• Title/Summary/Keyword: Adsorbent material

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Removal of Cu(II) ions by Alginate/Carbon Nanotube/Maghemite Composite Magnetic Beads

  • Jeon, Son-Yeo;Yun, Ju-Mi;Lee, Young-Seak;Kim, Hyung-Il
    • Carbon letters
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    • v.11 no.2
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    • pp.117-121
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    • 2010
  • The composites of alginate, carbon nanotube, and iron(III) oxide were prepared for the removal of heavy metal in aqueous pollutant. Both alginate and carbon nanotube were used as an adsorbent material and iron oxide was introduced for the easy recovery after removal of heavy metal to eliminate the secondary pollution. The morphology of composites was investigated by FE-SEM showing the carbon nanotubes coated with alginate and the iron oxide dispersed in the alginate matrix. The ferromagnetic properties of composites were shown by including iron(III) oxide additive. The copper ion removal was investigated with ICP AES. The copper ion removal efficiency increased greatly over 60% by using alginate-carbon nanotube composites.

Red Mud를 이용한 토양 및 슬러지내 중금속 제거 특성

  • 김이태;배우근;김우정;정원식
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.73-77
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    • 2003
  • Red mud is a waste material formed during the production of alumina when the bauxite ore is subjected to caustic leaching. It is a brick-red colored highly alkaline (pH 10-12) sludge containing mostly oxides of iron, aluminum, titanium, and silica. Red mud, due to its high aluminum, iron, and calcium contents, has been suggested as a cheap adsorbent for removal of toxic metals (e.g., As, Cr, Pb, Cd) as well as for water or wastewater treatment. The basic advantage of red mud is its versatility in application. This study was conducted to evaluate the effect of red mud on stabilization and fixation of heavy metals (such as Pb, Cu, C $r^{6+}$, Cd, Zn) contained in the Al-coating sludge and soil. The results showed that the concentration of heavy metals leached from the treated sludge and soil was low, meeting the regulatory permit level.

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Feasibility Study with Several Sorption Materials to Treat Road Runoff Pollutions (흡착 소재별 도로 노면 유출 오염원의 저감성 비교 연구)

  • Park, Sangwoo;Oh, Jeill;Choi, Younghwa
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.5
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    • pp.709-717
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    • 2006
  • This research was conducted to figure out the feasibility of several sorption materials to treat various pollutants in road runoff. In advance of the major feasibility test with various sorption materials, the separation process with $1.2{\mu}m$ filter was conducted and showed that slight portion of pollutants was removed(Orgamic pollutant - 20%, Nutrient salt - 50%, Heavy metals - 0~30%). To remove dissolved pollutants in runoff, various materials were tested through an isotherm sorption experiment. As a result, GAC showed most effective material among them to lessen most contaminants such as organic compounds and nutrients. On the other hand, ion-exchange resin and Zeolite showed limited usefulness on the some heavy metals. Freundlich model was most suitable for the current experiment data, and the amount of adsorbent (GAC) could calculated based on this model.

Carbonation of a few of Common materials which can fix CO2 (상용 CO2고정재료의 탄산화에 관한 문헌적 연구)

  • Chen, zheng-xin;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.10a
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    • pp.47-48
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    • 2016
  • Mineral carbonation technology is a process whereby CO2 is chemically reacted with calcium-and/or magnesium-containing minerals to form stable carbonate materials. Add the Materials that could fix CO2 as mineral admixture to concrete can improve the anti-carbonation properties of concrete. This paper has carried on the literature research on the carbonated mechanism of Material that could fix carbon dioxide. Such as Brucite, 𝜞-C2S, Mg2SiO4, MgO, Ca3MgSi2O8. And summarizes the development of the development of this field.

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Removing of Phosphate, Nitrogen and Anion surfactants in the Wastewater using ALC (경량기포콘크리트를 이용한 인과 질소 및 음이온계면활성제 제거)

  • 홍영호
    • Journal of environmental and Sanitary engineering
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    • v.16 no.1
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    • pp.102-107
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    • 2001
  • This research was carried out investigate the removed T-P, T-N and anion surfactants using Autoclaved Lightweight Concrete(ALC) in wastewater treatment system. Effects of pH, TDS on aqueous solution was measured. Specific area which measured by BET was $27.66m^2/g$. The phosphorous, nitrogen and anion surfactants removal efficiencies were examined by using artificial waste water(T-P : 66~73mg/L, T-N : 56~136mg/L and anion surfactants : 10~31mg/L). The results showed that the ALC was effective material as a adsorbent due to the structure and porosity. It was found that anion surfactants removed was 85~95%, phosphate removed was 92% and nitrogen removed was 90% in artificial wastewater. Agitation process was more effective than aeration process in that case of nitrogen removal system using ALC.

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Heavy metal removal with polypropylene material coating : artificial road coatings run-off (중금속 제거를 위한 폴리프로필렌 소재 코팅에 관한 연구 : 불투수면 유출수 처리)

  • Oh, Hye-Cheol;Park, Min-Ho;Rhee, Dong-Seok
    • Journal of Industrial Technology
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    • v.27 no.A
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    • pp.19-24
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    • 2007
  • This research was done for possible treatment of impermeable surfaces rainwater runoff containing heavy metal ions by manganese oxide coated on polypropylene support. Manganese oxide was coated by Birnessite Coating Methods(BCM)and the coating analyzed by SEM and FT-IR techniques. The efficiency of heavy metal ions adsorption was also assessed via both batch and column tests. Adsorption efficiencies of Cd, Zn, Cu, and Pb were 99.4%, 98.9%, 96.7%, and over 95.7%, respectively. The adsorption progress pattern reveals quite fast adsorption at initial periods of treatment and change to slower rates at later times.

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Properties of Fine Dust Adsorption Matrix Based Blast Furnace Slag using Bentonite (벤토나이트를 활용한 고로슬래그 기반 미세먼지 흡착형 경화체의 특성)

  • Kim, Yeon-Ho;Kyoung, In-Soo;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.05a
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    • pp.40-41
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    • 2019
  • Fine dust, which is emerging as a global problem, attracted much attention recently in Korea. One of the reasons is that recent factory relocation and expansion in China affected the increase of domestic fine dust concentration due to the influence of the Yangtze river battalion and westerlies. Fine dust is a big problem not only in outdoor but also indoors. The room requires periodic ventilation and is also essential for improving indoor air quality. The fine dusts are designated as Group 1 carcinogens in WHO and the risk of fine dusts on the human body due to respiratory diseases is also increasing. In this study, the characteristics of the fine dust adsorption matrix are examined and the actual application direction is derived.

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Research Progress of Antibiotic Pollution and Adsorption Materials in Aquatic environment

  • Zheng, Kun;Deng, ChengXun;Deng, Xu;Yu, ZhiMin
    • Journal of Urban Science
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    • v.8 no.2
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    • pp.1-5
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    • 2019
  • China is the great powers of use and production of antibiotics.The current process of sewage treatment plants can not effectively remove antibiotics in water. Chinese scholars have detected different kinds of antibiotics in major waters of the country, which have potential harm to human body. Among all kinds of antibiotic treatment technologies, adsorption removal technology has the advantages of simple operation, low cost and high removal efficiency. It is a widely concerned antibiotic removal technology. However, at present, few materials have been put into practical application, and more materials with low cost and high efficiency need to be found. Different adsorptive materials have different adsorptivity to different antibiotics. For different antibiotics, different adsorptive materials can be integrated in the future, and the theory can be extended to application.

Adsorption of Rare Earth Metal Ion on N-Phenylaza-15-Crown-5 Synthetic Resin with Styrene Hazardous Material

  • Kim, Se-Bong;Kim, Joon-Tae
    • Journal of Integrative Natural Science
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    • v.7 no.2
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    • pp.130-137
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    • 2014
  • Resins were synthesized by mixing N-phenylaza-15-crown-5 macrocyclic ligand attached to styrene (2th petroleum in 4th class hazardous materials) divinylbenzene (DVB) copolymer with crosslink of 1%, 2%, 6%, and 12% by substitution reaction. The synthesis of these resins was confirmed by content of chlorine, element analysis, thermo gravimetric analysis (TGA), surface area, and IR-spectroscopy. The effects of pH, equilibrium arrival time, dielectric constant of solvent and crosslink on adsorption of metal ions by the synthetic resin adsorbent were investigated. The metal ions were showed fast adsorption on the resins above pH 4. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order uranium (VI) > zinc (II) > europium (III) ions. The uranium ion adsorbed in the order of 1%, 2%, 6%, and 12% crosslink resin and adsorption of resin decreased in proportion to the order of dielectric constant of solvents.

Adsorption of Uranium (VI) Ion on 1-Aza-12-Crown-4 Synthetic Resin with Styrene Hazardous Material

  • Kim, Joon-Tae
    • Journal of Integrative Natural Science
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    • v.6 no.2
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    • pp.104-110
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    • 2013
  • 1-Aza-12-crown-4 macrocyclic ligand was combined with styrene (2th petroleum in 4th class hazardous materials) divinylbenzene copolymer having 1%, 2%, 3%, and 6% crosslinks by a substitution reaction, in order to synthesize resin. These synthetic resins were confirmed by chlorine content, elementary analysis and IR-spectrum. As the results of the effects of pH, equilibrium arrival time, crosslink of synthetic resin, and dielectric constant of a solvent on uranium ion adsorption for resin adsorbent, the uranium ion showed high adsorption at pH 3 or over and adsorption equilibrium of uranium ion was about 2 hours. In addition, adsorption selectivity for the resin in methanol solvent was the order of uranium ($UO_2{^{2+}}$) > iron ($Fe^{3+}$) > lutetium ($Lu^{3+}$) ions, adsorbability of the uranium ion was in the crosslinks order of 1%, 2%, 3%, and 6% was increased with the lower dielectric constant.