• Journal of Electrochemical Science and Technology
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• 제13권2호
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• pp.199-207
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• 2022

Lithium-sulfur batteries (LSBs) have emerged as a promising alternative to lithium-ion batteries (LIBs) owing to their high energy density and economic viability. In addition, all-solid-state LSBs, which use solid-state electrolytes, have been proposed to overcome the polysulfide shuttle effect while improving safety. However, the high interfacial resistance and poor ionic conductivity exhibited by the electrode and solid-state electrolytes, respectively, are significant challenges in the development of these LSBs. Herein, we apply a poly (ethylene oxide) (PEO)-based composite solid-state electrolyte with oxide Li₇La₃Zr₂O₁₂ (LLZO) solid-state electrolyte in an all-solid-state LSB to overcome these challenges. We use an electrochemical method to evaluate the degradation of the all-solid-state LSB in accordance with the carbon content and loading weight within the cathode. The all-solid-state LSB, with sulfur-carbon content in a ratio of 3:3, exhibited a high initial discharge capacity (1386 mAh g^-1), poor C-rate performance, and capacity retention of less than 50%. The all-solid-state LSB with a high loading weight exhibited a poor overall electrochemical performance. The factors influencing the electrochemical performance degradation were revealed through systematic analysis.

• International Journal of Advanced Culture Technology
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• 제11권1호
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• pp.232-240
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• 2023

The ecological expression of art in modern society takes the harmonious developmental relationship between man and nature as an element and combines it with the various manifestations of painting as an expression of ecological artistic development. The necessary relationship for the harmonious development of nature is accurately articulated, and the ecological changes in people are expressed in integrated materials that inspire human reflection. In the pursuit of material pleasures, mankind is neglectful and indifferent to the environment. The development of composite painting in art and ecology is a process that more reveres the harmony between man and nature as well as satisfying the creative value of the work. After systematic evaluation and research, people have engaged in various structural forms of composite art painting development in the long history of art development, focusing on the integration of environmental and ecological culture. In the process of nature education going through development, the comprehensive practical development of nature education is enhanced and efforts are made to feel new ecological art ideas and new ways of valuing environmental protection. In this paper, an observational study of eco-art will be carried out, starting from the theory of hierarchical division and analyzing the contradictory relationship between man and nature. Recognize nature, understand it and feel it through eco-art painting. The analysis of the contradictory relationship between man and nature is combined with the identification of various types of information that give value to the environmental protection public, and the combination of ecological painting and nature art to achieve an upgrade of the environmental protection idea of the value of painting. In the development of artistic ecological comprehensive painting, it is necessary to put forward technical requirements and standards that meet the development of modern industry according to the characteristics and methods of ecological painting. The author of this paper discusses the necessity and social value of artistic ecological painting creation from the artist's point of view, expounds the practical achievements of ecological painting from the perspective of the history and present situation of the development of ecological aesthetics at home and abroad, and gives the concept and creative method of contemporary art comprehensive material painting in combination with his own actual situation.

• 한국결정성장학회지
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• 제25권6호
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• pp.245-251
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• 2015

본 연구에서는 $Fe_2O_3$-Mg계 혼합분말을 사용하여 연자성 복합재료를 제조하기 위하여 기계적 합금화법(MA)을 적용하였다. 초미세 조직을 가진 연자성 ${\alpha}$-Fe/MgO 복합재료를 얻기 위하여 X선 회절, 열분석 및 자기특성 측정을 통하여 최적 볼밀조건 및 열처리 조건을 조사하였다. $Fe_2O_3$와 순금속 Mg의 혼합분말을 30분 동안 MA 처리한 결과. ${\alpha}$-Fe 기지에 MgO가 분산된 ${\alpha}$-Fe/MgO 복합분말을 얻을 수 있었다. MA 분말시료의 자화값은 볼밀처리 시간에 따라 증가하여 MA 5시간 시료에서 69.5 emu/g의 최대값이 관찰되었다. 또한 MA 처리에 의하여 ${\alpha}$-Fe의 결정립 미세화와 함께 보자력이 증가하는 자기경화 현상이 관찰되었다. MA 분말시료의 벌크화를 위하여 소결온도 $800{\sim}1000^{\circ}C$, 압력 60 MPa에서 SPS 소결을 실시하였다. X선 회절 결과로부터, 5시간 MA 처리한 분말을 $800^{\circ}C$에서 SPS 소결시킨 ${\alpha}$-Fe/MgO 연자성 복합재료의 경우 ${\alpha}$-Fe상 평균 결정립 크기가 110 nm임을 알 수 있었다.

• Journal of Advanced Marine Engineering and Technology
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• 제38권9호
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• pp.1150-1155
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• 2014

강화플라스틱(FRP) 선박은 화재 시 화염확산을 막기 위하여 관련 구조 기준에 따라 기관실 주위 벽 내부를 난연성 수지로 3회 이상 적층하거나, 이와 동등한 방열재로 둘러싸야한다. 관련 난연성 적층용 수지 및 일부 난연재료(연질폴리우레탄복합체)의 경우 선박용 물건의 형식승인 시험기준에 따라 그 성능을 평가할 수 있으나, 방열재로 빈번하게 사용되고 있는 '겔코트'에 대한 성능기준은 명확하지 않은 실정으로 난연성 수지와 화재안전성능이 비교 평가된 바 없다. 본 연구에서는 FRP 선박을 건조하는 조선소를 대상으로 설문조사를 실시하여 사용 중인 난연성 수지 3종, 겔코트 4종, 방염도료 1종 및 폴리우레탄 복합재 1종에 대해 화염전파시험과 방염성능시험을 적용하여 그 성능을 비교하였다. 화염전파시험 결과 임계열유속(CFE) 기준으로 각 종별 평균값을 비교하면 폴리우레탄 복합재, 난연성 수지, 방염도료, 겔코트 순으로 양호한 것으로 나왔고, 겔코트는 3회 도포한 것이 6회 도포한 것보다 양호한 결과를 보였다. 방염성능시험 결과 탄화면적 기준으로 각 종별 평균값을 비교하면 방염도료가 가장 좋게 나왔고 난연성 수지와 겔코트는 유사한 수준으로 나타났다.

• 한국전산구조공학회논문집
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• 제35권4호
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• pp.215-226
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• 2022

우수한 역학적 성능을 가진 생물체의 구조를 모방하여 고성능의 복합재료를 개발하려는 노력이 최근 활발히 이뤄지고 있다. 진주층 구조는 구성재료 대비 월등히 높은 파괴인성을 지닌다는 점에서 촉망받는 자연 모사 구조 중 하나이다. 하지만, 진주층 모사 구조의 형상이 변형될 때 구조의 충격성능이 어떻게 달라지는지에 관한 연구는 아직 충분히 진행되지 않았다. 본 연구에서는 무작위로 변형된 진주층 모사 복합재의 수치모델을 개발하고 충격성능을 분석하였다. 먼저, 균일한 진주층 모사 패턴에서 플레이트 판의 평면 크기를 무작위로 변형하는 알고리즘을 개발하고 이를 활용하여 불균일한 진주층 패턴 모사 구조를 모델링하였다. 그 후, 낙하충격 시뮬레이션을 수행하고 해당 모델의 충격거동을 에너지 흡수율과 본 미세스 응력 분포, 충격력-시간 그래프를 활용하여 평가하였다. 수치해석결과를 바탕으로, 충돌 범위 주변 플레이트 판의 기하학적 형상이 불균일할수록 진주층 모사 구조의 내충격성이 저하됨을 입증하였다. 이러한 진주층 모사 형상에 대한 심층적인 이해는 진주층 모사 구조의 최적설계를 수립하는 데 효율적으로 활용될 수 있을 것으로 기대된다.

• Coupled systems mechanics
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• 제5권3호
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• pp.269-283
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• 2016

A two new high-order shear deformation theory for bending analysis is presented for a simply supported, functionally graded plate with porosities resting on an elastic foundation. This porosities may possibly occur inside the functionally graded materials (FGMs) during their fabrication, while material properties varying to a simple power-law distribution along the thickness direction. Unlike other theories, there are only four unknown functions involved, as compared to five in other shear deformation theories. The theories presented are variationally consistent and strongly similar to the classical plate theory in many aspects. It does not require the shear correction factor, and gives rise to the transverse shear stress variation so that the transverse shear stresses vary parabolically across the thickness to satisfy free surface conditions for the shear stress. It is established that the volume fraction of porosity significantly affect the mechanical behavior of thick function ally graded plates. The validity of the two new theories is shown by comparing the present results with other higher-order theories. The influence of material parameter, the volume fraction of porosity and the thickness ratio on the behavior mechanical P-FGM plate are represented by numerical examples.

• Environmental Engineering Research
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• 제13권2호
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• pp.85-92
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• 2008

In this present study, we have synthesized Fe-containing AC(activated carbon)/$TiO_2$ composites with titanium (VI) n-butoxide (TNB) as a titanium source to Fe treated AC through an impregnation method. The result of the textural surface properties demonstrates that there is a slight decrease in the BET surface area of composite samples with an increase of the amount of Fe treated. The surface properties of scanning electron microscope (SEM) presented a characterization of a porous texture on the Fe-containing AC/$TiO_2$ composites and homogenous compositions for Fe and titanium dioxide distributed on the sample surfaces. Fe compound peaks and a titanium dioxide structure were observed in the X-ray diffraction patterns for the Fe-containing AC/$TiO_2$ composites. The results of chemical elemental composition for the Fe-containing AC/$TiO_2$ composites showed that most of the spectra for these samples gave stronger peaks for C, O, treated Fe components and Ti metal than that of any other elements. From the photo degradation results for the piggery waste, the Fe-containing AC/$TiO_2$ composites showed an excellent degradation activity for the chemical oxygen demand (COD) due to a photocatalysis of the supported $TiO_2$, radical reaction by Fe species and the adsorptivity and absorptivity of porous carbon.

• Journal of Advanced Marine Engineering and Technology
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• 제24권1호
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• pp.67-74
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• 2000

Recently, PTFE-polymide composites are being used self-lubricating parts for industrial field. Thus, this study is mainly concerned with friction and wear properties for the piston ring of non-lubricating air compressor which made of PTFE-polymide composites. The friction and wear test was carried out for the different composition ratio under the atomsphere room temperature and constant load of 7.69N and their friction and wear properties were compared with each other at various sliding speed. notable results are summarized as follows. PTFE 100% showed that friction coefficient was almost same values at 0.94 and 1.88m/s but the value was decreased at 2.83m/s because the friction temperature is higher than low speed. PTFE 80%-PI 20% showed the lowest mean friction coefficient at 2.83m/s. PTFE 20-PI 80% showed the highest friction coefficient at 0.94m/s and the value was decreased at high speed but the value is higher than other materials except PTFE 100 %. PI 100% showed the highest friction coefficient at 0.94 and 1.88m/s becuase adhesive wear mainly occurred that speed. PTFE 100% showed highest specific wear rate on the whole. Specific wear rate of PTFE 80%-PI 20% was almost the same value with PTFE 20%-PI80%. PI 100%showed the lowest value at high sliding speed because the friction surface was thicken and carbonated by high friction temperature.

• 한국재난정보학회 논문집
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• 제12권1호
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• pp.54-61
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• 2016

구조물에 복합재료를 사용한 보강과 복구에 대한 사용이 증가하고 있는 상황에서 갑작스러운 강도저하로 발생되는 재난을 피하기 위하여 임시 보강하고자 탄소섬유 판을 이용하여 기존금속재와 접합(접착방식)을 통한 강도증진효과를 연구하였다. 특히 실험을 통하여 강-탄소섬유보강재로 이루어진 복합 재 거동을 파악하였으며 여기에 적절한 시험을 위한 새로운 형태의 시험편을 제작하였다. 접합재로 레진을 접착하는 부착 면을 달리하여 거동을 비교하기 위하여 표면처리가 다른 시험편을 각각 고려하여 시험한 결과 강성보강효과는 물론 일체거동의 특성이 잘 나타남을 알 수 있었다.

• 한국안전학회지
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• 제29권5호
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• pp.7-14
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• 2014

This study aimed to develop members with the optimum impact characteristics to ensure a protected space for passengers in the case of automobile collisions. Accordingly, these members were fabricated to provide sufficient rigidity and safety to the passenger room structure and to absorb large amounts of energy during collision. In particular, CFRP members were fabricated with different section shapes such as square and single- and double-hat shapes. Next, their impact collapse characteristics and collapse modes were quantitatively analyzed according to the changes in section shapes and stacking angles. This analysis was performed to obtain design data that can be applied in the development of optimum lightweight members for automobiles.