• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 하계학술대회 논문집
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• pp.310-310
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• 2009

In the two structure of ITO/N,N'-diphenyl-N,N' bis (3-methylphenyl)-1,1'-biphenyl-4,4'-diamine(TPD)/R-H : R-D/Al device, ITO/Amorphous Fluoropolymers/TPD/R-H : R-D/LiF/Al device. we studied the effect of organic materials defending on the electrical characteristics of red OLEDs. The thickness of TPD and R-H : R-D was manufactured 40 nm, 60 nm, respectively under a base pressure of $5\times10^{-6}$Torr using a thermal evaporation. The AF used for an hole-injection is the thickness of 0.5 [nm] and the LiF used for an electron-injection is the thickness of 0.5 [nm]. Compared to the two from the devices made with the hole injection and without hole injection We found that the luminous efficiency and the external quantum efficiency are improved a fact of one- hundred, two, respectively.

• 전기학회논문지
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• 제67권7호
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• pp.854-859
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• 2018

This paper describes the characteristics of a hybrid supercapacitor module for power quality stabilization. Hybrid supercapacitor is an promising energy storage device that positioned between conventional EDLC and Li-ion battery. A cylindrical 7500F hybrid supercapacitor ($60{\times}138mm$) was assembled by using the $Li_4Ti_5O_{12}$ electrode as an anode and activated carbon as a cathode. Considering the ESR and efficiency has been designed to module with 41.6F 480V design results in 180 series combination. In order to determine the characteristics of the hybrid supercapacitor module for power system, hybrid supercapacitor cells were connected in series with active balancing circuit. As a result of measuring the 50kw UPS, it was discharged at the current of 104A~143A during the discharge in the voltage range of 350V~480V, and the compensation time at discharge was measured to be about 30s. These results can be used to stabilization of power quality by applying hybrid supercapacitor module.

• 한국지구과학회지
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• 제23권6호
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• pp.486-493
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• 2002

황강리 지역 형석 광화대내 석회암 및 화강암지역 지하수의 수문지화학적 특성을 연구하였다. 석회암 지역 지하수는 Ca$^{2+}$-HCO$_3\;^{-}$유형이며, 화강암 지역 지하수는 (Ca$^{2+}$+Na$^{+}$)-HCO$_3\;^{-}$유형이다. 연구지역 내 광산폐수에 의한 음용지하수의 오염은 아직 발견되지 않았으나, 백악기 화강암내 음용지하수에는 불소함량이 기준치를 초과하는 곳이 많다. 화강암 지역 지하수는 F 함량이 증가함에 따라 Na, HCO$_{3}$, Li, pH 등이 증가 하는 지구화학적 특성을 보인다. 지하수내 불소의 기원은 형석 혹은 함불소 규산염광물의 용해에 기인하며, 이들 광물은 산성 화강암류와 성인적 관련이 깊은 것으로 판단된다.

• 한국전기전자재료학회논문지
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• 제19권5호
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• pp.437-441
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• 2006

The red emitting OLEDs using $Alq_3$:Rubrene-GDI4234 phosphors have been fabricated and characterized . In the device fabrication, 2- TNATA [4,4',4' - tris (2- naphthylphenyl - phenylamino ) - tripheny lamine] as the hole injection material and NPB [N,N'-bis (1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine] as the hole transport material were deposited on the ITO(indium tin oxide)/glass substrate by vacuum evaporation. And then, red color emissive layer was deposited using $Alq_3$ as the host material and Rubrene(5,6,11,12-tetraphenylnaphthacene)-GDI4234 as the dopants. finally, small molecule OLEDs with structure of ITO/2-TNATA/NPB/$Alq_3$:Rubrene-GDI4234/$Alq_3$/LiF/Al were obtained by in-situ deposition of $Alq_3$, LiF and Al as the electron transport material, electron injection material and cathode, respectively. Red OLEDs fabricated in our experiments showed the color coordinate of CIE(0.65, 0.35) and the maximum power efficiency of 2.1 lm/W at 7 V with the peak emission wavelength of 632 nm.

• 한국표면공학회지
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• 제41권3호
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• pp.102-108
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• 2008

In this paper, the LiF and polymer thin film as passivation layer have been evaporated on green OLED devices. HDPE, polyacenaphthylene, polytetrafluoroethylene, poly(2,6-dimethyl-1,4-pheneylene oxide), poly sulfone and poly(dimer-acid-co-alkyl poly-amine) have been used as polymer materials. The optical transmittance of evaporated polymer thin film was very good as an above 90% in visible range. The morphology of polymer thin film was measured by AFM. As a result of the measurement average roughness($R_a$) value of the polysulfone was very low as 2.2 nm. The green OLED devices with a structure of ITO/HIL/HTL/EML/Buffer/Al in series of various passivation films were fabricated and analyzed. It was observed that an OLED device with LiF as first passivation film has shown the good electrical and optical property, and all kind of polymer films did not influence on the I-V-L characteristics and the life time of OLED devices. Therefore, we found that polymer layer played a key role as a buffer layer between the inorganic passivation layers to relieve the stress of the inorganic layers.

• 전기화학회지
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• 제4권3호
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• pp.113-117
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• 2001

탄소계 전극을 사용하는 EDLC(Electric Double Layer Capacitor)용의 축전용량과 충방전속도는 전해질의 종류, 충방전 조건 그리고 탄소계 물질의 물리화학적 성질에 따라 크게 달라질 수 있다. 이에 본 연구에서는 dip coating method에 의해 제조된 EDLC용 활성탄소 전극에서 유기 전해질의 종류를 달리하여 충방전 실험과 전기화학적인 실험을 시행하였다. 또한 충전전류밀도와 방전전류밀도의 변화에 따른 비축전 용량의 변화를 조사하였고, 최적 유기전해질의 조건에서 leakage current 특성, 자가방전 특성 그리고 시간전압곡선을 기존의 $1M-Et_4NBF_4/PC$와 비교하였다 활성탄, 소전극으로 비표면적이 $2000m^2/g$인 MSP-20을 사용하고 유기전해질로는 $1M-LiPF_6/PC-DEC(1:1)$를 사용한 EDLC에서 130 F/g 정도의 우수한 비축전 용량을 나타내었고 저항면에서도 가장 낮은 수치를 나타내었다 $1M-LiPF_6/PCDEC(1:1)$를 사용한 EDLC는 15분동안 0.0004A의 낮은 leakage current와 100시간 경과 후 0.8V의 우수한 자가 방전 특성 그리고 IR-drop이 적은 선형의 시간-전압곡선을 보여주었다.

• Korean Chemical Engineering Research
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• 제54권1호
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• pp.36-43
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• 2016

Hydrosilylation reactions of 2.4.6.8-tetrahydro-2.4.6.8-tetramethylcyclotetrasiloxane with allyl butyrate catalyzed by Karstedt's, $H_2PtCl_6$ and Pt/C catalyst were studied and 2.4.6.8-tetra (propyl butyrate)-2.4.6.8-tetramethylcyclotetrasiloxane was obtained. The reaction order, activation energies and rate constants were determined. Ringopening polymerization of 2.4.6.8-tetra (propyl butyrate)-2.4.6.8-tetramethylcyclotetrasiloxane in the presence of $CaF_2$, LiF, KF and anhydrous potassium hydroxide in $60-70^{\circ}C$ temperature range was carried out and methylsiloxane oligomers with regular arrangement of propyl butyrate pendant groups were obtained. The synthesized products were studied by FTIR and NMR spectroscopy. The polysiloxanes were characterized by wide-angle X-ray, gel-permeation chromatography and DSC analyses. Via sol-gel processes of oligomers doped with lithium trifluoromethylsulfonate or lithium bis (trifluoromethylsulfonyl)imide, solid polymer electrolyte membranes were obtained. The dependences of ionic conductivity of obtained polyelectrolytes on temperature and salt concentration were investigated, and it was shown that electric conductivity of the polymer electrolyte membranes at room temperature changed in the range $3.5{\times}10^{-4}{\sim}6.4{\times}10^{-7}S/cm$.

• Bulletin of the Korean Chemical Society
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• 제35권5호
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• pp.1422-1432
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• 2014

Convergent all-electron multi-reference configuration-interaction (MRCI) calculations are performed for a lithium dimer with Kaufmann's Rydberg basis functions. A comparison of the results of these calculations with those of the effective core potential/core polarization potential (ECP/CPP) method and experimental data reveals the deficiency of the all-electron ab initio method. The deficiency is related to the mere 51.9% attainment of electron correlation for the ground state. The percent attainment of electron correlation for the first excited state is slightly better than that for the ground state, preventing us from obtaining better agreements with experimental data by means of increasing the size of basis sets. The Kaufmann basis functions are then used with the ECP/CPP method to obtain the accurate convergent potential energy curves for the $^1\prod_u$ states correlated to Li(2p) + Li(2p) and Li(2s) + Li(n = 2, 3, 4). Quantum defect curves (QDCs) calculated for both the $X^2\sum_g$ and 1 $^2\prod_u$ states of the $Li{_2}^+$ ion and the Lu-Fano plot reveal a strong series-series interaction between the two $2snp{\pi}$ and $2pnp{\pi}$ Rydberg series. The QDCs are then used to resolve assignment problems in the literature. The reassignments, performed by Jedrzejewski-Szemek et al., of the dissociation product of the D $^1\prod$ state from (2s+3d) to (2s+3p) and that of the 6 $^1\prod_u$ from (2s+4d) to (2s+4p) are found to be incorrect. It may be more natural to assign their $2snp{\pi}$ Rydberg series as a $2snd{\pi}$ series. The state, assigned as 5p $^1\prod_u$ by Ross et al. and 4d $^1\prod$ by Jedrzejewski-Szemek et al., is assigned as the 7 $^1\prod_u$ state, correlated to the Li(2s) + Li(4f) limit.

• 한국세라믹학회지
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• 제52권3호
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• pp.215-220
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• 2015

Phase evolution, microstructure, and microwave dielectric properties of $Li_2O$ and $Al_2O_3$ doped $Zn_{1.9}Si_{1.05}O_4$, i.e., $Zn_{1.9-2x}Li_xAl_x-Si_{1.05}O_4$, ceramics (x = 0.02 ~ 0.10) were investigated. The ceramics were densified by $SiO_2$-rich liquid phase composed of the Li-Al-Si-O system, indicating that doped Li and Al contributed to the formation of the liquid. As the secondary phase, ${\beta}$-spodumene solid solution with the composition of $LiAlSi_3O_8$ was precipitated from the liquid during the cooling process. The dense ceramics were obtained for the specimens of $$x{\geq_-}0.06$$ showing the rapid densification above $1000^{\circ}C$, implying that a certain amount of liquid is necessary to densify. The specimen of x = 0.06 sintered at $1050^{\circ}C$ exhibited good microwave dielectric properties; the dielectric constant and the quality factor ($Q{\times}f_0$) were 6.4 and 11,213 GHz, respectively.

• 대한수학회보
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• 제60권6호
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• pp.1651-1672
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• 2023

In 2010, Li-Ye [13, Theorem 0.1] proved that P(ζ(z), ζ'(z), . . . , ζ^(m)(z), Γ(z), Γ'(z), Γ"(z)) ≢ 0 in ℂ, where m is a non-negative integer, and P(u₀, u₁, . . . , u_m, v₀, v₁, v₂) is any non-trivial polynomial in its arguments with coefficients in the field ℂ. Later on, Li-Ye [15, Theorem 1] proved that P(z, Γ(z), Γ'(z), . . . , Γ⁽ⁿ⁾(z), ζ(z)) ≢ 0 in z ∈ ℂ for any non-trivial distinguished polynomial P(z, u₀, u₁, . . ., u_n, v) with coefficients in a set L_δ of the zero function and a class of nonzero functions f from ℂ to ℂ ∪ {∞} (cf. [15, Definition 1]). In this paper, we prove that P(z, ζ(z), ζ'(z), . . . , ζ^(m)(z), Γ(z), Γ'(z), . . . , Γ⁽ⁿ⁾(z)) ≢ 0 in z ∈ ℂ, where m and n are two non-negative integers, and P(z, u₀, u₁, . . . , u_m, v₀, v₁, . . . , v_n) is any non-trivial polynomial in the m + n + 2 variables u₀, u₁, . . . , u_m, v₀, v₁, . . . , v_n with coefficients being meromorphic functions of order less than one, and the polynomial P(z, u₀, u₁, . . . , u_m, v₀, v₁, . . . , v_n) is a distinguished polynomial in the n + 1 variables v₀, v₁, . . . , v_n. The question studied in this paper is concerning the conjecture of Markus from [16]. The main results obtained in this paper also extend the corresponding results from Li-Ye [12] and improve the corresponding results from Chen-Wang [5] and Wang-Li-Liu-Li [23], respectively.