is reported in this study. The inlet concentration of NO is 500 ppm with air flow rates of 3 and 5 L/min. Reduction of NO was studied from 650 to $1,050^{\circ}C$ with urea concentrations of 0.3 to 1 mol/L. The efficiency for the reduction of NO increased by 44% when urea is added alone. A further increase in efficiency was observed in the presence of NaOH as additive in fact, the efficiency was increased by more than 25% and 75% when 0.5 mol/L and 1 mol/L NaOH were added with the urea. The efficiency for the reduction of NO increased with all additives, but descended in the order NaOH, $Na_2CO_3$, $NaNO_3$, HCOONa, and CHCOONa. The maximum efficiency of NaOH and $Na_2NO_3$ are 74% and 73%, respectively. All these additives did not alter the comparatively wide operating temperature window for reducing NO. However, sodium compounds do not shift the maximum NO concentration towards lower temperatures when the NO removal activity enhances.

• Korean Chemical Engineering Research
• /
• v.46 no.4
• /
• pp.806-812
• /
• 2008

The ammonia decomposition reaction has been of increasing interest as a means of treating ammonia in flue gas in the presence of precious metal catalyst. Various catalysts, $Pt-Rh/Al_2O_3$, $Pt-Rh/TiO_2$, $Pt-Rh/ZrO_2$, $Pt-Pd/Al_2O_3$, $Pd-Rh/Al_2O_3$, $Pd-Rh/TiO_2$, $Pd-Rh/ZrO_2$, $Pt-Pd-Rh/Al_2O_3$, $Pd/Ga-Al_2O_3$, $Rh/Ga-Al_2O_3$, and Ru/Ga-$Al_2O_3$, were synthesized by using excess wet impregnation method. Using a homemade 1/4" reactor at $10,000{\sim}50,000hr^{-1}$ of space velocity in the presence of precious metal catalyst ammonia decomposition reactions were carried out to investigate the catalyst activity. The inlet ammonia concentration was maintained at 2,000 ppm, with an air balance. Both $T_{50}$ and $T_{90}$, defined as the temperatures where 50% and 90% of ammonia, respectively, are converted, decreased significantly when alumina-supported catalysts were applied. In terms of catalytic performance on the ammonia conversion in the presence of hydrogen sulfide, $Pt-Rh/Al_2O_3$ catalyst showed no effect on the poisoning caused by hydrogen sulfide. These results indicate that platinum-rhodium bimetallic catalyst is a useful catalyst for ammonia decomposition.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.2 no.3
• /
• pp.99-106
• /
• 1998

The performance of the turbofan engine, a medium scale civil aircraft which has been developing in Rep. of Korea, was analyzed and the control scheme for optimization the performance was studied. The dynamic and real-time linear simulation was performed in the previous study The result was that the fuel scedule of the step increase overshoot the limit temperature(3105 $^{\cire}R$) of the high pressure turbine and got small surge margine of the high pressure compressor. Therefore a control scheme such as the LQR(Linear Quadratic Regulator) was applied to optimizing the performance in this studies. The linear model was expected for designing controller and the real time linear model was developed to be closed to nonlinear simulation results. The system matrices were derived from sampling operating points in the scheduled range and then the least square method was applied to the interpolation between these sampling points, where each element of matrices was a function of the rotor speed. The control variables were the fuel flow and the low pressure compressor bleed air. The controlled linear model eliminated the inlet temperature overshoot of the high pressure turbine and obtained maximum surge margins within 0.55. The SFC was stabilized in the range of 0.355 to 0.43.

• Korean Chemical Engineering Research
• /
• v.48 no.2
• /
• pp.268-274
• /
• 2010

Emission of heavy metals as hazardous air pollutants has been focused with tightening regulatory limits due to their hazardousness. Measurements and characteristic investigations of heavy metals emitted from a commercial power plant burning anthracite coal have been carried out. The plant consists of a circulating fluidized bed combustor, a cyclone, a boiler and an electrostatic precipitator(ESP) in series. Dust and gaseous samples were collected to measure main heavy metals including gaseous mercury before ESP and at stack. Dust emissions as total particulate matter (TPM), PM-10 and PM-2.5 at inlet of ESP were very high with 23,274, 9,555 and $7,790mg/Sm^3$, respectively, as expected, which is much higher than those from pulverized coal power plants. However TPM at stack was less than $0.16mg/Sm^3$, due to high dust removal efficiency by ESP. Similarly heavy metals emission showed high collection efficiency across ESP. From particle size distribution and metal enrichment in sizes, several metal concentrations could be correlated with particle size showing more enrichment in smaller particles. Mercury unlike other solid metals behaved differently by emitting as gaseous state due to high volatility. Removal of mercury was quite less than other metals due to it's volatility, which was 68% only. Across ESP, speciation change of mercury from elemental to oxidized was clearly shown so that elemental mercury was half of total mercury at stack unlike other coal power plants which equipped wet a scrubber.

• 한국해양학회지
• /
• v.26 no.3
• /
• pp.204-222
• /
• 1991

The annual cycles of plant major nutrients and dissolved oxygen in a nutrients-rich semi-enclosed coastal inlet, chinhae Bay, of the southern coast of the Korean Peninsula are first presented. The water column of the bay is stratified during summer (April-late September) and well0mixed during winter (October-March). During the summer stratification period, dissolved oxygen contents exceed 400uM in the surface but diminish to less than 50uM in the near bottom waters, which often results in an anoxic environment in the inner part of Chinhae Bay. After the breakdown of the stratification in October, dissolved oxygen concentration remains undersaturated until February. The evidence of allochthonous input of N-nutrients throughout the year is readily seen in the water column: however. crude budget calculations show that the nutrients are efficiently utilized within the bay ecosystem, and that export of the nutrients from the bay to the shelf must be negligible. There is no sign of the enrichment of the nutrients in the water column. The eutrophication phenomenon sensu stricto is not observed in chinhae Bay. Using the standing stock of dissolved oxygen and estimation of the oxygen fluxes across the air-sea boundary, a benthic oxygen respiration rate during winter is estimated conservatively at 21-24 mmol Cm/SUP -2/d/SUP -1/. this oxygen respiration rate accounts for about 20% of the total phytoplankton production in winter.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.20 no.2
• /
• pp.1-6
• /
• 2019

The objective of this study was to investigate performance characteristics of thermal management system(TMS) in a fuel cell electric vehicle with 100kW Fuel Cell(FC) system. In order to build up analytic modelling for TMS, each component was installed and tested under various operating conditions, such as water pump, radiator, 3-Way valve, COD heater, and FC stack etc. and as the results of them, correlations reflecting component's characteristics with flow rate, air velocity were developed. Developed analytic modelling was carried out under various operating conditions on the road. To verify modelling's accuracy, after prediction for optimum coolant flow rate was fulfilled under certain operating conditions, such as FC system, water pump speed, opening of 3-way valve, and pipe resistance, analytic and experimental values were compared and good agreement was shown. In order to predict cold-start operating performance for analytic modelling, coolant temperature variation was analyzed with $-20^{\circ}C$ ambient temperature and duration was predicted to rise in optimum temperature for FC. Because there is appropriate temperature difference between inlet and outlet of FC stack to operate FC system properly, related analysis was performed with respect to power consumption for TMS and heat rejection rate and performance map was depicted along with FC operating conditions.

• Plant Journal
• /
• v.14 no.4
• /
• pp.39-47
• /
• 2018

In this research, when the output of the standard coal-fired thermal power plant operating continuously at the rated output of 500 MW is changed to operate at 300 to 500 MW, the amount of sulfur oxide produced and the amount of sulfur oxide in the absorption tower of desulfurization equipment and proposed an extra liquid to gas ratio improvement inversely proportional to the output. In order to calibrate the combustion efficiency at low power, the ratio of sulfur oxides relative to the amount of combustion gas is increased as the excess air ratio is increased. When the concentration of sulfur oxide at the inlet of the desulfurization absorber was changed from 300 to 500 ppm along with the output fluctuation. The liquid to gas ratio of limestone slurry and combustion gas was changed from 10.99 to 16.27. Therefore, if the concentration of sulfur oxides with output of 300 MW is x, The following correlation equation is recommended for the minimum required flow rate of slurry for the reduction of surplus energy due to the increase of the liquid weight at low load. $y1[m^3/sec]=0.11x+3.74$

• The Journal of the Acoustical Society of Korea
• /
• v.40 no.6
• /
• pp.555-565
• /
• 2021

The goal of this study is to improve flow and noise performances of existing backward-curved blade centrifugal fan system used for circulating cold air in a refrigerator freezer by optimally designing airfoil shape. The unique characteristics of the system is to drive cold airflow with two volute tongues in combination with duct system in a back side of a refrigerator without scroll housing generally used in a typical centrifugal fan system. First, flow and noise performances of existing fan system were evaluated experimentally. A P-Q curve was obtained using a fan performance tester in the flow experiment, and noise spectrum was measured in an anechoic chamber in the noise experiment. Then, flow characteristics were numerically analyzed by solving the three-dimensional unsteady Navier-Stokes equations and noise analysis was performed by solving the Ffowcs Williams and Hawkins equation with input from the flow simulation results. The validity of numerical results was confirmed by comparing them with the measured ones. Based on the verified numerical method, blade inlet and outlet angles were optimized for maximum flow rate using the two-factor central composite design of the response surface method. Finally, the flow and noise performances of a prototype manufactured with the optimum design were experimentally evaluated, which showed the improvement in flow and noise performance.

• Korean Chemical Engineering Research
• /
• v.52 no.5
• /
• pp.688-693
• /
• 2014

For investigating NO reduction activity of an catalytic filter, the catalytic performance was measured under the presence of $SO_2$ and $H_2O$, respectively or simultaneously in the simulation gas composed of NO, $NH_3$, and air. The catalytic filter was prepared by coating $V_2O_5-WO_3/TiO_2$ catalyst on the pore surface of SiC filter element of which the superior performance for the particulate removal was well known. At the temperature below $260^{\circ}C$, the catalytic activities were enormously decreased under the presence of $SO_2$ and $H_2O$, respectively or simultaneously, compared with those under the cases of the absence of $SO_2$ and $H_2O$. However, the presence of $SO_2$ promoted the performance of the catalytic filter above $320^{\circ}C$ with showing the NO conversion better than 99.8% for the NO inlet concentration of 500 ppm and at the face velocity of 2 cm/s. In particular, the presence of water showed high NO conversion higher than 99% up to high temperature of $380^{\circ}C$. This effect of water was explained by the reason that it retarded the ammonia oxidation which is the main step into the formation of $N_2O$. The initial NO reduction activity of the catalytic filter maintained for the duration of 100 hours in the presence of $SO_2$ and $H_2O$. Therefore, it was concluded that the catalytic filter was promisingly useful for the industrial NOx reduction catalyst in order to treat the particulate and NO simultaneously.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.4 no.4
• /
• pp.79-93
• /
• 1984

The dissolved air flotation(DAF) has been shown to be efficient process for the removal of algae ftom water. The efficiency of DAF can be affected by the volume ratio of pressurized liquid to sample, the pressure pressurized liquid, the contact time, the appropriate coagulant and its amount, the water temperature, the turbulence of reactor, the bubble size and rising velocity etc. The purpose of this paper is to compare the practical bubble rising velocity with the theoretical one, to investigate the adhesion phenomenon of bubbles and floc, and the influence of bubble size and velocity upon the process. The results through theoretical review and experimental investigation are as follows: Ives' equation is more suitable than Stokes' equation in computation of the bubble rising velocity. The collection of bubble and algae floc is convective collection type and resulted from absorption than adhesion or collision. The treatment efficiency is excellent when the bubble sizes are smaller than $l00{\mu}m$, and the turbulence of reactor is small. In the optimum condition of continuous type DAF the volume ratio of pressurized liquid to sample is 15%, the contact time in reactor is 15 minutes, the pressure of pressurized liquid is $4kg/cm^2$ and the distance from jet needle to inlet is 30cm.