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Two Crystal Structures of Ag+-and TI+-Exchanged Zeolite X, Ag27TI65-X and Ag23TI69-X

  • Kim, Soo-Yeon;Choi, Eun-Young;Kim, Yang
    • Bulletin of the Korean Chemical Society
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    • v.23 no.12
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    • pp.1759-1764
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    • 2002
  • Two crystal structures of dehydrated $Ag^+-andTl^+$-exchanged zeolite X$Ag_{27}Tl_{65-}X\;and\;Ag_{23}Tl_{69-}X$have been determined by single-crystal X-ray diffraction techniques in the cubic space group Fd3 at 21(1) $^{\circ}C(a=24.758(4)\AAa=24.947(4)$, ${\AA}respectively).$, Their structures were refined to the final error indices $R_1$=0.055 and $wR_2$=0.057 with 375 reflections, and $R_1$=0.057 and $wR_2$=0.057 with 235 reflections, respectively, for which I > $3\sigma(I).$ In the structure of $Ag_{27}Tl_{65-}X,\;27\;Ag^+$ ions were found at two crystallographic sites: 15$Ag^+$ ions at site I at the center of the hexagonal prism and the remaining 12$Ag^+$ ions at site II' in the sodalite cavity. Sixty-five $Tl^+$ ions were located at three crystallographic sites: 20$Tl^+$ ions at site II opposite single six-rings in the supercage, 18$Tl^+$ ions at site I' in the sodalite cavity opposite the D6Rs, and the remaining 27$Tl^+$ ions at site III' in the supercage. In the structure of $Ag_{23}Tl_{69-}X$, 23$Ag^+$ ions were found at two crystallographic sites: 15 at site I and 8 at site II'. Sixty-nine $Tl^+$ ions are found at four crystallographic sites: 24 at site II, 17 at stie I', and the remaining 28 at two III' sites with occupancies of 22 and 6.

Direct Fabrication of a-Si:H TFT Arrays on Flexible Substrates;Principal Manufacturing Challenges and Solutions

  • O’Rourke, Shawn M.;Loy, Douglas E.;Moyer, Curt;Ageno, Scott K.;O’Brien, Barry P.;Bottesch, Dirk;Marrs, Michael;Dailey, Jeff;Bawolek, Edward J.;Trujillo, Jovan;Kaminski, Jann;Allee, David R.;Venugopal, Sameer M.;Cordova, Rita;Colaneri, Nick;Raupp, Gregory B.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.251-254
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    • 2007
  • Principal challenges to $\underline{direct\;fabrication}$ of high performance a-Si:H transistor arrays on flexible substrates include automated handling through bonding-debonding processes, substrate-compatible low temperature fabrication processes, management of dimensional instability of plastic substrates, and planarization and management of CTE mismatch for stainless steel foils. Viable solutions to address these challenges are described.

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Chilling Temperature and Humidity to Break Diapause of the Bumblebee Queen Bombus terrestris

  • Yoon, Hyung-Joo;Lee, Kyeong-Yong;Hwang, Jae-Sam;Park, In-Gyun
    • International Journal of Industrial Entomology and Biomaterials
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    • v.20 no.2
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    • pp.93-98
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    • 2010
  • Bumblebees are widely used to pollinate various crops, especially tomato, in greenhouses and fields. An artificial hibernation is essential for year-round rearing of the bumblebee, which passes through one generation per year. Here, we investigated whether a chilling temperature and humidity affect artificial hibernation of the bumblebee queen Bombus terrestris. In chilling temperature regimes of $0^{\circ}C$, $2.5^{\circ}C$, $5^{\circ}C$, $7.5^{\circ}C$ or $12.5^{\circ}C$ under constant humidity >70%, the queens stored at $2.5^{\circ}C$ exhibited the highest rate of survival, which was 74.0% at one month, 67.0% at two months, 60.0% at three months, 46.0% at 4 months, 33.0% at 5 months, and 24.0% at 6 months. Rates of survival decreased at the following temperatures: $0^{\circ}C$, $5^{\circ}C$, $7.5^{\circ}C$ and $12.5^{\circ}C$. Colony developmental characteristics after diapause were 1.2- to 1.5-fold higher than those of queens stored at $5^{\circ}C$. In terms of chilling humidity, the queens hibernated at 70% under $2.5^{\circ}C$ exhibited the highest rate of survival, which was $93.3{\pm}3.4%$ at one month, $83.3{\pm}0.0%$ at two months, $76.7{\pm}0.0%$ at 3 months and $36.7{\pm}12.1%$ at 5 months. The rates of oviposition, colony foundation and progeny-queen production of queens hibernated at 70% were 80.8%, 30.8% and 30.8%, respectively. These values correspond to 1.7- to 3.3-fold increases in comparison to queens stored at 50% humidity. Therefore, $2.5^{\circ}C$ and 70% R.H. were the favorable chilling temperature and humidity conditions for diapause break of B. terrestris queens.

The Community Structure and Spatial Distribution of Meiobenthos in the Kanghwa Tidal Flat, West Coast of Korea

  • Kim, Dong-Sung;Je, Jong-Geel;Lee, Jae-Hac
    • Ocean and Polar Research
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    • v.22 no.1
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    • pp.15-23
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    • 2000
  • The community structure of meiobenthos was studied in tidal flats of Kanghwado in November, 1997. Nematodes were the most dominant group among 18 total meiofaunal groups at most stations except for at lower tidal flats where the most abundant groups were harpacticoid copepods. Meiobenthos were the most abundant in the upper 1cm and their density decreased depending on the depth from the surface. The highest density of the meiobenthos was 6,094 inds. $10cm^{-2}$ at the upper tidal flat, while the lowest was 1,524 ind. $10cm^{-2}$ at the lower tidal flat. The density was higher in general at the upper tidal flats, but decreased at the stations toward lower tidal flat at all transect lines. At all transect lines, nematodes decreased as stations were along toward lower tidal flat whereas harpacticoids increased. The values of N/C(nematodes/benthic harpacticoids) ratio were higher at the upper tidal flats than the lower tidal flats at all transect lines.

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The Relationships between Preschool Teachers' Personality Traits and Their Relationships at Workplace

  • Jin, Byoung Sook;Kim, Sang Lim
    • International Journal of Advanced Culture Technology
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    • v.6 no.3
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    • pp.53-58
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    • 2018
  • Preschool teachers' relationships at workplace is an important component that affects the work performance of caring and educating young children. This study investigated the connection between preschool teachers' personality traits and their relationships at workplace. The participants were two hundred and eighty two teachers in 55 preschools and asked to answer the survey questionnaires. Two research questions were investigated; (1) are there correlations between preschool teachers' personality traits and their relationships at workplace? (2) do preschool teachers' personality traits affect their relationships at workplace? The results showed that preschool teachers' personality traits were correlated with their relationships at workplace; neuroticism showed a negative correlation while the other four (extraversion, openness, agreeableness, and conscientiousness) showed positive correlations with relationships at workplace. In addition, preschool teachers' personality traits had effects on their relationships at workplace in overall. Especially, neuroticism, agreeableness, and conscientiousness were revealed as significantly influencing personality traits on preschool teachers' relationships at workplace.

Variation of Plant Temperature at Joining Parts of Grafted Watermelon Seedlings Graft-taken under Different Light Quality (상이한 광질하에서 활착된 수박 접목묘 결합 부위의 식물체온 변화)

  • Kim, Y.H.;Lee, S.H.
    • Journal of Biosystems Engineering
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    • v.31 no.5 s.118
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    • pp.449-453
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    • 2006
  • Effect of light quality on plant temperatures at joining parts of grafted watermelon seedlings was investigated using a thermal imaging system in this study. Plant temperatures at joining parts lowered than those at stem region during graft-taking. However, difference in plant temperatures at joining parts and at stem region decreased by days after graft-taking. Plant temperatures of grafted seedlings graft-taken under white, blue, red, and blue + red fluorescent lamps repeatedly fluctuated high at photoperiod and low at dark period. Considering the variation of plant temperatures at joining pa퍼5, the illumination of blue and red light as well as white light will be effective for grafting of grafted watermelon seedlings. It is recommended that air temperature around grafted seedlings should be maintained at 27 to $29^{\circ}C$ for enhancing the physiological reaction of callus and for the smooth joining of scion and rootstock.

Effects of Confinement and Transport Stress on Physiological Condition in Olive Flounder (Paralichthys olivaceus)

  • Hur, Jun-Wook;Park, Cheol-Young;Chang, Young-Jin;William H. Neill
    • Proceedings of the Korean Aquaculture Society Conference
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    • 2003.10a
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    • pp.105-106
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    • 2003
  • Physiological responses (cortisol, glucose, lactic acid, osmolality and hematology) of olive flounder (Paralichthys olivaceus) to stressors associated with confinement and subsequent transport were investigated. Specimens were subjected to confinement stress for 3 h, prior to transport for 15 h. Two different size cohorts of the fish, large (839.6$\pm$162.7 g) and small (98.2$\pm$14.8 g), were used. Experimental cohorts of the fish were divided into 3 groups for blood sampling: group A, sampled at the beginning of confinement and 3 h before transport (BT, -3 h), after confinement and at the beginning of transport (BT, 0 h), 3 h after transport had begun (AT, 3 h), and after 15 h transport (AT, 15 h); group B, sampled at BT, 0 h, at AT, 3 h, and at AT, 15 h; and, group C, sampled at AT, 3 h, and at AT, 15 h. In the cohort of large fish, plasma cortisol levels of the A group were increased over time, from 4.2 ng/ml (BT, -3 h), to 92.0 ng/ml (BT, 0 h), 118.5 ng/ml (AT, 3 h) and 105.5 ng/ml (AT, 15 h). A similar pattern was evident in the B group, in which cortisol increased from 47.5 ng/ml (BT, 0 h) to 53.5 ng/ml (AT, 15 h); and, for the C group, in which cortisol increased from 43.5 ng/ml (AT, 3 h) to 71.5 ng/ml (AT, 15 h). Glucose levels of the A group also were significantly increased, from 39.5 mg/dl (BT, -3 h), to 121.0 mg/dl (BT, 0 h), 298.0 mg/dl (AT, 3 h) and 260.5 mg/dl (AT, 15 h). Lactic acid levels increased markedly during transport, from less than 1 mmol/L (BT, 0 h) to 12.0 mmol/L (AT, 15 h). Plasma osmolality increased from 405.5 mOsm/kg (BT, -3 h, for group A) to values near 500 mOsm/kg subsequent to confinement and transport. In the small-size cohort, plasma cortisol, glucose, lactic acid and osmolality levels showed similar but less pronounced trends than those observed for the large-size cohort. This research provides baseline data on cortisol, glucose, lactic acid, osmolality and hematological responses to confinement and transport, which should be useful to aquaculturists working with olive flounder and to scientists studying other flatfish species.

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Feasibility Analysis of Introducing CM at Risk Delivery Method to the Korean Public Construction Industry by Analyzing Attributes of the Projects (대상공사의 특성요인 적합도 분석에 의한 공공부문 'CM at Risk 방식' 도입의 타당성 분석)

  • Koh, Min-Hyeok;Kim, Yea-Sang;Kwon, Soon-Wook;Chin, Sang-Yoon
    • Korean Journal of Construction Engineering and Management
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    • v.11 no.2
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    • pp.3-14
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    • 2010
  • A high degree of management skills and functions is essential to the success of construction projects. While the various construction management delivery methods have been realized as the solutions, Korean government is planning to introduce 'CM at Risk Method' to the public construction projects. However, even if its effect has been verified successful in the international market, it must be considered before legally adapting the method that it would be suitable to our public sector, In this respect, the purpose of this study is to evaluate and analyze feasibility of 'CM at Risk Method'. In order to do that, 15 attributes of construction projects were found, which were suitable to 'CM at Risk Method' in general, 'CM at Risk-GMP Method', and 'CM at Risk-Cost Reimbursable Method' and suitability of each attribute to each of 9 categories of public construction facilities was evaluated by questionnaire survey to CM specialists. Results showed that 'CM at Risk Method' might not bring improper effect to the industry but due to the characteristic of public sector, the effect would be very limited.

Cloning a Mannanase 26AT Gene from Paenibacillus woosongensis and Characterization of the Gene Product (Paenibacillus woosongensis으로부터 Mannanase 26AT 유전자의 클로닝과 유전자 산물의 분석)

  • Yoon, Ki-Hong
    • Journal of Life Science
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    • v.27 no.9
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    • pp.1003-1010
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    • 2017
  • An open reading frame coding for mannanase predicted from the partial genomic sequence of Paenibacillus woosongensis was cloned into Escherichia coli by polymerase chain reaction amplification, and completely sequenced. This mannanase gene, designated man26AT, consisted of 3,162 nucleotides encoding a polypeptide of 1,053 amino acid residues. Based on the deduced amino acid sequence, Man26AT was identified as a modular enzyme, which included a catalytic domain belonging to the glycosyl hydrolase family 26 and two carbohydrate-binding modules, CBM27 and CBM11. The amino acid sequence of Man26AT was homologous to that of several putative mannanases, with identity of 81% for P. ihumii and identity of less than 57% for other strains of Paenibacillus. A cell-free extract of recombinant E. coli carrying the man26AT gene showed maximal mannanase activity at $55^{\circ}C$ and pH 5.5. The enzyme retained above 80% of maximal activity after preincubation for 1 h at $50^{\circ}C$. Man26AT was comparably active on locust bean gum (LBG), galactomanan, and kojac glucomannan, whereas it did not exhibit activity on carboxymethylcellulose, xylan, or para-nitrophenyl-${\beta}$-mannopyranoside. The common end products liberated from mannooligosaccharides, including mannotriose, mannotetraose, mannopentaose, and mannohexaose, or LBG by Man26AT were mannose, mannobiose, and mannotriose. Mannooligosacchrides larger than mannotriose were found in enzymatic hydrolyzates of LBG and guar gum, respectively. However, Man26AT was unable to hydrolyze mannobiose. Man26AT was intracellularly degraded into at least three active proteins with different molecular masses by zymogram.

A Study on the Characteristics of Plant Fiber Materials for Diffusion Tensor Imaging Phantom (확산텐서영상 팬텀 제작을 위한 식물섬유 재료의 특성에 관한 연구)

  • Lee, Jung-Hoon
    • Journal of radiological science and technology
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    • v.43 no.6
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    • pp.475-480
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    • 2020
  • The purpose of this study was to reconstruct diffusion tensor tractography (DTT) using stem of garlic and asparagus for in vitro phantom of diffusion tensor imaging (DTI), and to compare and evaluate the fractional anisotropy (FA) value and the apparent diffusion coefficient (ADC) value to determine whether it can be used as materials for in vitro phantoms. Among various plant fibers such as stem of garlic, palmae, cotton, asparagus, etc., stem of garlic and asparagus, which are considered to be the most suitable for making phantoms, and whose shape is considered to be the most suitable for making phantoms, were selected and tests were conducted. Holes were made in a plastic bucket at an angle of 0°, 30°, 60°, 90°, and 120°, then tubes were inserted. In the tube, asparagus and stem of garlic were inserted as far in as possible, and the inserted tube was inserted into the center of the heat bathed gelatin to harden. We were able to reproduce DTT images in asparagus and stem of garlic. Fiber tissues of asparagus and stem of garlic did not show complete connectivity, but the reconstructed images of DTT showed good connectivity. The FA values of asparagus in the tubes were 0.198 at 0° (straight), 0.207 at 30°, 0.187 at 60°, 0.231 at 90°, and 0.204 at 120°. In addition, the FA values of stem of garlic in the tubes were 0.235 at 0°, 0.236 at 30°, 0.216 at 60°, 0.218 at 90°, and 0.257 at 120°. The ADC values of asparagus in the tubes were 1.545 at 0°, 1.677 at 30°, 1.629 at 60°, 1.535 at 90°, and 1.725 at 120°. In addition, the ADC values of stem of garlic in the tubes were 1.252 at 0°, 1.396 at 30°, 1.698 at 60°, 1.756 at 90°, and 1.466 at 120°. For the best expressed DTT reconstruction image, it showed the longest connectivity in the straight line as we hypothesized. In addition, when comparing the FA values and ADC values of fiber tissues of stem of garlic and asparagus, FA value was generally higher in stem of garlic and ADC value was slightly higher in asparagus.