• Title/Summary/Keyword: Advanced Composite Materials

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Fabrication of Nanocrystalline Co-Al2O3 from Mechanically Synthesized Powders by Rapid Sintering (기계적으로 합성한 분말로부터 급속 소결에 의한 나노 구조의 Co-Al2O3 복합재료 제조)

  • Park, Na-Ra;Shon, In-Jin
    • Korean Journal of Metals and Materials
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    • v.50 no.12
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    • pp.961-966
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    • 2012
  • Nano-sized Co and $Al_2O_3$ powders were successfully synthesized from $3/4Co_3O_4$ and 2Al by high-energy ball milling. A dense nanocrystalline $2.25Co-Al_2O_3$ composite was consolidated from mechanically synthesized powders by the pulsed current activated sintering (PCAS) method within 2 min. Consolidation was accomplished under the combined effects of a pulsed current and mechanical pressure. A dense $2.25Co-Al_2O_3$ with relative density of up to 95% was produced under simultaneous application of a 80 MPa pressure and a pulsed current of 2800 A. The fracture toughness and hardness of the $2.25Co-Al_2O_3$ composite were $8MPa{\cdot}m^{1/2}$, $870kg/mm^2$, respectively.

Fabrication of Hybrid NiO/ACF/TiO2 Composites and Their Photocatalytic Activity Under Visible Light

  • Meng, Ze-Da;Han, Sang-Bum;Kim, Doo-Hwan;Park, Chong-Yeon;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.48 no.3
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    • pp.211-216
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    • 2011
  • Nickel oxide-doped ACF and $TiO_2$ composites (NiO/ACF/$TiO_2$) were prepared by a sol-gel method. The composite obtained was characterized by BET surface area measurements, X-ray diffraction, transmission electron microscopy and energy dispersive X-ray analysis. A methylene blue (MB) solution under visible light irradiation was used to determine their photocatalytic activity. Excellent photocatalytic degradation of the MB solution was observed using the $TiO_2$, Ti-ACF and NiO/ACF/$TiO_2$ composite under visible light.

Effect of Process Condition on Tensile Properties of Carbon Fiber

  • Lee, Sung-Ho;Kim, Ji-Hoon;Ku, Bon-Cheol;Kim, Jun-Kyong;Chung, Yong-Sik
    • Carbon letters
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    • v.12 no.1
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    • pp.26-30
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    • 2011
  • For polyacrylonitrile (PAN) based carbon fiber (CF) process, we developed a lab scale wet spinning line and a continuous tailor-made stabilization system with ten columns for controlling temperature profile. PAN precursor was spun with a different spinning rate. PAN spun fibers were stabilized with a total duration of 45 to 110 min at a given temperature profile. Furthermore, a stabilization temperature profile was varied with the last column temperature from 230 to $275^{\circ}C$. Stabilized fibers were carbonized in nitrogen atmosphere at $1200^{\circ}C$ in a furnace. Morphologies of spun and CFs were observed using optical and scanning electron microscopy, respectively. Tensile properties of resulting CFs were measured. The results revealed that process conditions such as spinning rate, stabilization time, and temperature profile affect microstructure and tensile properties of CFs significantly.

Manufacturing and characteristics of PAN-based composite carbon fibers containing cellulose particles

  • Yang, Jee-Woo;Jin, Da Young;Lee, Ji Eun;Lee, Seung Goo;Park, Won Ho
    • Carbon letters
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    • v.16 no.3
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    • pp.203-210
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    • 2015
  • This study fabricated low thermal conductive polyacrylonitrile (PAN)-based carbon fibers containing cellulose particles while maintaining their mechanical properties. The high thermal conductivity of carbon fibers limits their application as a high temperature insulator in various systems such as an insulator for propulsion parts in aerospace or missile systems. By controlling process parameters such as the heat treatment temperature of the cellulose particles and the amount of cellulose added, the thermal and mechanical properties of the PAN-based carbon fibers were investigated. The results show that it is possible to manufacture composite carbon fibers with low thermal conductivity. That is, thermal conductivities were reduced by the cellulose particles in the PAN based carbon fibers while at the same time, the tensile strength loss was minimized, and the tensile modulus increased.

Effect of SiC Nanorods on Mechanical and Thermal Properties of SiC Composites Fabricated by Chemical Vapor Infiltration

  • Lee, Ho Wook;Kim, Daejong;Lee, Hyeon-Geun;Kim, Weon-Ju;Yoon, Soon Gil;Park, Ji Yeon
    • Journal of the Korean Ceramic Society
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    • v.56 no.5
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    • pp.453-460
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    • 2019
  • To reduce residual pores of composites and obtain a dense matrix, SiCf/SiC composites were fabricated by chemical vapor deposition (CVI) using SiC nanorods. SiC nanorods were uniformly grown in the thickness direction of the composite preform when the reaction pressure was maintained at 50 torr or 100 torr at 1,100℃. When SiC nanorods were grown, the densities of the composites were 2.57 ~ 2.65 g/㎤, higher than that of the composite density of 2.47 g/㎤ for non-growing of SiC nanorods under the same conditions; grown nanorods had uniform microstructure with reduced large pores between bundles. The flexural strength, fracture toughness and thermal conductivity (room temperature) of the SiC nanorod grown composites were 412 ~ 432 MPa, 13.79 ~ 14.94 MPa·m1/2 and 11.51 ~11.89 W/m·K, which were increases of 30%, 25%, and 25% compared to the untreated composite, respectively.

Coating of Cobalt Over Tungsten Carbide Powder by Wet Chemical Reduction Method

  • Hong, Hyun-Seon;Yoon, Jin-Ho
    • Journal of Powder Materials
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    • v.21 no.2
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    • pp.93-96
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    • 2014
  • Cobalt coated tungsten carbide-cobalt composite powder has been prepared through wet chemical reduction method. The cobalt sulfate solution was converted to the cobalt chloride then the cobalt hydroxide. The tungsten carbide powders were added in to the cobalt hydroxide, the cobalt hydroxide was reduced and coated over tungsten carbide powder using hypo-phosphorous acid. Both the cobalt and the tungsten carbide phase peaks were evident in the tungsten carbide-cobalt composite powder by X-ray diffraction. The average particle size measured via scanning electron microscope, particle size analysis was around 380 nm and the thickness of coated cobalt was determined to be 30~40 nm by transmission electron microscopy.

Phase Transformation and Work-hardening Behavior of Ti-based Bulk Metallic Glass Composite

  • Hong, Sung Hwan;Kim, Jeong Tae;Park, Hae Jin;Kim, Young Seok;Park, Jin Man;Suh, Jin Yoo;Na, Young Sang;Lim, Ka Ram;Kim, Ki Buem
    • Applied Microscopy
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    • v.45 no.2
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    • pp.37-43
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    • 2015
  • In present work, work-hardening behavior of TiCu-based bulk metallic glass composite with B2 particles has been studied by systemic structural and mechanical investigations. After yield, pronounced work-hardening of the alloy was clearly exhibited, which was mainly related to the martensitic transformation as well as the deformation twinning in B2 particles during deformation. At the early plastic deformation stage (work-hardening stage), the stress-induced martensitic transformation from B2 phase to B19' phase and deformation-induced twinning of B19' phase was preferentially occurred in the around interface areas between B2 phase and amorphous matrix by stress concentration. The higher hardness value was observed in vicinity of interface within the B2 particles which are probably connected with martensitic transformation and deformation twinning. This reveals that the work-hardening phenomenon of this bulk metallic glass composite is a result of the hardening of B2 particles embedded in amorphous matrix.

State-of-the-art of the multi-scale analysis of advanced composite materials by homogenization method (일본내 연구동향 (6편중 제4편))

  • Takano, Naoki
    • Composites Research
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    • v.15 no.5
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    • pp.44-52
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    • 2002
  • To study numerically the mechanical behaviors of advanced composite materials considering the microscopic phenomena as well as the macroscopic properties and behaviors, a multi-scale modeling and analysis by the mathematical homogenization method with the help of the finite element method(FEM) are reviewed. The hierarchical modeling strategy and the formulation are briefly described first to give some idea of the multi-scale framework. The latter half of this article focuses on the verification of the multi-scale analysis by the homogenization method in its applications to real advanced materials. The first example is the verification of the predicted macroscopic(homogenized) properties based on the microstructure of porous ceramics. In spite of the complexity of the random microstructure, the error between the predicted and the measured values was only 1%. Next, two applications to the process simulation of fiber reinforced polymer matrix composites are presented. The permeability characteristics are evaluated for sheared weave fabrics for resin transfer molding(RTM) simulation, and the thermoforming of FRTP sheet is analyzed considering the large deformation of the knit structure during the deep-draw forming was verified by comparison with the experimental results.

Effect of Air-jet Texturing Conditions on the Physical Properties of Low Melting Polyester/Tencel Composite Yarn (에어제트 텍스처링 조건이 저융점 폴리에스터/텐셀 복합사의 물리적 특성에 미치는 영향)

  • Lee, Sun Young;Yoo, Jae Jung;Choi, Oh Gon;Lee, Si Woo;Lee, Seung Goo
    • Textile Coloration and Finishing
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    • v.25 no.1
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    • pp.47-55
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    • 2013
  • Physical properties of the composite yarn using low-melting(LM) polyester/Tencel were investigated with air-jet texturing conditions such as temperature, take-up overfeed, yarn speed and air pressure. Surface morphology, microstructure, tensile property, glossiness were evaluated. Surface morphology of a composite yarn had more damaged and loosened structure according to increase of take-up overfeed, yarn speed and air pressure. Crystallinity was affected by parameters such as temperature, yarn speed, take-up overfeed and air pressure and especially, yarn speed was most effective for increase of crystallinity. Also, it was found that temperature and air pressure had significantly affected tensile properties of a composite yarn. The glossiness of yarn increased with increase of temperature, yarn speed and air pressure.