• Title/Summary/Keyword: A Heavy Metal

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A Study on the Solidification of Heavy Metal Ion by Phosphate Magnesia Cement (인산염 마그네시아 시멘트에 의한 중금속 이온 고정화에 관한 연구)

  • Choi, Hun;Choi, Jung-Ok;Kang, Hyun-Ju;Song, Myong-Shin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.321-322
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    • 2009
  • when the polluted soil with heavy metal ions was solidified using magnesia-phosphate cement, heavy metal ions were rarely eluted. Furthermore, the results cf SEM-EDS analysis showed that heavy metal ions in polluted soil turns into insoluble solid solution by magnesia-phosphate cement, it come to have the effect to stabilize heavy metals.

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Removal of Cupper(II), Zinc(II) in Marine Environment by Heavy Metal Resistant Desulfovibrio desulfuricans (중금속 내성이 있는 Desulfovibrio desulfuricans를 이용한 해양 환경에서의 Cu(II), Zn(II) 제거)

  • Joo, Jeong Ock;Kim, In Hwa;Oh, Byung-Keun
    • KSBB Journal
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    • v.29 no.3
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    • pp.139-144
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    • 2014
  • Microorganisms play a significant role in bioremediation of heavy metal contaminated seawater. In this study, we reported an effective removal of Cu and Zn in marine envionment by using Desulfovibrio desulfuricans (D. desulfuricans) which belong to sulfate reducing bacteria. D. desulfuricans showed stable growth characteristics in high salt concentration and had resistance to heavy metals. Cu and Zn was removed not only by physical adsorption on the surface of bacteria but also by precipitation reaction of microbial metabolism by D. desulfuricans in seawater. In case of different heavy metal concentration, Cu was effectively removed 85% at 25 ppm and 60% at 50 ppm and Zn was effectively removed 54% at 50 ppm and 46% at 200 ppm, respectively.

Photoluminescent Graphene Oxide Microarray for Multiplex Heavy Metal Ion Analysis

  • Liu, Fei;Ha, Hyun Dong;Han, Dong Ju;Park, Min Su;Seo, Tae Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.281.2-281.2
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    • 2013
  • Since heavy metal ions included in water or food resources have critical effects on human health, highly sensitive, rapid and selective analysis for heavy metal detection has been extensively explored by means of electrochemical, optical and colorimetric methods. For example, quantum dots (QDs), such as semiconductor QDs, have received enormous attention due to extraordinary optical properties including high fluorescence intensity and its narrow emission peaks, and have been utilized for heavy metal ion detection. However, the semiconductor QDs have a drawback of serious toxicity derived from cadmium, lead and other lethal elements, thereby limiting its application in the environmental screening system. On the other hand, Graphene oxide (GO) has proven its superlative properties of biocompatibility, unique photoluminescence (PL), good quenching efficiency and facile surface modification. Recently, the size of GO was controlled to a few nanometers, enhancing its optical properties to be applied for biological or chemical sensors. Interestingly, the presence of various oxygenous functional groups of GO contributes to opening the band gap of graphene, resulting in a unique PL emission pattern, and the control of the sp2 domain in the sp3 matrix of GO can tune the PL intensity as well as the PL emission wavelength. Herein, we reported a photoluminescent GO array on which heavy metal ion-specific DNA aptamers were immobilized, and sensitive and multiplex heavy metal ion detection was performed utilizing fluorescence resonance energy transfer (FRET) between the photoluminescent monolayered GO and the captured metal ion.

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A Study on Bioaccumulation of Heavy Metals in Mussels (Mytilus edulis) from the Onsan Coastal Zone (온산 연안에 서식하는 진주담치(Mytilus edulis)의 중금속 생물농축에 관한 연구)

  • 백수민;이인숙
    • The Korean Journal of Ecology
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    • v.21 no.3
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    • pp.217-224
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    • 1998
  • The heavy metal concentrations of seawater collected from the Onsan coastal zone in February and July 1996 and mussels(Mytilus edulis) in February 1997 were analysed. The concentrations of cadmium in seawater were in the range of 0.008-2.988 ${\mu}g/L$, while the ranges of copper and zinc concentrations were 0.08-2.55, and 0.21-35.12 ${\mu}g/L$, respectively. The metal concentrations decreased gradually with increasing distances from Daejeong stream, indicating that this stream was the major source of heavy metal input into the Onsan coastal zone. The concentrations of cadmium, copper and zinc in mussels were in the ranges of 1.40-25.09, 8.5-64.5, and 46.8-291.2 ${\mu}g/g$, respectively. The metal concentrations decreased gradually with increasing distances from Daejeong stream. Among organs of mussels, gill showed the highest concentrations of cadmium and the digestive gland showed the highest concentrations of copper and for zine the kidney showed the highest concentrations. The digestive gland and kidney revealed high proportion of cadmium in cytosolic fraction and the percentage of copper was high in the kidney and that of zine was high in the digestive gland. Metal-binding protein of mussels collected from the mouth of Daejeong stream was separated, using gel-filtration chromatography. In the kidney and gill of mussels, most of cadmium was associated with metal-binding protein. In contrast, most of the metal in the digestive gland and remaining tissues is bound to high molecular weight protein rather than metal-binding protein.

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A Study on the Production of Tile using Waste Activated Carbon and its Character Evaluation (폐 활성탄을 이용한 타일 제조 및 특성 평가에 관한 연구)

  • Park, Heung-Jai;Kim, Min-Su;Jeong, Jing-Wun;Jeong, Un;Lee, Bong-Hun;Kim, Young-Sik;Park, Yeon-Kyu;Jung, Sung-Uk
    • Journal of Environmental Health Sciences
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    • v.27 no.1
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    • pp.8-13
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    • 2001
  • The tiles were manufactured using a mixture of the TK material(a raw material in making tile) and Cu-Cr-Ag impregnated activated carbon(ASC Charcoal). The extraction character of heavy metals in making tile was evaluated and the manufacturing conditions of tile were studied. The heavy metals in the mixture-before and after the tile was production of tiles was successful and as a result of heavy metal analysis, the tile showed that the concentration of heavy metal after the production of tiles was lower than that of the before one. The concentration of eluted heavy metal by acidic and basic solutions was low and the quality of the produced tile was similar to the commercial one. The result of this study suggested that the waste ASC charcoal was used to produce good tiles and it also might reduce soil pollution.

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A Study on the Heavy Metal Content in Vegetables in In Chon Area (仁川市 一圓에서 栽培된 野菜類中 重金屬 含量에 관한 연구)

  • Cho, Tae Woong
    • Journal of Environmental Health Sciences
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    • v.12 no.1
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    • pp.55-61
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    • 1986
  • This study was carded out to evaluate the heavy metal content in vegetables such as lettuce, chinese cabbage, sesame leaf, radish, cucumber and pumpkin that cultivated in Inchon area. The results obtained were as follows: As a whole, the heavy metal content in vegetables was the higher at industrial area and the lower at residential and green-belt area.

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Modality of Heavy Metal Contamination of Soil in Military Rifle Shooting Range (소화기 사격장의 중금속 오염 양상)

  • Lee, Kwang-Lyeol;Hyun, Jae-Hyuk
    • Journal of Soil and Groundwater Environment
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    • v.21 no.3
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    • pp.58-63
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    • 2016
  • The study examined the level of heavy metal contamination by dividing military rifle shooting ranges into the three areas, i.e firing, trajectory, and target. The target area was found to be contaminated at a level higher (Cu 845 mg/kg, Pb 30,487 mg/kg) than the Worrisome Level of Soil Contamination (hereinafter referred to as the “Worrisome Level”) The trajectory area was predicted to be free from contamination, but it did indicate contamination although it was pretty much lower (Cu 23 mg/kg, Pb 99 mg/kg) than Worrisome Level. This is attributed to the contamination spread when rearranging the soil of the target area during the maintenance of the shooting range. The firing area was also predicted to be free from heavy metal contamination, but the results analyzed indicated a contamination higher (Cu 201 mg/kg, Pb 2,286 mg/kg) than Worrisome Level. This is attributed to the fragments of the broken bullet scattering due to the pressure generated as the bullet leaves the muzzle. An examination of heavy metal contamination in the discharge area as well as gutters to prevent the intrusion of rain water from perimeter revealed a high level of contamination (Cu 298 mg/kg, Pb 6,497 mg/kg), which makes it necessary to take measures.

Assessment of Soil Pollutant Distribution Characteristics and Heavy Metal Pollution in Korea (국내 토양오염물질 분포 특성 및 중금속 오염도 평가)

  • Lee, Jong Cheol;Kang, Min Woo;Choi, Gyu Hyuk;Oh, Se Jin;Kim, Dong Jin;Lee, Sang Soo
    • Korean Journal of Environmental Agriculture
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    • v.41 no.1
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    • pp.9-15
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    • 2022
  • BACKGROUND: Heavy metals discharged from various sources contaminate the soil and water and the residuals can persistently be accumulated. In this study, the concentration of soil heavy metals was assessed over the whole regions of Korea based on the contamination factor and the geoaccumulation index. METHODS AND RESULTS: The data of averaged concentrations of heavy metals and fluorine were collected from the Korean Statistical Information Service (KOSIS) and the research papers published. In order to classify the levels of heavy metal concentration, the contamination index, including the contamination factor and the geoaccumulation index, based on the relative ratio of the actual concentration of heavy metals in the soil to the background concentration was calculated. In addition, the distribution of heavy metals in soils was visualized by using the geographic information system (GIS). As a result, the Cd contamination in the soils was the most concerned. CONCLUSION(S): This study very roughly indicated the outline of heavy metal concentration over the whole regions of Korea. The change in heavy metals' concentration over the time should further be monitored and the larger data of heavy metal contamination are needed for better understanding in the future.

Natural Background Level Analysis of Heavy Metal Concentration in Korean Coastal Sediments (한국 연안 퇴적물 내 중금속 원소의 자연적 배경농도 연구)

  • Lim, Dhong-Il;Choi, Jin-Yong;Jung, Hoi-Soo;Choi, Hyun-Woo;Kim, Young-Ok
    • Ocean and Polar Research
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    • v.29 no.4
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    • pp.379-389
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    • 2007
  • This paper presents an attempt to determine natural background levels of heavy metals which could be used for assessing heavy metal contamination. For this study, a large archive dataset of heavy metal concentration (Cu, Cr, Ni, Pb, Zn) for more than 900 surface sediment samples from various Korean coastal environments was newly compiled. These data were normalized for aluminum (grain-size normalizer) concentration to isolate natural factors from anthropogenic ones. The normalization was based on the hypothesis that heavy metal concentrations vary consistently with the concentration of aluminum, unless these metals are of anthropogenic origin. So, the samples (outliers) suspected of receivingany anthropogenic input were removed from regression to ascertain the "background" relationship between the metals and aluminum. Identification of these outliers was tested using a model of predicted limits at 95%. The process of testing for normality (Kolmogorov-Smirnov Test) and selection of outliers was iterated until a normal distribution was achieved. On the basis of the linear regression analysis of the large archive (please check) dataset, background levels, which are applicable to heavy metal assessment of Korean coastal sediments, were successfully developed for Cu, Cr, Ni, Zn. As an example, we tested the applicability of this baseline level for metal pollution assessment of Masan Bay sediments.

Characteristics for Heavy Metal Pollution in Road Dust from Daebul Industrial Complex: Classification by Particle Size and Magnetic Separation (대불산업단지 도로먼지 내 중금속류 오염 특성: 입도와 자성에 따른 구분)

  • Jeong, Hyeryeong;Choi, Jin Young;Ra, Kongtae
    • Journal of Environmental Impact Assessment
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    • v.29 no.4
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    • pp.252-271
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    • 2020
  • In this study, we investigated physical and chemical properties such as grain size, heavy metal pollution, magnetic properties, and their environmental impacts of road dusts (RD) collected from 14 sampling points in Daebul industrial Complex. Heavy metal concentrations in RD were in the order of Fe>Zn>Cu>Pb>Cr>Ni>As>Cd>Hg, and this pollution pattern was related to major industries and traffic activities in this area. The results of the correlation analysis between heavy metal elements and particle size in RD showed that Fe and all of analyzed heavy metals had a significant correlation with each other and metal concentrations had a significantly negative correlation (p<0.05). However, due to the input of large metal particles some heavy metal concentrations in the particle fraction of >1000 ㎛ were highest. Pollution load per unit area of this fraction was the highest among the grain size fractions. Cr, Ni, Cu, Zn, Cd, Pb levels in RD decreased and the levels of Cr, Ni, Cu, Zn, Cd, and Pb were reduced to 85 (As) -22 (Ni)% of the whole after removal of MFs fraction from RD. The mean heavy metal levels in the study area did not exceed the soil contamination guide value of Korea, indicating that heavy metal levels in RD were not a concern. However, at some sampling points, Zn concentrations were exceeded the soil contamination guide value for the 3rd areas of Korea and this result indicated that further studies of the impact of RD on the surrounding environment through re-suspension or non-point pollution, and of effective management methods are required.