• Title/Summary/Keyword: 4 전극법

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A Study on Electrode Array for Measurement of Induced Polarization of Rock Samples (암석 시료의 유도분극 측정을 위한 전극배열 비교)

  • Man-ho Han;Jung-hwan Lee;Keun-Soo Lee;Myeong-Jong Yi
    • Tunnel and Underground Space
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    • v.33 no.6
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    • pp.483-494
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    • 2023
  • Measurement of the physical properties of rocks or minerals is an important factor in determining the distribution of the underground medium as well as mineral resource investigations. Resistivity and induced polarization, which are widely used in Korea, are methods for measuring electrical properties, which are representative properties of obtaining subsurface information. In order to precisely analyze the exploration data obtained from various sites, it is important to accurately measure the material properties. Electrical properties of rock is measured using two-electrode or four-electrode method. Compared to the four-electrode method, the two-electrode method is generally used because it is very easy to contact the sample and the electrode, but there is a problem in that the impedance of the electrode and the sample is measured together. In this study, the time-domain the induced polarization effects were measured using the 2-electrode method and the 4-electrode method for artificial samples mixed with graphite and cement having induced polarization characteristics, and the results were compared. Although the 4-electrode method has difficulties in installing potential electrodes, it was confirmed that it is effective in measuring electrical properties because it can reduce the problem caused by the impedance of potential electrodes compared to the 2-electrode method.

Synthesis of Electrode Catalyst for Polymer Electrolyte Membrane Fuel Cells Using Colloidal Method (콜로이드법을 이용한 고분자전해질 연료전지용 백금전극 촉매의 제조)

  • Park, Jin-Nam
    • Clean Technology
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    • v.19 no.1
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    • pp.59-64
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    • 2013
  • Pt/carbon Electrode catalysts for PEMFC were synthesized using colloidal method. PSA (platinum sulfite acid) was used as a Pt precursor and CPA (chloroplatinic acid) was also used to replace relatively expensive PSA. Electrode catalysts prepared using PSA showed Pt particle size less than 3.5 nm and Pt yield higher than 90% in 10~40 wt% Pt loading. Electrode catalysts prepared using CPA also showed Pt particle size less than 4.4 nm and Pt yield higher than 80% in 10~40 wt% Pt loading. The MEA (membrane electrode assembly) using 20 wt% Pt/VXC72 showed equivalent I-V curve comparing with commercial electrode catalyst in single cell test.

Numerical Study of Electrolyte Wetting Phenomena in the Electrode of Lithium Ion Battery Using Lattice Boltzmann Method (격자 볼츠만법을 이용한 리튬이온전지의 전극내 전해액 함침현상에 관한 수치적 연구)

  • Lee, Sang Gun;Jeon, Dong Hyup
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.4
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    • pp.357-363
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    • 2014
  • The electrolyte wetting phenomena in the electrode of lithium ion battery is studied numerically using a multiphase lattice Boltzmann method (LBM). When a porous electrode is compressed during roll-pressing process, the porosity and thickness of the compressed electrode are changed, which can affect its wettability. In this study, the change in electrolyte distribution and degree of saturation as a result of varying the compression ratio are investigated with two-dimensional LBM approach. We found that changes in the electrolyte transport path are caused by a reduction in through-plane pore size and result in a decrease in the wettability of the compressed electrode.

A Study on the Modified Electrode Arrays in Two-Dimensional Resistivity Survey (2차원 전기비저항 탐사를 위한 변형된 전극배열법에 관한 연구)

  • Kim Jung-Ho;Yi Myeong-Jong;Song Yoonho;Chung Seung-Hwan
    • Geophysics and Geophysical Exploration
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    • v.4 no.3
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    • pp.59-69
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    • 2001
  • Five kinds of modified electrode arrays were proposed to overcome the weak points of the commonly used arrays using dipole and/or pole in two-dimensional resistivity surveys. The modified pole-pole array was suggested to overcome the inefficiency caused by distant earthing in pole-pole array. Four kinds of modified arrays using dipole were designed to enhance the signal-to-noise ratio of the conventional dipole-dipole and pole-dipole arrays through boosting up the measured potential difference. In the numerical experiments using the two-dimensional modeling and inversion, the effects of the ambient electrical noise and the resolving power were examined and the results showed the validity of the modified arrays proposed in this study.

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Characterization of Fuel Cell Electrode Prepared by the Colloidal Method (콜로이달법으로 제조한 연료전지 전극의 특성화)

  • 이승재;김덕기;신창섭;이태희
    • Journal of Energy Engineering
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    • v.4 no.3
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    • pp.309-314
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    • 1995
  • 촉매의 담지순서 카본블랙의 종류 및 전처리 방법 등을 달리하여 연료전지 전극용 백금/카본 분말을 제조하고 이것의 백금 유실율, 백금 분산율 및 촉매 활성을 살표보았으며, 이를 사용하여 제조한 전극의 단위전지 성능을 상용전극과 비교하였다. 실험결과 카본블랙에 백금용액을 먼저 혼합한 후 환원시키는 전극제조 방법은 기존의 콜로이달법 보다 백금의 유실율이 적고 분산율이 높았다. 그리고 산/염기를 이용한 카본블랙의 전처리는 표면적은 줄어들지만 촉매활성을 증가시켰으며, 전극촉매의 최적 활성화 온도는 30$0^{\circ}C$이었다.

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Preparations and Electrochemical Characteristics of Polypyrrole by Constant Potential Electroplymerization (정전위 전해 중합법에 의한 폴리피롤 제조 및 전기화학적 특성)

  • Cho, Seung-Koo;Sim, Chol-Ho
    • Journal of the Korean Electrochemical Society
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    • v.8 no.2
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    • pp.99-105
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    • 2005
  • In this study, the $PPy/CLO_4$ and PPy/PVS composite electrodes were prepared at various polymerization potential by incorporating electrolyte anions of different anion size during constant potential polymerization. The reulting Polypyrrole surfaces were inspected by SEM, and their electrochemical Properties were investigated with CV and ac impedance method. The results of electrochemical analysis were suggested that anion for $PPy/CLO_4$ electrode and cation fir PPy/PVS electrode were transferred during redox reaction. As constant potential of polymerization was increased, the charge transfer resistance of $PPy/CLO_4$ and PPy/PVS was decreased and the electric double layer capacitances of $PPy/CLO_4$ was higher than that of PPy/PVS. The change of PPy/PVS surface was relatively smaller than that of $PPy/CLO_4$ according to electropolymerization potential.

A Body Composition Measurement using the 4-Electrode BIA Method (4전극 BIA 법에 의한 체성분의 측정)

  • Park, Chan-Won;Nam, Hyun-Shik
    • Proceedings of the KIEE Conference
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    • 2005.07d
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    • pp.2705-2707
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    • 2005
  • 본 논문은 4 전극법을 이용한 BIA (Bioelectrical Impedance Analysis)측정 기술로 측정된 신체의 내부 임피던스와 중량, 그리고 신장의 데이터를 활용하여 서로의 상관관계를 밝히고, 내부 임피던스와 중량의 관계로부터 신장을 측정하는 실험에 관한 것이다.

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Effects of the Position of Potential Probe on Ground Resistance Measurements Using the Fall-of-Potential Method (전위강하법에 의한 접지저항측정에 미치는 전위보조전극 위치의 영향)

  • 이복희;어주홍;김성원
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.15 no.2
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    • pp.97-104
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    • 2001
  • The effects of the position of potential probe on the measurements of the ground resistance in the fa11-of-potential method are described. The ground resistance is theoretically calculated by applying the 61.8[%] rule, and then the potential probe is located on the straight line between the grounding electrode to be measured and the current probe. However, sometimes the grounding electrode to be measured and the measuring potential and current probes in on-site test might not be arranged on the straight line with adequate distance because there are building, roadblock construction and other establishments. Provided that the grounding electrode to be measured and the measuring potential probes are out of position on the straight line, the measurement of the ground resistance classically falls into an error and the measured ground resistance should be corrected. In this work, measurements were focused on the grounding electrode system made by the ground rods of 2.4 m long. The measuring error was increased with increasing the angle which is made by the 3-points of the grounding electrode to be measured, the potential anti current probes, and it was a negative. That is, all of the measured ground resistances ware less than the true ground resistance.

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Effects of the Current Probe on Ground Resistance Measurements Using Fall-of-Potential Method (전위강하법에 의한 접지저항측정에 미치는 전류보조전극의 영향)

  • 이복희;엄주홍
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.14 no.6
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    • pp.69-77
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    • 2000
  • In this paper, the effects of the positions of the potential and current probes on the measurements of the ground resistance and potential gradients with the fall-of-potential method are described and the testing techniques to minimize the measuring errors are proposed. The fall-of-potential method is theoretically based on the potential and current measuring principle and the measuring error is primarily caused by the position and ground resistance of the measuring probes. The ground resistance is calculated by applying the 61.8% and rule in the fall-of-potential method, and then the potential probe is located on the straight line between the grounding electrode to be measured and the current probe. However, sometimes the grounding electrode to be measured and the measuring probes in on-site test might not be arranged on the straight line with adequate distance because there are building, road block, construction and other establishments. Provided that the grounding electrode to be measured and the measuring probes ar out of position on the straight line or have inadequate distance, the measurement of the ground resistance classically falls into an error and the measured ground resistance should be corrected. Measurements were focused on the grounding electrode system made by the ground rods of 2.4m long. It was found that the suitable separation between the grounding electrode to be measured and the current probe is more than 5 times of the length of the grounding electrode to be measured.

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그라핀 전극을 이용한 유연 투명 구동기 제작 및 특성 평가

  • Park, Yun-Jae;Im, Yeong-Jin;Im, Gi-Hong;Choe, Hyeon-Gwang;Jeon, Min-Hyeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.286.2-286.2
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    • 2013
  • 기존의 이온성 고분자-금속 복합체(IPMC)는 백금(Pt)전극을 이온성 전기활성 고분자(Ionic electroactive polymer)인 나피온에 무전해 도금으로 만들어졌다. 본 연구는 백금전극을 그래핀으로 대체하여 투명 이온성 고분자-그래핀 복합체(IPGC)를 제작하였다. 그래핀은 근적외선 화학기상증착법(NIR-CVD)으로 전이금속 (Cu, Ni) 위에 탄화수소 가스(CH4)를 이용하여 성장하였다. 전이 금속위에 성장된 그래핀을 나피온 양쪽면에 van der Waals 결합력을 이용하는 습식 전이공정으로 전극을 형성하였다. IPGC는 면 저항(4-point probe), 투과도(UV/Vis spectrometer) 및 라만 분광법(Micro Raman spectroscopy)의 측정으로 그래핀 전극의 특성평가를 하였고, 전계방사 주사전자현미경(Field Emisson Scanning Electron Microscope; FE-SEM)을 사용하여 IPGC의 구조적 특성을 확인하였다. 제작된 IPGC의 성능은 백금전극을 이용한 IPMC의 변위(displacement), 힘(force), 작동 주파수(Operating frequency) 분석을 통해 비교 평가하였다.

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