• Title/Summary/Keyword: Ag$_2$O

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The Effect of the Sn contents on Rapidly Solidified Ag-X%Zn Electric Contact Materials (급속응고한 Ag-X%Zn계 전기접점재료에 미치는 Sn함량의 영향)

  • Kim, Jong-Kyu;Jang, Dae-Jung;Ju, Kwang-Il;Lee, Eun-Ho;Um, Seung-Yeul;Nam, Tae-Woon
    • Journal of Korea Foundry Society
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    • v.28 no.4
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    • pp.184-189
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    • 2008
  • Ag-Cd alloy has been widely used as an electrical contact material, since Ag-Cd alloy has a good wear resistance and stable contact resistance. But nowadays Ag-Cd alloy is not considered as electrical contact material any more due to detrimental effect on environments. Currently, active researches are being performed on ($Ag-SnO_2$ and $Ag-SnO_{2}-In_{2}O_{3}$) as an alternative solution which can fix the remaining environmental problems. However, $In_{2}O_{3}$ is relatively expensive and Ag-Sn alloy has low wear resistance. Our recent research results show that Ag-X%Zn-Y%Sn has similar physical and chemical properties. In the present study, so we tried to change and to optimize the Zn oxide content to over 6 wt% and Sn oxide content with 0.5, 1.0, 1.5 wt%. Results obtained from the experiments on the Ag-X%ZnO-Y%$SnO_2$ are discussed.

Synthesis and Photocatalytic Activity of Ag Spot-coated TiO2-SrO Composite Powders (나노 Ag spot-coated TiO2-SrO 복합분체의 합성과 광촉매 활성 평가)

  • Han, Jae-Kil;Kim, Hyeong-Chul;Hong, Won-Seok;Choi, Sung-Chang
    • Korean Journal of Materials Research
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    • v.18 no.7
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    • pp.389-393
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    • 2008
  • Nano-sized $TiO_2$-60 wt% SrO composite powders were synthesized by a sol-gel method using titanium isopropoxide and $Sr(OH)_2\;{\cdot}\;8H_2O$ as precursors. 3, -5, -7 wt%Ag spot-coated $TiO_2$-60 wt% SrO composite powders were synthesized by a Ag electroless deposition method using $TiO_2$-60 wt% SrO composite powders calcined at $1050^{\circ}C$, which mainly exhibited the $SrTiO_3$phase. However, a small number of rutile $TiO_2$, $Sr_2TiO_4$ and $SrO_2$ phases were also detected. In the Ag spot-coated powders synthesized by electroless deposition, nano-sized particles about 5-25 nm in diameter adhered to the $TiO_2$-60 wt% SrO composite powders. The photocatalytic activity of Ag spot-coated $TiO_2$-SrO and $TiO_2$-SrO composite powders for degradation of phenol showed that all of $TiO_2$-SrO composite powders were highly active under UV light irradiation. 7 wt%Ag spot-coated $TiO_2$-60wt.%SrO composite powders had a relatively higher photocatalytic activity than did $TiO_2$-SrO composite powders under visible light.

Ag-functionalized SnO2 Nanowires Based Sensor for NO2 Detection at Low Operating Temperature (NO2 감응을 위한 Ag 금속입자가 기능화된 SnO2 나노선 기반 저온동작 센서)

  • Choi, Myung Sik;Kim, Min Young;Ahn, Jihye;Choi, Seung Joon;Lee, Kyu Hyoung
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.2
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    • pp.11-17
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    • 2020
  • In this study, Ag-functionalized SnO2 nanowires are presented for NO2 gas sensitive sensors at low temperatures (50℃). SnO2 nanowires were synthesized using vapor-liquid-solid method, and Ag metal particles were functionalized on the surface of SnO2 nanowires using flame chemical vapor deposition method. As a result of the sensing test about Ag-functionalized SnO2 nanowires based sensor, the response (Rg/Ra) to 10 ppm NO2 was 1.252 at 50℃. We believe that metal-functionalizing is a one of good way to increase the feasibility about semiconductor gas sensor.

Dielectric and Pyroelectric Properties for 0.65PbMg1/3Ta2/3)O3-0.35PbTiO3 Solid Solution Modified with Ag2O (Ag2O가 첨가된 0.65PbMg1/3Ta2/3)O3-0.35PbTiO3 고용체의 유전, 초전 특성)

  • Kim, G.B.
    • Journal of the Korean Vacuum Society
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    • v.17 no.5
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    • pp.442-447
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    • 2008
  • Ferroelectric samples of the 0.65Pb$(Mg_{1/3}Ta_{2/3})O_3-0.35PbTiO_3$ modified with $Ag_2O$ were prepared by sintering at $1200^{\circ}C$ for 4 h. The fractured surface of sintered pellets were examined by scanning electron microscopy(SEM). The dielectric constant, loss, and pyroelectric coefficient of the ceramics samples were determined. The dielectric and pyroelectric properties could be improved with the addition of small amount of $Ag_2O$ up to 0.2 mol%. The dielectric and pyroelectirc peak temperatures are continuously shifted to lower temperature with addition of small amounts of $Ag_2O$.

Effect of the Alloying Elements in Ag-Cu-Zr-X Brazing Alloy on the Microstructure and the Bond Strength of $Al_2O_3$/Ni-Cr Steel Brazed Joint (알루미나/니켈크롬강 접합체의 미세조직 및 접합강도에 미치는 Ag-Cu-Zr-X 브레이징 합금성분의 영향)

  • Kim, Jong-Heon;Yoo, Yeon-Chul
    • Transactions of Materials Processing
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    • v.7 no.5
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    • pp.465-473
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    • 1998
  • The effect of alloying elements of Ag-Cu-Zr-X brazing alloy on the microstructure and the bond strength of $Al_2O_3/Ni-Cr$ brazed steel joint was investigated. The reaction layer, $ZrO_2$ (a=5.146 ${\AA}$ , b=5.213 ${\AA}$ , c=5.311 ${\AA}$ )was formed at the interface of $Al_2O_3/Ni-Cr$ steel joint by the redox reaction between alumina and Zr. The addition of An and Al to the Ag-Cu-Zr brazing alloy gave rise to changes in the thickness of the reaction product layer and the morphology of the brazement. Sn caused the segregation of Zr was decreased b Al the $ZrO_2$ layer formed at the Ag-Cu-Zr-Al alloy was thinner than that of $ZrO_2$ formed at the Ag-Cu-Zr-An alloy. The fracture shear strength was strongly dependent on the microstructure of the brazement. Brazing with Ag-Cu-Zr-Sn alloy resulted in a better bond strength than with Ag-Cu-Zr or Ag-Cu-Zr-Al alloy.

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Synthesis of Ag/TiO2 Core/Shell Nanoparticles with Antibacterial Properties

  • Lin, Yue;Qiqiang, Wang;Xiaoming, Zhang;Zhouping, Wang;Wenshui, Xia;Yuming, Dong
    • Bulletin of the Korean Chemical Society
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    • v.32 no.8
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    • pp.2607-2610
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    • 2011
  • Monodispersed Ag/$TiO_2$ core/shell nanoparticles were synthesized in solution via colloid-seeded deposition process using Ag nanoparticles as colloid seeds and $Ti(SO_4)_2$ as Ti-source respectively. Silver nitrate was reduced to Ag nanoparticles with $N_2H_4{\cdot}H_2O$ in the presence of CTAB as stabilizing agent. The titania sols hydrolyzed by the $Ti(SO_4)_2$ solution deposited on the surface of Ag nanoparticles to form the Ag/$TiO_2$ core/shell nanoparticles. Inductively coupled plasma atomic emission spectrometry (ICP-AES) showed low amount of Ag ion leaching from the Ag/$TiO_2$ core/shell nanoparticles. The Ag/$TiO_2$ core/shell nanoparticles indicated excellent antibacterial effects against Escherichia coli and maintained long-term antibacterial property.

Preparation of Ag2Se-Graphene-TiO2 Nanocomposite and its Photocatalytic Degradation (Rh B)

  • Ali, Asghar;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.54 no.5
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    • pp.388-394
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    • 2017
  • Here, utilizing rhodamine B (RhB) as standard color dye, we examined the photo degradation proficiency of $Ag_2Se-Graphene-TiO_2$ nanocomposites under visible light irradiation; samples were prepared by ultrasonication techniques and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopic investigation and UV-Vis absorbance spectra examination. Our outcomes demonstrate that the $Ag_2Se-G-TiO_2$ nanocomposite showed significant photodegradation efficiency as compared with those of $TiO_2-G$ and $Ag_2Se-G$, with around 85.2% of Rhodamine B (RhB) degraded after 180 min. It is concluded that the $Ag_2Se-G-TiO_2$ nanocomposite is a competent candidate for dye pollutants.

The Influence of Temperature on the Recovery Reaction of Silver Based on the Pourbaix Diagram (Pourbaix Diagram에 의거한 은(銀)의 회수반응(回收反應)에 미치는 온도영향(溫度影響))

  • Won, Yu-Ra;Kim, Dong-Su
    • Resources Recycling
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    • v.21 no.6
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    • pp.74-81
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    • 2012
  • The Influence of temperature on the recovery reaction of silver in aqueous solution was investigated based on Pourbaix diagram constructed by thermodynamic calculation at different temperatures. It was observed that the stability of water is more strongly affected by pH variation and the stable region of ${Ag^+}_{(aq)}$ is diminished at higher temperature. It was shown that the recovery of $Ag_{(aq)}$ in the forms of $Ag_{(s)}$ and $Ag_2O_{3(s)}$ is more advantageous thermodynamically at lower temperature, however, the recovery of $Ag_{(aq)}$ in the forms of $Ag_2O_{(s)}$$Ag_2O_{2(s)}$ is more advantageous as temperature increases. The rise of temperature is considered to demote the recovery of silver thermodynamically in strong acidic condition ($pH{\leq}2$), but more silver is regarded to be recovered with temperature above pH 2. Finally, The recovery of silver in the elemental state is shown to be more sensitively influenced by temperature variation compared with the recovery of silver in its oxide form.

Ag Doping Effect on Li[Ni0.2Li0.2Mn0.6]O2 Cathode Material (Li[Ni0.2Li0.2Mn0.6]O2 양극물질의 Ag 도핑(Doping) 효과)

  • Ryu, Jea-Hyeok;Kim, Seuk-Buom;Park, Yong-Joon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.3
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    • pp.249-254
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    • 2008
  • Ag doping effect on $Li[Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ cathode material was studied. Specially, we focused on rate performance of Ag doped samples. The $Li[Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ powder was prepared by simple combustion method and the Ag was doped using $AgNO_3$ during gelation process. Based on X-ray diffraction analysis, there was no structural change by Ag doping, but the 'metallic' form of Ag was included in the doped powder. Both bare and Ag 1 wt.% doped sample showed similar discharge capacity of 242 mAh/g at 0.2C rate. However, as the increase of charge-discharge rate to 3C, Ag 1 wt.% doped sample showed higher discharge capacity (172 mAh/g) and better cyclic performance than those of bare sample. The discharge capacity of Ag 5 wt.% doped sample was relatively low at all rate condition. However it displayed better rate performance than other samples.

Recovery of An, Ag, and Ni from PCB Wastes by CaF2-containing Slag (형우(螢右) 함유(含有) 슬래그 노이(盧理)를 통한 PCB 스크랩으로부터 Au, Ag, Ni의 회수(回收)에 관한 연구(班究))

  • Park, Joo-Hyun
    • Resources Recycling
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    • v.20 no.4
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    • pp.58-64
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    • 2011
  • Recovery of novel metals such as Au, Ag and Ni from wastes PCB was investigated by slag treatments. The CaO-$Al_2O_3$(-$SiO_2$) and CaO-$SiO_2$-$CaF_2$ slags were employed in the present study. The PCB/Cu ratio is recommended to be lower than unity. The use of CaO-$SiO_2$-$CaF_2$ slag provided the more higher yield of Au, Ag and Ni than the CaO-$Al_2O_3$(-$SiO_2$) slag did, which was mainly due to the lower melting point and the viscosity of $CaF_2$-containing slag. The terminal descending velocity of metal droplets in the slag phase increased with decreasing slag viscosity.