• Bulletin of the Korean Chemical Society
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• 제33권7호
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• pp.2325-2332
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• 2012

A series $[C_3Omim]$[X] of imidazolium cation-based ILs, with ether functional group on the alkyl side-chain have been synthesized and structure of the materials were confirmed by various techniques like $^1H$, $^{13}C$ NMR spectroscopy, MS-ESI, FTIR spectroscopy and EA. More specifically, the influence of changing the anion with same cation is carried out. The absorption capacity of $CO_2$ for ILs were evaluated at 30 and $50^{\circ}C$ at ambient pressure (0-1.6 bar). Ether functionalized ILs shows significantly high absorption capacity for $CO_2$. In general, the $CO_2$ absorption capacity of ILs increased with a rise in pressure and decreased when temperature was raised. The obtained results showed that absorption capacity reached about 0.9 mol $CO_2$ per mol of IL at $30^{\circ}C$. The most probable mechanism of interaction of $CO_2$ with ILs were investigated using FTIR spectroscopy, $^{13}C$ NMR spectroscopy and result shows that the absorption of $CO_2$ in ether functionalized ILs is a chemical process. The $CO_2$ absorption results and detailed study indicates the predominance of 1:1 mechanism, where the $CO_2$ reacts with one IL to form a carbamic acid. The $CO_2$ absorption capacity of ILs for different anions follows the trend: $BF_4$ < DCA < $PF_6$ < TfO < $Tf_2N$. Moreover, the as-synthesized ILs is selective, thermally stable, long life operational and can be recycled at a temperature of $70^{\circ}C$ or under vacuum and can be used repeatedly.

• 한국컴퓨터정보학회논문지
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• 제23권12호
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• pp.211-218
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• 2018

In this paper, we propose that investigating the relationship between the dynamic capacity and the technological innovation performance of firms. Based on the previous research, we divide the dynamic capacity into the adaptive capacity, absorption capacity, and productive capacity. Among the 3,400 companies responding to the technical statistics of SMEs in 2011, we performed multiple regression analysis with 2,807 except service industries. As a result, the absorptive capacity and productive capacity have a positive effect on the technological innovation performance at the 99% level, whereas the adaptive capacity has a negative effect on the technological innovation performance at the 95% level. The implications of this study are as follows. First, in order to improve the performance of technological innovation, it is important to strengthen the absorption capacity and productive capacity of companies. Absorption capacity shows that it is important to secure sufficient R & D manpower and R & D cost to utilize internal knowledge as well as to bring outside knowledge into the capacity to assimilate and utilize external knowledge. Second, the ability to commercialize a product is a capability to commercialize a technology that has succeeded in development, showing that the technology development organization must have the capability of post-development commercialization as well as technology development. Finally it shows the negative effect on adaptation capacity and innovation performance. Companies actively utilize external sources of information in order to respond to and adapt to the rapidly changing business environment. However, the results of this study show that a strategic approach is needed to use external sources of information and technology development resources. Especially as the use of external information resources and technology development resources increases.

• 한국콘텐츠학회논문지
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• 제20권8호
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• pp.274-284
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• 2020

4차 산업 혁명 시대에는 데이터의 효율적인 활용 수준이 그 기업의 성과에 큰 영향을 미친다. 본 연구는 조직 메모리 제공이 개인-직무 적합성과 개인-조직 적합성의 수준에 따라 조직성과에 미치는 영향을 흡수역량이 매개로 했을 때의 효과를 실증 분석하였다. 대기업, 중견기업, 중소기업 재직자 317명을 대상으로 설문데이터를 분석한 결과, 조직 메모리 제공이 충분한 조직은 개인-직무 및 개인-조직 적합성 모두 긍정적인 영향을 미쳤으며, 흡수역량도 긍정적인 영향을 미쳤다. 그리고 조직 메모리 제공은 개인-조직 적합성을 매개할 '때 흡수역량에 긍정적인 영향을 주는 것으로 확인되었다. 개인-직무 적합성과 개인-조직 적합성은 조직성과에 긍정적 영향을 미치나, 흡수역량을 매개할 경우는 개인-조직 적합만이 긍정적인 영향 관계가 나타났다. 본 연구는 흡수역량의 선행 요인으로 조직 IT 구축환경과 구성원들의 조직과 직무에 대한 인식을 종합적으로 분석하고, 조직성과에 미치는 영향을 동시에 실증함으로써 연구의 의의가 있다.

• 동아시아식생활학회지
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• 제11권3호
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• pp.209-218
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• 2001

This study was conducted to examine the water absorption, water-holding capacity, color and mineral contents in natural and cultured dried sea mustards on soaking treatment. Four dried samples of natural and cultured sea mustards were used for the experiments. The effects of soaking treatment on water absorption and water-holding capacity in sea mustards were examined, as the results, these were rapidly accelerated 5 minutes after soaking. It showed that water-holding capacity was significantly high in the case of high absorption of water by soaking. The L, a and b values were increased until 30 minutes after soaking. There was significant difference for potassium content between dried natural and dried cultured sea mustards and the natural sea mustard was 10 times as high as the cultured sample. All mineral elements in these materials were significantly decreased and especially, potassium were significantly more decreased at 50~80% of total content by soaking treatment. Ca/ P ratio in these materials by soaking was about 2~3 : 1 levels.

• 농업생명과학연구
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• 제44권6호
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• pp.23-26
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• 2010

펄라이트자루를 사용한 수경재배에서 급액관리방식의 일종인 배액전극제어법에 필요한 배액 이동매개체를 선발하기 위해서 시판되고 있는 친수성 매트 중에서 극세사, 융, 면 등의 배양액 흡수속도를 분석했다. 또한, 선택된 매트가 배액전극제어법을 적용하였을 때에도 높은 흡수속도를 갖는지 알아보기 위해 연구를 수행하였다. 실험결과 면이 가장 수분보유력이 뛰어났으며, 배액전극제어법을 적용했을 때에도 가장 적합한 것으로 나타났다.

• 한국산학기술학회논문지
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• 제10권3호
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• pp.602-606
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• 2009

나트륨계 흡수용액의 이산화탄소흡수특성을 알아보기 위하여 회분식 기-액 흡수평형 반응기를 이용하여 $Na_{2}CO_{3}$ 5%, 10%, 15%, 20% 수용액에 대한 이산화탄소 흡수능 및 초기흡수속도를 측정하였으며 반응온도는 $40^{\circ}C$이었다. 또한, 알칼리염계 흡수제($KHCO_3$, $CaCO_3$, $K_{2}CO_{3}$)들의 혼합에 따른 초기흡수속도를 비교하였다. 농도에 따른 실험결과 10%의 $Na_{2}CO_{3}$에서 가장 좋은 흡수능 및 흡수속도를 보였고, 알칼리염계 흡수제들 중에서 $K_{2}CO_{3}$와 혼합할 때 흡수속도가 다소 증가되었다. $Na_{2}CO_{3}$ 5% 용액의 초기흡수속도를 개선시키기 위하여 Pz와 Pp를 각각 첨가하여 실험한 결과, 증진제를 첨가함으로써 초기흡수속도를 증가시킬 수 있었다.

• 한국강구조학회 논문집
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• 제9권1호통권30호
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• pp.121-128
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• 1997

It has been reported by the existing papers that the ultimate load capacity and energy absorption capacity of the CFST column are considerably higher than those resulting from a simple addition of the capacities of the concrete and the steel tube. It is normally believed that the confined effect for the infilled concrete due to the hoop tension of steel at the parameter of cross sections can remarkably improve the ductility and energy absorption capacities of the CFST columns. This paper provides the results of a study on the load-carrying capacities and energy absorption capacities of the CFST columns, a numerical analysis method, i. e. N-M interaction curves and Moment curvature relationships. The numerical approaches are verified by comparing with the existing test results and the circular and square steel tube sections are selected to clarify the amount of confinement effects to improve the ultimate deformable capacity(a ultimate strain value) of the infilled concrete. Then, an adequate value of the ultimate strain of the infilled concrete and an equation of the ultimate capacity of the CFST column are suggested.

• 디지털융복합연구
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• 제18권9호
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• pp.159-167
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• 2020

본 연구는 경영자가 합리적인 의사결정을 할 때 경영자의 직무스트레스가 의사결정품질에 어떠한 영향을 미치는 지를 알아보고, 기업네트워크와 흡수역량을 통해 의사결정품질을 높일 수 있는지에 대해 실증분석 하고자 하였다. 이를 위해 중소기업 경영자를 대상으로 356명의 설문 데이터를 수집하였고, SPSS v.25와 AMOS v.24를 활용하여 분석하였다. 연구결과 직무스트레스 중 도전적스트레스는 의사결정품질에 정(+)의 영향을 주었고, 방해적스트레스는 의사결정품질에 부(-)의 영향을 주었으며, 기업네트워크와 흡수역량은 모두 의사결정품질에 정(+)의 영향을 주었다. 또한, 도전적스트레스와 방해적스트레스는 기업네트워크와 흡수역량을 통해 의사결정품질에 정(+)의 영향을 주는 것으로 나타났다. 이와 같은 연구결과를 통해 직무스트레스의 도전요인이 의사결정품질에 긍정적 영향을 주는 것을 검증하였으며, 기업네트워크와 흡수역량이 의사결정품질을 높이는 중요한 요인임을 확인할 수 있었다. 이와같이 결론을 논의하고 시사점 및 후속연구의 방향을 제시하였다.

• 한국산학기술학회논문지
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• 제22권3호
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• pp.763-769
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• 2021

본 연구는 지구 온난화 현상의 주원인인 이산화탄소의 제거를 목적으로 최근에 주목 받고 있는 물질인 이온성액체를 실험실 규모로 제조하였다. 음이온이 Sulfite계인 이온성 액체의 이산화탄소 흡수능, 초기흡수속도 그리고 재생성을 조사하기 위하여 기-액 흡수평형장치를 이용하여 연구하였다. 그 결과 음이온이 Sulfite계인 이온성액체 중 높은 흡수능을 갖는 이온성액체는 음이온이 ethyl sulfite인 경우이며, 특히 [beim] ethyl sulfite의 경우 흡수평형압력이 22 bar인 조건에서의 흡수력은 1.1 mol CO2/mol IL로 가장 높은 흡수력을 나타냈다. 재생성 연구에서 음이온이 Sulfite계인 이온성액체는 모두 재생후의 흡수력이 약 7%정도 감소하였으며, 이로부터 재생성이 우수함을 알 수 있다. 점도 감소를 목적으로 두 종류의 희석제를 첨가하였을 때 희석제는 단지 이온성액체의 흡수력을 감소시키는 희석효과로 작용하였으며 희석제 첨가에 따른 흡수력의 증가는 없었다. 흡수실험에 따른 점도변화의 정도를 조사하기 위해 흡수반응 전과 흡수 실험 후 재생한 시료의 점도를 측정하였으며, 실험결과 흡수실험 후 시료의 점도가 흡수실험 전보다 약 8% 정도 감소하는 경향을 보였다. 그러나 흡수제 합성은 1단계에서 이루어지며 사용되는 원료물질 또한 저렴한 장점이 있으며 흡수능에서는 우수한 재생성과 높은 안정성을 가지고 있음을 알 수 있었다.

• 한국도로학회논문집
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• 제17권2호
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• pp.99-105
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• 2015

PURPOSES: In this study, alkali-activated blast-furnace slag (AABFS) was investigated to determine its capacity to absorb carbon dioxide and to demonstrate the feasibility of its use as an alternative to ordinary Portland cement (OPC). In addition, this study was performed to evaluate the influence of the alkali-activator concentration on the absorption capacity and physicochemical characteristics. METHODS: To determine the characteristics of the AABFS as a function of the activator concentration, blast-furnace slag was activated by using calcium hydroxide at mass ratios ranging from 6 to 24%. The AABFS pastes were used to evaluate the carbon dioxide absorption capacity and rate, while the OPC paste was tested under the same conditions for comparison. The changes in the surface morphology and chemical composition before and after the carbon dioxide absorption were analyzed by using SEM and XRF. RESULTS: At an activator concentration of 24%, the AABFS absorbed approximately 42g of carbon dioxide per mass of paste. Meanwhile, the amount of carbon dioxide absorbed onto the OPC was minimal at the same activator concentration, indicating that the AABFS actively absorbed carbon dioxide as a result of the carbonation reaction on its surface. However, the carbon dioxide absorption capacity and rate decreased as the activator concentration increased, because a high concentration of the activator promoted a hydration reaction and formed a dense internal structure, which was confirmed by SEM analysis. The results of the XRF analyses showed that the CaO ratio increased after the carbon dioxide absorption. CONCLUSIONS : The experimental results confirmed that the AABFS was capable of absorbing large amounts of carbon dioxide, suggesting that it can be used as a dry absorbent for carbon capture and sequestration and as a feasible alternative to OPC. In the formation of AABFS, the activator concentration affected the hydration reaction and changed the surface and internal structure, resulting in changes to the carbon dioxide absorption capacity and rate. Accordingly, the activator ratio should be carefully selected to enhance not only the carbon capture capacity but also the physicochemical characteristics of the geopolymer.