• Transactions on Electrical and Electronic Materials
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• 제14권6호
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• pp.324-328
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• 2013

An alternating current (AC) electrical treeing phenomena in an epoxy system with low chlorine BDGE (1,4-butanediol diglycidyl ether) was studied in a needle-plate electrode arrangement. To measure the treeing propagation rate and breakdown time, a constant AC of 10 kV with three different electric field frequencies (60, 500, and 1,000 Hz) was applied to the needle-plate electrode specimen at $130^{\circ}C$ in aninsulating oil bath. The treeing propagation rate of the DGEBA/high-chlorine BDGE system was higher than that of the DGEBA/low-chlorine BDGE system and the breakdown time of the system with high-chlorine BDGE was lower than that of the system with low-chlorine BDGE. These results implied that chlorine had a negative effect on the electrical insulation property of the epoxy system. As the electric field frequency increased, the treeing propagation rate increased and the breakdown time decreased.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1996년도 추계학술대회 논문집
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• pp.425-428
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• 1996

Treeing deterioration which is one of the main cause of breakdown in insulating materials is affected by temperature, applied voltage and frequency. In this study, GN was introduced to improve impact strength of DGEBA/MDA system and the temperature dependence of AC treeing deterioration in this system was investigated. Dielectric breakdown strength decreased with the increment of temperature. As temperature increased, the growth rate of tree Increased.

• Transactions on Electrical and Electronic Materials
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• 제14권4호
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• pp.221-224
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• 2013

Effects of ambient temperature on the ac electrical treeing and breakdown behaviors in an epoxy/layered silicate (1 wt%) were carried out in needle-plate electrode geometry. A layered silicate was exfoliated in an epoxy base resin,, using our ac electric field apparatus. To measure the treeing initiation and propagation, and the breakdown rate, constant alternating current (ac) of 10 kV (60 Hz) was applied to the specimen in a needle-plate electrode arrangement, at $30^{\circ}C$, $90^{\circ}C$ or $130^{\circ}C$ of insulating oil bath. At $30^{\circ}C$, the treeing initiation time and the breakdown time in the epoxy/layered silicate (1 wt%) system were 1.4 times higher than those of the neat epoxy resin. At $90^{\circ}C$ (lower than Tg), electrical treeing was initiated in 55 min, and propagated until 1,390 min at the speed of $0.35{\times}10^{-3}mm/min$, which was 4.4 times higher than that at $30^{\circ}C$; however, there was almost no further treeing propagation after 1,390 min. At $130^{\circ}C$ (higher than Tg), electrical treeing was initiated in 44 min, and propagated until 2,000 min at the speed of $0.96{\times}10^{-3}mm/min$. Typical branch type electrical treeing was obtained from the neat epoxy and epoxy/layered silicate at $30^{\circ}C$, while bush type treeing was observed out from the needle tip at $90^{\circ}C$ and $130^{\circ}C$.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제49권8호
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• pp.455-461
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• 2000

The inhibiting effects of electrical treeing and insulation properties of LDPE contained with treeing inhibitors was studied under radiation environment. Barbituric acid and its derivatives were selected as treeing inhibitors. The inception voltage and growth of tree, AC breakdown strength, volume resistivity, high frequency capacitance, and dissipation factor were observed as a function of dose(up to 1000 kGy). And also, measurements of thermo-luminescence(TL), and gel content were carried out. Crosslinked low density polyethylene(XLPE) contained with treeing inhibitors shows better insulation characteristics such as electrical tree propagation, AC breakdown strength, and volume resistivity than those of pure LDPE. The most effective treeing inhibitor was found on the barbituric acid contained XLPE.

• 전기학회논문지
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• 제62권11호
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• pp.1571-1577
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• 2013

Electrical tree structure is one of the most important influencing factors for electrical treeing characteristics in polymers. In this paper, we focused on the structure characteristics of electrical treeing in epoxy resins (original) insulation under different high-frequency voltages (60, 500, 1000Hz). Effects of voltage frequency on the ac electrical treeing phenomena in an epoxy resins were carried out in needle-plate electrode arrangement. To measure the treeing initiation and propagation, and the breakdown rate, constant AC of 10 kV with three different voltage frequencies (60, 500 and 1,000 Hz) was applied to the specimen in needle-plate electrode specimen at $30^{\circ}C$ of insulating oil bath. At 60 Hz, the treeing initiation time was 360 min and the propagation rate was $6.85{\times}10^{-4}mm/min$, and the morphology was dense branch type. As the voltage frequency increased, the treeing initiation time decreased and the propagation rate increased. At 1,000 Hz, the treeing initiation time was 0 min and the propagation rate was $7.81{\times}10^{-2}mm/min$, and the morphology was dense bush type.

• Transactions on Electrical and Electronic Materials
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• 제14권5호
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• pp.278-281
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• 2013

The effects of electric field frequency on the AC electrical treeing phenomena in an epoxy/layered silicate (1.5 wt%) were investigated in a needle-plate electrode arrangement. A layered silicate was exfoliated in an epoxy-base resin with AC electric field apparatus. To measure the treeing initiation and propagation- and the breakdown rate, a constant alternating current (AC) of 10 kV with three different electric field frequencies (60, 500, and 1,000 Hz) was applied to the specimen in the needle-plate electrode specimen in an insulating oil bath at $130^{\circ}C$. At 60 Hz, the treeing initiation time was 12 min, the propagation rate was $0.24{\times}10^{-3}$ mm/min, and the morphology was a dense branch type. As the electric field frequency increased, the treeing initiation time decreased and the propagation rate increased. At 1,000 Hz, the treeing initiation time was 5 min, the propagation rate was $0.30{\times}10^{-3}$ mm/min, and the morphology was a dense bush type.

• Transactions on Electrical and Electronic Materials
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• 제13권3호
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• pp.149-152
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• 2012

The effects of amino silane coupling agent on the AC electrical treeing and breakdown behaviors in an epoxy/layered silicate (1 wt%) were examined in needle-plate electrode geometry. A layered silicate was exfoliated in an epoxy base resin by using our AC electric field apparatus. To measure the tree initiation and propagation and the breakdown rate, an alternating current (AC) of 10 kV (60 Hz) was applied to the specimen in needle-plate electrode arrangement with a $30^{\circ}C$ insulating oil bath. In the epoxy/amino silane system, the tree initiation time was 11.5 times higher and the breakdown time was 17.9 times higher than those of the neat epoxy resin. The tree initiation time in the epoxy/layered silicate (1 wt%) system with the amino silane was 2.0 times higher, and the breakdown time was 1.5 times higher than those of the epoxy/layered silicate (1 wt%) system.

• Transactions on Electrical and Electronic Materials
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• 제13권2호
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• pp.85-88
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• 2012

Studies on the effects of layered silicate content on the AC electrical treeing and breakdown behaviors of epoxy/layered silicate nanocomposites were carried out in needle-plate electrode geometry. Wide-angle X-ray diffraction (WAXD) analysis and transmission electron microscopy (TEM) observation showed that 1 wt% of the multilayered silicate was fully exfoliated into nano-sized monolayers in the epoxy matrix however, over 3 wt% of the silicate was in an intercalated state. When 1 wt% layered silicates were incorporated, an electrical tree was initiated in 439 min and propagated at a speed of 2.3 ${\mu}m$/min after applying 781.4 kV/mm, representing a decreased in starting initiation time by a factor of 11.0 and increase in propagation speed by a factor 8.2 in comparison with neat epoxy resin. These values were in great decline after the layered silicate content was increased to 3wt% which implies that the exfoliated silicate blocked the tree initiation and propagation processes effectively. However the effect was largely decreased in the intercalated state.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2002년도 추계학술대회 논문집 전기물성,응용부문
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• pp.179-182
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• 2002

XLPE compound have used for insulation of 22.9(kV) power cable. But tree retardant power cable has developed and is going to br used commonly. TR XLPE compound retard production and growth of water tree. In this paper, tensile strength, elongation at break, degree of crosslinking, lightning impulse test, AC breakdown test, cyclic aging for 14days and accelerated water treeing test of TR XLPE insulated power cable were examined according to the KEPCO buying spec. & AEIC CS 5-94 standards. before and after As the result, tensile strength, elongation at break and degree of crosslinking test results of TR XLPE insulation were higher than requirement values. After accelerated water treeing test for 120 days, 240 days and 360 days, AC breakdown voltages were not decreased for accelerated water treeing aging duration

• 한국안전학회지
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• 제27권2호
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• pp.13-19
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• 2012

The effectiveness of treeing resistance in low density polyethylene containing azocompounds were investigated under radiation environments. 4-(4-nitrophenylazo)-1-naphthol and 4-(4-nitrophenylazo) resorcinol were selected for treeing inhibitors. LDPE containing the additives were crosslinked with dicumyl peroxide, irradiated by $Co^{60}$ ${\gamma}$-ray in the presence of air at room temperature. Treeing inception voltage, AC breakdown strength measurements were carried out for electrical insulation characteristics, thermoluminescence and gel contents were analyzed as various irradiation doses also. LDPE with treeing inhibitors showed much better insulation characteristics than pure LDPE. It is interpreted that molecular structures, polar groups and the type of radicals connected on the benzene ring of the additives affected electrical characteristics. From the results, 4-(4-nitrophenylazo) resorcinol was the most effective upon the best treeing and radiation resistance.