• Title/Summary/Keyword: Additive Layer

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High-Mobility Ambipolar Polymer Semiconductors by Incorporation of Ionic Additives for Organic Field-Effect Transistors and Printed Electronic Circuits (이온성 첨가제 도입을 통한 고이동도 고분자 반도체 특성 구현과 유기전계효과트랜지스터 및 유연전자회로 응용 연구)

  • Lee, Dong-Hyeon;Moon, Ji-Hoon;Park, Jun-Gu;Jung, Ji Yun;Cho, Il-Young;Kim, Dong Eun;Baeg, Kang-Jun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.3
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    • pp.129-134
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    • 2018
  • Herein, we report the manufacture of high-performance, ambipolar organic field-effect transistors (OFETs) and complementary-like electronic circuitry based on a blended, polymeric, semiconducting film. Relatively high and well-balanced electron and hole mobilities were achieved by incorporating a small amount of ionic additives. The equivalent P-channel and N-channel properties of the ambipolar OFETs enabled the manufacture of complementary-like inverter circuits with a near-ideal switching point, high gain, and good noise margins, via a simple blanket spin-coating process with no additional patterning of each active P-type and N-type semiconductor layer.

Effect of Injection Stage of SF6 Gas Incorporation on the Limitation of Carbon Coils Geometries (육불화황 기체의 주입단계에 따른 탄소코일 기하구조의 제약)

  • Kim, Sung-Hoon
    • Journal of the Korean Vacuum Society
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    • v.20 no.5
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    • pp.374-380
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    • 2011
  • Carbon coils could be synthesized on nickel catalyst layer-deposited silicon oxide substrate using $C_2H_2$ and $H_2$ as source gases and $SF_6$ as an additive gas under thermal chemical vapor deposition system. The characteristics (formation density and morphology) of as-grown carbon coils according to the injection stage of $SF_6$ gas incorporation were investigated. A continuous injecting of $SF_6$ gas flow could give rise to many types of carbon coils-related geometries, namely linear tub, micro-sized coil, nano-sized coil, and wave-like nano-sized coil. However, the limitation of the geometry as the nano-sized geometries of carbon coils could be achieved by the incorporation of $SF_6$ in a short time (1 min) during the initial deposition stage. A delayed injection of a short time $SF_6$ gas flow can deteriorate the limitation of the geometries. It confirms that the injection time and its starting point of $SF_6$ gas flow would be very important to determine the geometries of carbon coils.

Micro Emulsion Synthesis of LaCoO3 Nanoparticles and their Electrochemical Catalytic Activity

  • Islam, Mobinul;Jeong, Min-Gi;Ghani, Faizan;Jung, Hun-Gi
    • Journal of Electrochemical Science and Technology
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    • v.6 no.4
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    • pp.121-130
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    • 2015
  • The micro emulsion method has been successfully used for preparing perovskite LaCoO3 with uniform, fine-shaped nanoparticles showing high activity as electro catalysts in oxygen reduction reactions (ORRs). They are, therefore, promising candidates for the air-cathode in metal-air rechargeable batteries. Since the activity of a catalyst is highly dependent on its specific surface area, nanoparticles of the perovskite catalyst are desirable for catalyzing both oxygen reduction and evolution reactions. Herein, LaCoO3 powder was also prepared by sol-gel method for comparison, with a broad particle distribution and high agglomeration. The electro catalytic properties of LaCoO3 and LaCoO3-carbon Super P mixture layers toward the ORR were studied comparatively using the rotating disk electrode technique in 0.1 M KOH electrolyte to elucidate the effect of carbon Super P. Koutecky-Levich theory was applied to acquire the overall electron transfer number (n) during the ORR, calculated to be ~3.74 for the LaCoO3-Super P mixture, quite close to the theoretical value (4.0), and ~2.7 for carbon-free LaCoO3. A synergistic effect toward the ORR is observed when carbon is present in the LaCoO3 layer. Carbon is assumed to be more than an additive, enhancing the electronic conductivity of the oxide catalyst. It is suggested that ORRs, catalyzed by the LaCoO3-Super P mixture, are dominated by a 2+2-electron transfer pathway to form the final, hydroxyl ion product.

Effect of PCB Switching Noise on Radiated Emission from Enclosure Aperture (PCB에 인가된 스위칭 잡음이 함체 개구 방사에 미치는 영향)

  • Jang, Hyoung-Seok;Lee, Soong-Keun;Kim, Eun-Ha;Ryu, Seung-Real;Lee, Jae-Hyun;Park, Dong-Chul
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.22 no.1
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    • pp.67-75
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    • 2011
  • This paper investigates the radiated emission from the enclosure aperture, when the enclosure contains a 4-layer PCB and the PCB is driven by a pulse train additive with the switching noise from an active device. Radiated emission characteristics with and without switch noise cases, respectively, are analyzed by changing the PCB location and the slot direction. The equivalent circuit of a DC-DC converter is used to simulate the switching noise of active device. Also, MWS simulation results are directly connected to the ADS simulator as a 2-port block. The simulated results are compared with the measured ones.

Symbol Time Tracking Algorithm for WAVE Systems (WAVE 시스템에서 심볼 시간추적 알고리듬)

  • Hong, Dae-Ki
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.13 no.2
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    • pp.397-406
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    • 2009
  • A Wireless Access for Vehicular Environment (WAVE) system based on Orthogonal frequency Division Multiplexing (OFDM) is made for vehicle to vehicle wireless communications. The physical layer standard of the WAVE system is very similar to that of the IEEE802.1la wireless local area network (WLAN). Therefore, the performance of the WAVE system is degraded by continual timing delay in the WAVE multipath fading channels after starting initial timing synchronization. In this paper, the tracking algorithm that synchronizes symbol timing is proposed to continually compensate additional timing delay. Computer simulation of the proposed algorithm is performed in the worst communication environments that apply to maximum timing delay. Computer simulation shows that the proposed algorithm can improve the system performance in various channel conditions.

Water desalination by membrane distillation using PVDF-HFP hollow fiber membranes

  • Garcia-Payo, M.C.;Essalhi, M.;Khayet, M.;Garcia-Fernandez, L.;Charfi, K.;Arafat, H.
    • Membrane and Water Treatment
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    • v.1 no.3
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    • pp.215-230
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    • 2010
  • Poly(vinylidene fluoride-co-hexafluoropropylene), PVDF-HFP, hollow fiber membranes were prepared by the dry/wet spinning technique using different polyethylene glycol (PEG) concentrations as non-solvent additive in the dope solution. Two different PEG concentrations (3 and 5 wt.%). The morphology and structural characteristics of the hollow fiber membranes were studied by means of optical microscopy, scanning electron microscopy, atomic force microscopy (AFM) and void volume fraction. The experimental permeate flux and the salt (NaCl) rejection factor were determined using direct contact membrane distillation (DCMD) process. An increase of the PEG content in the spinning solution resulted in a faster coagulation of the PVDF-HFP copolymer and a transition of the cross-section internal layer structure from a sponge-type structure to a finger-type structure. Pore size, nodule size and roughness parameters of both the internal and external hollow fiber surfaces were determined by AFM. It was observed that both the pore size and roughness of the internal surface of the hollow fibers enhanced with increasing the PEG concentration, whereas no change was observed at the outer surface. The void volume fraction increased with the increase of the PEG content in the spinning solution resulting in a higher DCMD flux and a smaller salt rejection factor.

Densification of Reaction Bonded Silicon Nitride with the Addition of Fine Si Powder - Effects on the Sinterability and Mechanical Properties

  • Lee, Sea-Hoon;Cho, Chun-Rae;Park, Young-Jo;Ko, Jae-Woong;Kim, Hai-Doo;Lin, Hua-Tay;Becher, Paul
    • Journal of the Korean Ceramic Society
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    • v.50 no.3
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    • pp.218-225
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    • 2013
  • The densification behavior and strength of sintered reaction bonded silicon nitrides (SRBSN) that contain $Lu_2O_3-SiO_2$ additives were improved by the addition of fine Si powder. Dense specimens (relative density: 99.5%) were obtained by gas-pressure sintering (GPS) at $1850^{\circ}C$ through the addition of fine Si. In contrast, the densification of conventional specimens did not complete at $1950^{\circ}C$. The fine Si decreased the onset temperature of shrinkage and increased the shrinkage rate because the additive helped the compaction of green bodies and induced the formation of fine $Si_3N_4$ particles after nitridation and sintering at and above $1600^{\circ}C$. The amount of residual $SiO_2$ within the specimens was not strongly affected by adding fine Si powder because most of the $SiO_2$ layer that had formed on the fine Si particles decomposed during nitridation. The maximum strength and fracture toughness of the specimens were 991 MPa and $8.0MPa{\cdot}m^{1/2}$, respectively.

Production of Ni-Cr Metal Powder by Selective Laser Melting for Dentistry to Observation of Characteristics (치과 SLM용 Ni-Cr 금속분말 특성 관찰)

  • Hong, Minho
    • Journal of Technologic Dentistry
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    • v.37 no.1
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    • pp.23-29
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    • 2015
  • Purpose: The selective laser melting (SLM) process for dentistry, which is one of the additive manufacturing technologies (AM) allows for rapid production of a three-dimensional model with complex shape by directly melting metal powder. This process generates detailed items of a three-dimensional model shape through consolidation of a thin powder layer by utilizing both selective melting and laser beam simultaneously. In regard to SLM process, Fe-base powder, Ti-6AI-4V powder, AI-base powder, etc. have been researched. It is believed that the aforementioned technologies will be widely utilized in manufacturing metal parts using metal powder of raw material. This study chose Ni-Cr-Mo metal powder in order to manufacture metal powder materials that would be used in the selective laser melting for dentistry. Methods: This study manufactured metal powder using mechanical alloying technique (MA) among those metal powder manufacturing techniques. Moreover, this study aimed to utilize the metal powder manufactured after observing the characteristics of powder as preliminary data of Ni-Cr-Mo metal powder. This study could obtain the following conclusions within the experimental limitations. Results: As a result of mechanically alloying Ni-Cr-Mo powder over time, its mean particle size was $66.93{\mu}m$ $54.4{\mu}m$ and $45.39{\mu}m$ at 10h, 20h and 30h, respectively. The gtain form of metal powder by mechanical alloying technique was a sponge-like shape of irregular plate; however, the gtain form manufactured by high-pressure water aromization process had the following three types: globular type, chain type and oval type. Conclusion: This study found $37.65{\mu}m$ as the mean particle size of Ni-Cr-Mo metal powder, which was manufactured using water atomization technique under the following conditions: water atomization flux of 300 liter/min, hydraulic pressure of $400kgf/cm^2$ and injection angle of $45^{\circ}$. This study confirmed that the grain form of powder (solid particle form) would vary depending on the manufacturing process.

Solubillzation and Extraction Of Antioxidant Astaxanthin by Micelle Formation from Phaffia rhodozyma Cell Homogenate (Phaffia rhodozyma 세포파쇄액으로부터 항산화제 Astaxanthin의 미셀 형성을 통한 가용화 및 추출)

  • Kim, Young-Beom;Ryu, Kang;Lim, Gio-Bin;Lee, Eun-Kyu
    • KSBB Journal
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    • v.17 no.2
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    • pp.176-181
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    • 2002
  • Astaxanthin (3,3'-dihydroxy-${\beta}$, ${\beta}$-carotene-4-4'-dione), a natural pigment of pink to red color, is widely distributed in nature particularly in the skin layer of salmonoids and the crust of shrimp, lobster, etc. Recently, it was produced from the yeast culture of Phaffia rhodozyma. Because of its high thermal stability and antioxidant functionality, its applications can be extended into food, cosmetics, and pharmaceutical ingredient beyond the traditional feed additive. Because of its very high lipophilicity, astaxanthin has been extracted traditionally by strong organic solvents such as chloroform, petroleum ether, acetone, etc. In this study, we developed a surfactant-based solubillization system for astaxanthin, and used it to extract astaxanthin from disrupted yeast cells. Among Tween 20, Triton X-100 and SDS, Tween 20 was identified as the most suitable surfactant in terms of extraction capacity and safety. The ethylene oxide group of Tween 20 was identified as the most significant factor to increase the HLB value that determined the extraction capacity. The effects of micelle formation condition, such as the molar ratio of astaxanthin and Tween 20, pH, and ionic strength were also investigated. pH and ionic strength showed no significant effects. The optimal molar ratio between astaxanthin and Tween 20 was 1 : 12. Antioxidant activity of astaxanthin was higher than ${\beta}$-carotene and ${\alpha}$-tocopherol. Astaxanthin in the crude extract from the yeast cell was more resistant to air and/or light degradation than pure astaxanthin, probably because of the presence of other carotenoids and lipids.

Effects of the Additives on Etching Characteristics of Aluminum Foil (첨가제에 의한 알루미늄박의 에칭특성변화)

  • Kim, Seong-Gap;Shin, Dong-Cheol;Jang, Jae-Myeong;Lee, Jong-Ho;Oh, Han-Jun;Chi, Chung-Su
    • Korean Journal of Materials Research
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    • v.11 no.1
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    • pp.48-54
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    • 2001
  • The effects of additives in the HCI etching solution on etching behaviors of aluminum foil as dielectric film for electrolytic capacitors were investigated. The etch pits formed in 1M hydrochloric acid containing ethylene glycol as an additive contain more fine and homogeneous etch tunnels compared to those in 1 M hydrochloric acid only, which led to the increase in the effective internal surface area of aluminum foil. After anodizing of aluminum foil etched in etching solutions, the LCR meter results have shown that the capacitance of dielectric film etched in hydrochloric acid with ethylene glycol was increased remarkably compared to that etched in hydrochloric acid only.

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