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http://dx.doi.org/10.4491/eer.2008.13.2.085

Synthesis and Characterization of Fe-containing AC/TiO2 Composites and Their Photodegradation Effect for the Piggery Waste  

Oh, Won-Chun (Department of Advanced Materials & Science Engineering, Hanseo University)
Publication Information
Abstract
In this present study, we have synthesized Fe-containing AC(activated carbon)/$TiO_2$ composites with titanium (VI) n-butoxide (TNB) as a titanium source to Fe treated AC through an impregnation method. The result of the textural surface properties demonstrates that there is a slight decrease in the BET surface area of composite samples with an increase of the amount of Fe treated. The surface properties of scanning electron microscope (SEM) presented a characterization of a porous texture on the Fe-containing AC/$TiO_2$ composites and homogenous compositions for Fe and titanium dioxide distributed on the sample surfaces. Fe compound peaks and a titanium dioxide structure were observed in the X-ray diffraction patterns for the Fe-containing AC/$TiO_2$ composites. The results of chemical elemental composition for the Fe-containing AC/$TiO_2$ composites showed that most of the spectra for these samples gave stronger peaks for C, O, treated Fe components and Ti metal than that of any other elements. From the photo degradation results for the piggery waste, the Fe-containing AC/$TiO_2$ composites showed an excellent degradation activity for the chemical oxygen demand (COD) due to a photocatalysis of the supported $TiO_2$, radical reaction by Fe species and the adsorptivity and absorptivity of porous carbon.
Keywords
Activated carbon; Titanium (IV) n-butoxide; BET; XRD; SEM; Photocatalysis;
Citations & Related Records
Times Cited By KSCI : 6  (Citation Analysis)
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1 Oh, W. C., Han, S. B., and Bae, J. S., "The analysis for the HCl modification effect and formation of $TiO_2$ on activated carbon fiber surface," Analytical Science & Technology, 20(4), 279-288 (2007)
2 Oh, W. C., Bae, J. S., Chen, M. L., "Photocatalytic effect for the pitch-coated $TiO_2$," Analytical Science & Technology, 19(4), 301-308 (2006)
3 Zhang, X., Zhou, M., and Lei, L., "Preparation of photocatalytic $TiO_2$ coating of nanosized particles on activated carbon by AP-MOCVD," Carbon, 43, 1700-1708 (2005)   DOI   ScienceOn
4 Oh, W. C., Bae, J. S., and Chen, M. L., "Characterization of $AC/TiO_2$ composite prepared with pitch binder and their photocatalytic activity," Bull. Korean Chem. Soc., 27(9), 1423-1328 (2006)   DOI   ScienceOn
5 Tryba, B., Morawski, A. W., Inagaki, M., and Toyoda, M., "Effect of the carbon coating in $Fe-C-TiO_2$ photocatalyst on phenol decomposition under UV irradiation via photo- Fenton process," Chemosphere, 64, 1225-1232 (2006)   DOI   ScienceOn
6 Reztsova, T., Chang, C. H., Koesh, J., and Idriss, H., "Dark and photoreaction of ethanol and actaldehyde over $TiO_2/carbon$ molecular sieve fibers," J. Catal., 185, 223-235 (1999)   DOI   ScienceOn
7 Oh, W. C., Bae, J. S., and Chen, M. L., "Preparation of carbon-coated $TiO_2$ at different heat treatment temperatures and their photoactivity," Carbon Science, 7(4), 259-265 (2006)
8 Matos, J., Laine, J., and Herrmann, J. M., "Association of activated carbons of different origins with titania in the photocatalytic purification of water," Carbon, 37, 1870-1872 (1999)   DOI   ScienceOn
9 Oh, W. C., and Chen, M. L., "Preparation $AC/TiO_2$ composites from activated carbon modified by $HNO_3$ and their photocatalytic activity," Carbon Science, 8(2), 108-144 (2007)
10 Tatsuda, N., Itahara, H., Setoyama, N., and Fukushma, Y., "Preparation of titanium dioxide/activated carbon composites using supercritical carbon dioxide," Carbon, 43, 2358-2365 (2005)   DOI   ScienceOn
11 Inagaki, M., Hirose, Y., Matsunage, T., Tsumura, T., and Toyoda, M., "Carbon coating of anatase-type $TiO_2$ through their precipitation in PVA aqueous solution," Carbon, 41, 2619-2624 (2003)   DOI   ScienceOn
12 Oh, W. C., and Lim, C. S., "Comparison of physical properties and dye photo-degradation effects for $carbon/TiO_2$complexes," J. of the Korean Crystal Growth and Crystal Technology, 17(5), 196-203 (2007)   과학기술학회마을
13 Arana, J., Gonzalez Diaz, O., Miranda Saracho, M., Dona Rodriguez, J. M., Herrera Melian, J. A., and Perez Pena, J., "Photocatalytic degradation of formic acid using $Fe/TiO_2$ catalysts: the role of $Fe^{3+}/Fe^{2+}$ ions in the degradation mechanism," Appl. Catal. B: Environ., 32, 49-61 (2001)   DOI   ScienceOn
14 Bauer, R., Waldner, G., Fallmann, H., Hager, S., Klare, M., Krutzler, T., Malato, S., and Maletzky, P., "The photo-Fenton reaction and the $TiO_2/UV$ process for waste water treatment- novel developments," Catal. Today, 53, 131-144 (1999)   DOI   ScienceOn
15 Chen, M. L., Ko, Y. S., and Oh,W. C., "$Carbon/TiO_2$ prepared from to pitch and their photocatalytic activity," Carbon Science, 8(1), 6-11 (2007)
16 Oh, W. C., Ko, W. B., "Physical properties for K-activated carbon and its removal efficiencies for chemical factors," J. Ind. Eng. Chem., 12(3), 373-379 (2006)
17 Oh, W. C., Chen, M. L., and Lim, C. S., "Preparation with different mixing ratios of anatase to activated carbon and their photcatalytic performance," Journal of Ceramic Processing Research, 8(2), 119-124 (2007)
18 Yu, K., Zhao, J., Tian, Y., Jiang, M., Ding, X., Liu, Y., Zhu, Y., and Wang, Z., "Preparation of nonosized titanium dioxide from titanium n-butoxide modified with tartaric acid and its influence on the phase transformation," Materials Letters, 59, 3563-3566 (2005)   DOI   ScienceOn
19 Oh, W. C., and Park, T. S., "Electro-chemical removal of water pollutants by silver-ACF from piggery waste," J. Ind. Eng. Chem, 11, 671-680 (2005)   DOI
20 Oh, W. C., Bae, J. S., Chen, M. L., Ko, Y.S. "Characterization of composite prepared with different mixing ratios of $TiO_2$ to activity carbon and their photocatalytic activity," Analytical Science & Technology, 19(5), 376-382 (2006)
21 Oh, W.C., Bae, J. S., and Chen, M. L., "Photocatalytic effect for the carbon-coated $TiO_2$ prepared from different heat treatment temperature," Analytical Science & Technology, 19(6), 460-467 (2006)
22 Oh, W. C., and Park, T. S., Comparative analysis of the physical properties and photocatalytic effects for $C/TiO_2$ complexes derived from titanium n-butoxide, Environmental Engineering Research, 12(5), 218-223, 2007   과학기술학회마을   DOI   ScienceOn