• 대한금속재료학회지
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• 제49권8호
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• pp.601-607
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• 2011

The study investigated the influence of current density on the corrosion-protection properties of an AZ91 Mg alloy subjected to plasma electrolytic oxidation coating. The present coatings were carried out under an AC condition at three different current densities, i.e., 100, 150, and $200mA/cm^2$. From microstructural observations, the micro cracks connecting each micro pore were pronounced on the oxide surface of the samples coated at current densities higher than $150mA/cm^2$ since increasing the current density in this study led to an increment in the relative volume fraction of the MgO compound. Based on potentio dynamic polarization and immersion tests, the sample coated at a current density of $100mA/cm^2$ showed superior corrosion resistance.

• 한국마린엔지니어링학회:학술대회논문집
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• 한국마린엔지니어링학회 2005년도 후기학술대회논문집
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• pp.192-193
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• 2005

Magnesium thin films were prepared on cold-rolled steel substrates by RF(Radio Frequency) magnetron sputtering technique.$^{1)}$ The crystal orientation and monitoring of the deposited films were investigated by using XRD(X-ray Diffraction) and EIS(Electrochemical Impedance Spectroscopy), respectively. The corrosion rates of Mg thin films deposited with different argon gas pressure and substrate bias voltage were monitored by AC impedance method under a cyclic wet-dry condition, which was conducted by exposure to alternate conditions of 1h immersion in 3%NaCl solution and 5h drying at 60% RH and 25$^{\circ}C$. The result of corrosion rate of Mg thin films deposited at various Ar gas pressures and substrate bias voltage under wet-dry cyclic exposure in chloride-containing solutions was showed the following conclusions. At the region I during the onset of the wet cycle, corrosion rate showed relatively low value. The increase in the Corrosion rate of region II is due to the increase in the chloride concentration. Corrosion rate of region III during the onset of the cycle zero and salt crystals remain on the metal surface.$^{2)}$

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2017년도 춘계학술대회 논문집
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• pp.80-80
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• 2017

Titanium and its alloys that have a good biocompatibility, corrosion resistance, and mechanical properties such as hardness and wear resistance are widely used in dental and orthopedic implant applications. However, they do not form a chemical bond with bone tissue. Plasma electrolytic oxidation (PEO) that combines the high voltage spark and electro-chemical oxidation is a novel method to form ceramic coatings on light metals such as tita-nium and its alloys. This is an excellent re-producibility and economical, because the size and shape control of the nano-structure is relatively easy. Silicon (Si), manganese (Mn), and magne-sium (Mg) have a useful to bone. Particularly, Si has been found to be essential for normal bone, cartilage growth, and development. Mn influences regulation of bone remodeling be-cause its low content in body is connected with the rise of the concentration of calcium, phosphates and phosphatase out of cells. Pre-studies have shown that Mg plays very im-portant roles in essential for normal growth and metabolism of skeletal tissue in verte-brates and can be detected as minor constitu-ents in teeth and bone. In this study, Electrochemical behavior of plasma electrolytic oxidized films formed in solution containing Mn, Mg and Si ions were researched using various experimental in-struments. A series of Si-Mn-Mg coatings are produced on Ti dental implant using PEO, with the substitution degree, respectively, at 5 and 10%. The potentiodynamic polarization and AC impedance tests for corrosion behav-iors were carried out in 0.9% NaCl solution at similar body temperature using a potentiostat with a scan rate of 1.67mV/s and potential range from -1500mV to + 2000mV. Also, AC impedance was performed at frequencies anging from 10MHz to 100kHz for corrosion resistance.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.350-350
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• 2010

에너지 효율이 높은 LED조명을 사용하면 에너지 절감, 이산화탄소, 환경오염물질 배출 감소의 효과를 얻을 수 있다. 그러나 LED조명에서 발생하는 열은 LED조명의 수명과 에너지 효율을 감소시킨다. 따라서 LED조명을 상용화하기 위해서는 LED조명에서 발생되는 열을 효율적으로 제거하는 것이 필수적이며 LED조명 방열판의 생산단가 또한 낮아야 한다. 이러한 조건을 충족하는 LED조명용 방열판은 Al 6063이 주로 사용되고 있다. Al 6063은 열전도 특성이 우수하고 생산단가가 저렴하다. 그러나 100 W급 이상의 고출력 LED조명에 Al 6063을 사용하기 위해서는 Al 6063의 열 방출 특성을 향상시킬 필요가 있다. 금속의 열 방출 특성을 향상시키기 위해서 주로 이용되는 방법은 표면적을 극대화 시키는 것이다. 금속에 국부적인 깊이 부식을 일이키는 Pitting corrosion을 이용하면 저렴한 비용으로 Al 6063의 표면적을 극대화하여 방열판의 열 방출 특성을 향상시킬 수 있다. 실험에 사용한 기본적인 구조의 Al 6063 방열판의 크기는 $50{\times}50{\times}30(mm)$ 이며 1M HCl + 0.05M $H_2SO_4$에서 $I_a$ = +40 mA, $t_a$ = 60 ms, $I_c$ = -40 mA, $t_c$ =20 ms로 50, 100, 200 cycle AC 에칭 하였다. Pitting corrosion된 방열판은 $3W{\times}3$개의 LED모듈에서 1시간 발광 시킨 후, 열화상 카메라를 이용하여 표면온도를 측정하였다. 실험결과 AC에칭 cycle이 증가할수록 발열특성이 우수하였으며, Pitting corrosion을 이용하지 않은 방열판에 비해 최대 $5^{\circ}C$의 표면온도 감소가 이루어졌다. 본 연구를 통해, 저렴하면서도 열 방출 특성이 높은 방열판을 설계하면, 고출력 LED조명의 상용화를 앞당길 수 있을 것이다.

• 한국가스학회지
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• 제5권4호
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• pp.21-26
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• 2001

최근 국내에서는 효율적인 공간활용을 위해 해저터널을 이용하여 전력을 공급하는 것이 시도되고 있으며, 해저터널 내에 에너지 공급 기간시설물(진력케이블, 가스배관, 송유관, 지역난방배관 등)들이 같이 포설될 수 있으면 공사비 절감의 효과는 엄청날 것이므로 관심도가 높아지고 있다. 최근, 국내에서도 해저터널 내에 가스배관과 전력선이 병행 시공되는 경우가 발생하여 가스배관에 대한 안전성에 대한 평가가 요구되고 있다. 따라서 본 논문에서는 해해저터널 내 고전압 전력케이블에 의한 가스배관의 교류부식, 가스배관의 코팅과 용융. 절연 플랜지, 전기방식용 정류기 등의 전기방식설비의 안정성에 대하여 검토함으로써, 최종적으로 가스배관의 안전성을 평가$\cdot$연구하였다.

• 한국가스학회지
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• 제4권3호
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• pp.26-32
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• 2000

최근 국내에서는 효율적인 공간활용을 위해 해저터널을 이용하여 전력을 공급하는 것이 시도되고 있으며, 해저터널내에 에너지 공급 기간시설물(전력케이블, 가스배관, 송유관, 지역난방배관 등)들이 같이 포설될 수 있으면 공사비 절감의 효과는 엄청날 것이므로 관심도가 높아지고 있다. 따라서 본 논문에서는 세계최초로 몰타르(Mortar)로 충진되어 있는 해저터널에서 전력케이블과 가스배관이 병행할 경우, 유도에 의한 교류부식에 대하여 검토하였으며, 아직 국내에는 유도전압 제한치가 마련되어 있지 않으므로 인$\cdot$축의 안전적인 측면과 시스템의 보안적인 측면을 세심하게 검토하여 이에 대한 제한치를 정립하였고, 유도전압이 최소가 되도록 전력케이블의 상배치를 최적으로 설계하였다. 이 결과들은 실 사례에 적용되었다.

• 한국자동차공학회논문집
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• 제10권6호
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• pp.171-177
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• 2002

Metal matrix composites had generated a lot of interest in recent times because of significant in specific properties, it was also highlighted as the material of frontier industry because strength, heat-resistant, corrosion-resistant and wear-resistant were superiored. In recent years, the study of metal matrix composite has increased by aluminum alloy. The study is based on the tribological properties of AC4CH that is a part of the mechanical property of metal matrix composites. Metal matrix composite that is produced from matrix material AC4CH and reinforcement SiO$_2$, Al$_2$O$_3$ and TiO$_2$ are added to the metal matrix composite fur strength so binding among the whisker can take place. Each metal matrix composite is produced using the squeeze casting method. To test for tribe a pin-on-disk machine and lubricant is used without paraffine 8.2CST at room temperature which is 40$\^{C}$. As the results of this study, the tribological properties of each specimen are more improved than AC4CH. The variation of coefficient resistance is more stable at the AC4CH and TiO$_2$, but the variation rates are higher at the inanimate binder.

• 한국해양공학회지
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• 제18권1호
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• pp.75-79
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• 2004

Organic coatings are widely used to control of the corrosion of a steel structure. The water in coatings may cause the coatings to swell, leading to the degradation of the coatings. In addition, water affects the permeation of oxygen and other corrosive agents, and consequently, the presence of such substances at coating-metal interface promotes corrosion of the metal substrate. In this study, the anticorrosive properties of 4 types of coating, such as epoxy-epoxy, epoxy-urethane, urethane-epoxy, urethane-urethane, were evaluated. The evaluation tests were conducted under cyclic water-absorption/desorption conditions, consisting of alternative exposure to diluted 0.001M-LiCl(a$H_2O$≒1) and concentrated 10M-LiCl(a$H_2O$≒0.15). The anticorrosive performance of coatings was found to decrease in the order of urethane-urethane > urethane-epoxy > epoxy-epoxy coating.

• Corrosion Science and Technology
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• 제5권5호
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• pp.177-180
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• 2006

The anticorrosive performance of epoxy coating was examined by using the hygrothermal cyclic test and the degradation mechanism of the coating was investigated by using the AC impedance method. The relationship between the results obtained from different tests was studied. It was revealed that the hygrothermal cyclic test can be used as an effective acceleration test for the degradation of organic coating. It was also found in hygrothermal cyclic test that the epoxy coatings have the resistance to stresses at some extent. The degradation of organic coating seems to be caused by the decrease of resistance of coating and the increase of both capacitance and free volume in the organic coating.

• 대한금속재료학회지
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• 제47권10호
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• pp.652-659
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• 2009

Many ancient and historical artifacts were made by copper and its alloys. In the case of outdoor exposure artifacts, the surface could be suffered from corrosion and tarnish by the reaction with its environment. In order to preserve the artifacts, surface treatment would be needed and BTA coating has been usually applied to tin-bronze. This paper dealt with the evaluation of the properties of BTA coated film using a linear polarization method and AC impedance measurement. On the base of corrosion rate and film resistance for the specimen formed by coating process, optimum coating conditions are as follows; 3 cycles brushing or 3 cycles spraying coatings for natural dried process and 1 cycle brushing coating or 5 cycles spraying coating for hot-air dried process.