• 제목/요약/키워드: Ag electrode

검색결과 652건 처리시간 0.048초

Effect of Bottom Electrode on Resistive Switching Voltages in Ag-Based Electrochemical Metallization Memory Device

  • Kim, Sungjun;Cho, Seongjae;Park, Byung-Gook
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제16권2호
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    • pp.147-152
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    • 2016
  • In this study, we fabricated Ag-based electrochemical metallization memory devices which is also called conductive-bridge random-access memory (CBRAM) in order to investigate the resistive switching behavior depending on the bottom electrode (BE). RRAM cells of two different layer configurations having $Ag/Si_3N_4/TiN$ and $Ag/Si_3N_4/p^+$ Si are studied for metal-insulator-metal (MIM) and metal-insulator-silicon (MIS) structures, respectively. Switching voltages including forming/set/reset are lower for MIM than for MIS structure. It is found that the workfunction different affects the performances.

순수한 Ag 내부전극을 사용한 PZW-PMN-PZT 저손실 적층 액츄에이터의 적층수에 따른 압전 특성 (Piezoelectric Properties of PZW-PMN-PZT Low Loss Multilayer Actuator according to the Number of Multilayer using Pure Ag Internal Electrode)

  • 류주현;이갑수;이일하
    • 한국전기전자재료학회논문지
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    • 제21권6호
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    • pp.524-529
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    • 2008
  • In this paper, in order to develop low loss multilayer actuator, piezoelectric properties of PZW-PMN-PZT multilayer actuator sintered at $900^{\circ}C$ low temperature were investigated according to the number of multilayer. The multilayer actuator was fabricated using tape casting method and used pure Ag internal electrode. The density above $8.0\;g/cm^3$ was obtained at all specimens. With increasing number of multilayer, effective electromechanical coupling factor($k_{eff}$) was increased. $k_{eff}$ of multilayer actuator shows the maximum value of 0.283 at 11 layers actuator. However, effective mechanical quality factor(Qm') was decreased according to the increase of number of multilayer. The Qm' of multilayer actuator showed the maximum value of 920 at 5 layers actuator.

$SrTiO_3$ 세라믹 전극에 의한 광전기 화학변환 (Photoelectrochemical Converision with $SrTiO_3$ Ceramic Electrodes)

  • 윤기현;김태희
    • 한국세라믹학회지
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    • 제22권3호
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    • pp.19-24
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    • 1985
  • The phtoelectrochemical porperties of $Nb_2O_5$, $Sb_2O_3$ and $V_2O_5$ doped and pure $SrTiO_3$ ceramic electodes were investigated. Shapes of I-V and I-λ characteristics of the pure $SrTiO_3$ ceramic electrode are similar to those of SrTiO3 single crystal electorde ; the anodic current strats at -0.9V (vs. Ag/AgCI) in 1 N-NaOH aqueous solution and the photoresponse appears at a wavelength of about 390nm and the quantum efficiency is about 3.5% at wavelength of 390nm under 0.5V vs. Ag/AgCl. Photocurrents of $Nb_2O_5$, $Sb_2O_3$ and $V_2O_5$ doped electrodes and $V_2O_5$ doped ceramic electrode appears at wavelength of 390nm and 500nm respectively.

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수은 막전극을 이용한 수용액 중 과염소산이온의 전기화학적 환원 (Electrochemical Reduction of Perchlorate Using Mercury Film Electrode)

  • 명노승;김은영;지형우;금나래;이인숙;팽기정
    • 전기화학회지
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    • 제19권3호
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    • pp.95-100
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    • 2016
  • 과염소산이온의 전기화학적 분해에 관한 연구가 진행되었다. 전기화학적 방법은 비교적 단순한 전처리 방법으로 가능하다. 하지만 전기화학적 방법은 과염소산이온이 분해되는 전압을 가해주었을 때 수소발생으로 인한 방해가 발생하기 때문에 사용하는 전극의 수소 과전압이 큰 것을 사용하여 수소발생을 줄이는 것이 요구되어 왔다. 본 연구에서는 수소 과전압이 큰 수은박막전극을 작업 전극으로 사용하였다. Ag / AgCl (sat. NaCl) 전극을 기준전극으로 사용하였으며 Pt를 상대전극으로 사용하였다. 수은박막전극은 순환 전압-전류법(Cyclic voltammetry, CV)으로 제작하였는데 과염소산 용액에서의 CV를 고려하여 수은박막전극의 안정성을 위해 10분 동안 전착시켰다. 과염소산이온의 환원전위는 CV 방법에 의해 설정되었고, 분해실험은 시간대 전류법 (Chronoamperometry, CA)로 시행하였다. 과염소산이온의 분해율 확인을 위해 이온 크로마토그래피(Ion chromatography, IC)를 사용하였다.

TiO2/ZnS/Ag/ZnS/TiO2 다층막의 PDP 필터용 전극 특성 (Transparent Electrode Performance of TiO2/ZnS/Ag/ZnS/TiO2 Multi-Layer for PDP Filter)

  • 오원석;이서희;장건익;박성완
    • 한국전기전자재료학회논문지
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    • 제23권9호
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    • pp.681-684
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    • 2010
  • The $TiO_2$/ZnS/Ag/ZnS/$TiO_2$ multilayered structure for the transparent electrodes in plasma display panel was designed by essential macleod program (EMP) and the multilayered film was deposited on a glass substrate by direct-current (DC)/radio-frequency (RF) magnetron sputtering system. During film deposition process, the Ag layer in $TiO_2$/Ag/$TiO_2$ structure became oxidized and the filter characteristic was degraded easily. In this study, ZnS layer was adopted as a diffusion blocking layer between $TiO_2$ and Ag to prevent the oxidation of Ag layer efficiently in $TiO_2$/ZnS/Ag/ZnS/$TiO_2$ structure. Based on the AES depth profiling analysis, the Ag layer was effectively protected by the ZnS layer as compared with the $TiO_2$/Ag/$TiO_2$ multilayered films without ZnS as an antioxidant layer. The 3 times stacked $TiO_2$/ZnS/Ag/ZnS/$TiO_2$ films have low sheet resistance of $1.22{\Omega}/{\square}$ and luminous transmittance was as high as 62% in the visible ranges.

Polypyrrole-Glucose Oxidase 효소전극의 전기화학적 특서: 1. 효소전극의 산화환원에 대한 Glucose Oxidase의 영향 (Electrochemical Properties of Polypyrrole-Glucose Oxidase Enzyme Electrode: 1. An Influence of Glucose Oxidase on Redox Behavior of Enzyme Electrode)

  • 김현철;구할본;사공건
    • 한국전기전자재료학회논문지
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    • 제13권6호
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    • pp.520-525
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    • 2000
  • Glucose oxidase was immobilized in polypyrrole by electrosynthesis. The enzyme had an influence on the redox properties of a complex enzyme electrode. In the cyclic voltammograms of the enazyme electrode new peaks were appeared at the potential around 0.7V vs. Ag/AgCl in additional to the typical peaks for polypyrrole. The more immobilized the stronger the peaks became. During the cycling the pH of electrolyte solution was decreased to about 4.4 The reason for that is to be the proton released from the carboxyl in the glucose oxidase in order to keep on a charge neutrality of the oxidized enzyme. This fact suggests that the new peaks in the voltammograms are caused by the redox of glucose oxidase. In the AC impedance spectrum analysis of the electrode the diffusion of electrolyte anion was limited because of chained structure of the enzyme. The faradic impedance was large since the glucose oxidase is an insulator. Therefore when glucose oxidase is entrapped the enzyme should be limited in amount. Because the growth of the polypyrrole is accompanied both charge transfer and mass transport. For the traditional electrosynthesis that means amount of enzyme present in the electrode is limited to as much as film growable.

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