• Title/Summary/Keyword: Acid/base treatment

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Synthesis of LiCoO2 Powders using Recycled Cobalt Precursors from Waste WC-Co Hard Metal (폐 WC-Co계 초경합금에서 추출된 코발트 재생 원료를 이용한 LiCoO2 입자 합성 연구)

  • Yang, Hee-Seung;Pee, Jae-Hwan;Kim, Yoo-Jin
    • Journal of Powder Materials
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    • v.18 no.3
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    • pp.277-282
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    • 2011
  • [ $LiCoO_2$ ] a cathode material for lithium rechargeable batteries, was prepared using recycled $Co_3O_4$. First, the cobalt hydroxide powders were separated from waste WC-Co hard metal with acid-base chemical treatment, and then the impurities were eliminated by centrifuge method. Subsequently, $Co_3O_4$ powders were prepared by thermal treatment of resulting $Co(OH)_2$. By adding a certain amount of $Li_2CO_3$ and $LiOH{\cdot}H_2O$, the $LiCoO_2$ was obtained by sintering for 10 h in air at $800^{\circ}C$. The synthesized $LiCoO_2$ particles were characterized by X-ray diffraction (XRD) and Scanning Electron Microscope (SEM) analysis.

A Review of Cupping Application in the field of Physical Therapy (물리치료의 장에 부항 적용에 대한 고찰)

  • Shin, Hong-Cheul;Seo, Gyu-Won;Kim, Kang-Su;Kim, Woo-Jin
    • Journal of Korean Physical Therapy Science
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    • v.5 no.4
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    • pp.729-750
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    • 1998
  • The purpose of this Review is to help activities of daily living by normalizing bodily functions through the use of negative pressure. Cupping therapy has been holding the important role as a form of treatment in ancient medicine of Oriental and Occidental country, and still being used widely due to it's effectiveness. Principle of Cupping therapy is to neutralize somatic dysfunctions by elimination of nonphysiological somatic fluid of hematoma through application of negative pressure on region of dermatomal meridian. The effectiveness of Cupping therapy as follows; 1) Effects on acid base balance of bodily fluid. 2) Through the reabsorption of subcutaneous hematoma, it affects on formation of immune system and produce the blood serum cleaning reaction. 3) By application of negative pressure on subcutaneous, induce renal system to produce steroid hormone. 4) By stimulating hemopoietic system, it maxmize the blood production level. Recently, Alternative medicine has been a focus due to it's nature of effectiveness and safety without adverse complication. Therefore, every family possess and use the cupping modality for preventive measure and/or treatment purpose in order to eliminate accumulated byproducts of body and clean the blood system.

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Inactivation by Chemical Disinfectants in vitro against Tobacco Mosaic Virus (화학적 제어제에 의한 담배모자이크 바이러스의 불활성화)

  • Choi, C.W
    • The Journal of Natural Sciences
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    • v.10 no.1
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    • pp.17-21
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    • 1998
  • Numerous chemicals were tasted to show antiviral activity in vitro against tobacco mosaic virus (TMV). With a brief exposure of TMV to 1 N HCl or 1-0.1 N NaOH, Virions and their encapsidated RNAs were degraded completely and rapidly. When TMV was exposed to 0.1 N HCl, the hydrolysis of viral capsid in 5 min after treatment was observed in the 1% agarose gel. Virions and their encapsidated RNAs were not degraded by 0.01N HCl of 0.01N NaOH. These characteristics indicate that a short exposure to optimal concentration of acid or base is of practical value in eliminating infectious virus. The treatment of 50% isopropanol or UV light did not damage in viral integrity or their encapsidated RNAs. Disinfection of the agricultural tools and laboratory equipments using appropriate disinfectants is necessary to prevent cross contamination if farm and laboratory.

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Degradation and Ecotoxicity Reduction of Reactive Dye by Using Advanced Oxidation Process (고도산화공정을 이용한 반응성 염료의 제거 및 생태독성 저감)

  • Seo, Kyung Ae;Park, Jae Hong;Jung, Soo Jung;Lim, Byung Jin
    • Journal of Korean Society on Water Environment
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    • v.29 no.2
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    • pp.204-211
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    • 2013
  • In this study, the deriving optimum conditions for decolorization of Acid Orange II solution was carried using $TiO_2$ advanced oxidation process. After that, on base of the deriving results, the range of dye concentration was estimated. In addition, acute toxicity test was also carried to assess toxicity unit according to decolorization and TOC removal. In case of the blockage of light, 20 mg/L of dye solution, and 0.5 g $TiO_2$, the effect of decolorization at pH 3 was larger than at pH 6 and 10, so it was shown that decolorization is dependent on pH. The use of 5 g $TiO_2$ showed best performance of decolorization, but that of 3 g $TiO_2$ was chosen to optimum condition in considering of economical aspects. Four light sources, sun, fluorescent lamp, BLB lamp, and UV-B lamp, were used and decolorization was 99.4% and 100% at 50 mg/L, 98.6% and 99.7% at 100 mg/L for sun and UV-B lamp, respectively. In spite of the optimum condition of decolorization at pH 3, the evaluation of acute toxicity test showed highly toxic. In conclusion, although the optimum treatment of dye solution is performed, water ecology can be polluted in discharging it into water system. Therefore, it is needed to study of water ecological system with dye water treatment, and it takes all the circumstances into consideration.

Qualitative and quantitative analysis of furosine in fresh and processed ginsengs

  • Li, Yali;Liu, Xiaoxu;Meng, Lulu;Wang, Yingping
    • Journal of Ginseng Research
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    • v.42 no.1
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    • pp.21-26
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    • 2018
  • Background: Furosine (${\varepsilon}$-N-2-furoylmethyl-L-lysine, FML) is an amino acid derivative, which is considered to be an important indicator of the extent of damage (deteriorating the quality of amino acid and proteins due to a blockage of lysine and a decrease in the digestibility of proteins) during the early stages of the Maillard reaction. In addition, FML has been proven to be harmful because it is closely related to a variety of diseases such as diabetes. The qualitative analysis of FML in fresh and processed ginsengs was confirmed using HPLC-MS. Methods: An ion-pair reversed-phase LC method was used for the quantitative analysis of FML in various ginseng samples. Results: The contents of FML in the ginseng samples were 3.35-42.28 g/kg protein. The lowest value was observed in the freshly collected ginseng samples, and the highest value was found in the black ginseng concentrate. Heat treatment and honey addition significantly increased the FML content from 3.35 g/kg protein to 42.28 g/kg protein. Conclusion: These results indicate that FML is a promising indicator to estimate the heat treatment degree and honey addition level during the manufacture of ginseng products. The FML content is also an important parameter to identity the quality of ginseng products. In addition, the generation and regulation of potentially harmful Maillard reaction products-FML in ginseng processing was also investigated, providing a solid theoretical foundation and valuable reference for safe ginseng processing.

Change of Microbial Community and Fermentative Production of Hydrogen from Tofu Wastewater (두부 폐수를 이용한 수소생산 및 미생물의 군집 변화)

  • Jun, Yoon-Sun;Joe, Yoon-A;Lee, Tae-Jin
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.2
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    • pp.139-146
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    • 2009
  • In this study, characteristics of biological hydrogen production and microbial distribution were investigated with the wastewater of Tofu manufacturing process. Comparison of hydrogen production was conducted with acid or base pre-treatment of the wastewater. Maximum hydrogen production was acquired with combination of heat and acid treatment. Hydrogen production ($P_h$) and maximum hydrogen production rate ($R_h$) was calculated 661.01 mL and 12.21 mL/g dry wt biomass/hr from the modified Gompartz equation. Most of microbial community was analyzed as Streptococcus sp. from PCR-DGGE experiment of 16S rDNA. It was concluded that most significant microorganism for hydrogen production was Streptococcus gallolyticus sub sp. in this experiment.

Acid Drainage and Damage Reduction Strategy in Construction Site: An Introduction (건설현장 산성배수의 발생현황 및 피해저감대책)

  • Kim, Jae-Gon
    • Economic and Environmental Geology
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    • v.40 no.5
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    • pp.651-660
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    • 2007
  • Acid drainage has been recognized as an environmental concern in abandoned mine sites for long time. Recently, the environmental and structural damage by acid drainage is a current issue in construction sites in Korea. Here, the author introduces the type of damages by acid drainage in construction sites and emphasizes the importance of geoscience discipline in solving the problem. Metasedimentary rock of Okcheon group, coal bed of Pyeongan group, Mesozoic volcanic rock. and Tertiary sedimentary and volcanic rocks are the major rock types with a high potential for acid drainage upon excavation in Korea. The acid drainage causes the acidification and heavy metal contamination of soil, surface water and groundwater, the reduction of slope stability, the corrosion of slope structure, the damage on plant growth, the damage on landscape and the deterioration of concrete and asphalt pavement. The countermeasure for acid drainage is the treatment of acid drainage and the prevention of acid drainage. The treatment of acid drainage can be classified into active and passive treatments depending on the degree of natural process in the treatment. Removal of oxidants, reduction of oxidant generation and encapsulation of sulfide are employed for the prevention of acid drainage generation.

Filler-Elastomer Interactions : 4. Effect of Plasma Treatment on Surface Properties of Carbon Blacks (충전제-탄성체 상호작용 4. 플라즈마 처리가 카본블랙 표면 특성에 미치는 영향)

  • Kim, Jeong-Soon;Choi, Kyung-Eun;Park, Soo-Jin
    • Elastomers and Composites
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    • v.36 no.2
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    • pp.94-101
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    • 2001
  • In this work, the effect of NE plasma treatment generated by radio-frequency was investigated in acid-base surface values, ion adsorption characteristics, and surface free energies of carbon blacks. As the results, it was clearly found that the obvious improvement of the treatment is in the London dispersive component (${\gamma}s^L$) of surface free energy of carbon blacks. Also both electron-acceptor ( ${\gamma}s^+$) and -donor (${\gamma}s^-$) parameters for the specific component (${\gamma}s^{sp}$) were also increased with increasing the treatment time, resulting in increasing the surface functional groups of the carbon blacks studied, together with a consequence of the increases of acidic and basic surface functional groups, ion exchange, zeta potential, and ion mobility.

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Influence of Ozone Treatment on the Surface Characteristics of Montmorillonite and the Thermal Stability of Montmorillonite/polypropylene Nanocomposites (오존처리가 몬모릴로나이트의 표면특성 및 몬모릴로나이트/폴리프로필렌 나노복합재료의 열안정성에 미치는 영향)

  • Jin Sung-Yeol;Lee Jae-Rock;Park Soo-Jin
    • Composites Research
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    • v.18 no.1
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    • pp.23-29
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    • 2005
  • In this work, the effect of ozone treatment of montmorillonite (MMT) on the surface characteristics of montmorillonite and the thermal stability of MMT/polypropylene (PP) nanocomposites was investigated. The surface properties of MMT were determined by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), and X-ray photoelectron spectroscopy (XPS). Also, the thermal stability of nanocomposites was investigated in thermogravimetric analysis (TGA). As a result, it was found that the silicate interlayers of the organically modified MMT (D-MMT) were increased by about 11${\AA}$, as compared with the MMT. Also, FT-IR showed that a new peaks at $2800\~2900\;cm^{-1}$ appeared due to the $CH_2$ mode in the D-MMT The ozone treatment of the MMT led to an increase of SiO or $SiO_2$ groups on MMT surfaces, resulting in increasing the oxygen-containing functional groups on MMT. The ozonized MMT had higher thermal stability than that of untreated nanocomposites. This was due to the improvement of interfacial bonding strengths, resulting from the acid-base interfacial interactions between PP and MMT.

The Study of Corrosion Behavior for Solution and Aging Heat Treated Ti alloy (Ti 합금의 용체화열처리와 시효열처리에 따른 부식거동)

  • Baik, Shin-Young
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.22 no.1
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    • pp.138-144
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    • 2016
  • Titanium is resistant to general corrosion and in sea water because of the passivity layer film on the surface of material, but may be attacked by environments that cause breakdown of the protective oxide layer including hydrochloric, sulfuric and phosphoric acids. In this study, the Ti alloys were solution heat treatment 5hours at $1066^{\circ}C$ and $966^{\circ}C$, and followed by aging heat treated, 1, 4, 8 and 16 hours in $500^{\circ}C$, $600^{\circ}C$ and $650^{\circ}C$ respectively. The heat treated specimens were measured micro Vicker's hardness, and then accomplished electrochemical polarization test for comparing corrosion in 1N sulfuric acid solution. Additionally, micro structures were taken for corrosion tested specimens. The results showed that corrosion resistance was higher in solution heat treated alloy than base and age heat treated metal. Measured corrosion resistants were increased as increasing aging heat treatment time and temperature.