• Journal of the Korean Chemical Society
• /
• v.22 no.2
• /
• pp.86-94
• /
• 1978

The crystal and molecular structure of theophylline hydrochloride has been determined from X-ray data by Patterson techniques. The structure has been refined by block-diagonal least-squares and Fourier synthesis on three dimensional data. The unit cell is orthorhombic, space group $P_{na21}$, with a = 14.01, b = 11.49, c = 6.77${\AA}$, and contains four molecules. The final R value based on 743 observed reflexions is 12.2%. The intramolecular distances are similar to those in other compounds containing a purine or pyrimidine group. The molecules are nearly planar and are stacked in layers parallel to the (001)plane. The chlorine atom is coordinated to N(1) atom at a distance of 3.06${\AA}$. The structure is stabilized mainly by van der Waals interactions; however, a short N${\cdot}{\cdot}{\cdot}$Cl contact of length $3.06\AA$, which is slightly less than the expected van der Waals separation, suggest that weak charge transfer interaction may be present. The relationship between this structure and the known structures of theophylline monohydrate and caffeine monohydrate are discussed.

• Journal of Korean Tunnelling and Underground Space Association
• /
• v.19 no.5
• /
• pp.717-732
• /
• 2017

Recently, the construction of underground structure such as a double-deck tunnel is increasing to manage rapid growth of roadway traffic volume. Double-deck tunnel includes middle slab to separate upper and lower road inside, and various sources affect the dynamic behaviour of middle slab due to dynamic loading of vehicle. Therefore, it is important to investigate the dynamic response of middle slab precisely to apply it to design and analysis of double-deck tunnel. In this study, dynamic analysis model of middle slab considering structural type, design velocity, vehicle load, and surface roughness, etc. is built. 3-dimensional dynamic analysis is performed to assess dynamic response of middle slab. Consequently, Dynamic Magnification Factor which represents dynamic response of middle slab shows maximum in case of elastomeric bearings (EB) and average roughness (Grade C). It is also expected that dynamic response can be reduced under the condition of good roughness (Grade B) and fixed bearings (FB).

• Journal of Korean Tunnelling and Underground Space Association
• /
• v.20 no.6
• /
• pp.989-1002
• /
• 2018

Grouting for the rock joint is to strengthen the rock strata by infiltrating cement grout materials into the rock joints. Grouting is one of a field of study which is difficult to develop deterministic and quantitative design approach because of multiphase behaviors of grout materials and 3 dimensional features of rock joints. Therefore, GIN (Grouting Intensity Number) can be a good index with appropriate monitoring of pressure and volume of grout. In this paper, we investigate the effects of joint roughness (JRC) and rheology of cement material during the infiltration of cement grout material into rock joint through CFD (computational fluid dynamics) analyses. With rough joint surface and increase of WC ratio, the frictional resistance during the grouting increases. The results have been summarized with polynomial correlations.

• Journal of the Korean Society of Safety
• /
• v.36 no.5
• /
• pp.71-78
• /
• 2021

There are regularly planned overhaul periods in thermal power plants, which involve the maintenance of the boiler of the power plants. However, thermal power plants workers are always exposed to risk during overhaul periods owing to the narrow space and significant dust inside the boiler. Therefore, it is essential to develop a safety monitoring system that is suitable for operating in this type of environment. In this study, we developed not only a worker three-dimensional (3D)-location monitoring system that can monitor and record the entry/exit of workers, their 3D-location, and fall accidents but also a method to secure the working environment and operation efficiency. This system comprises of a worker tag, which was equipped with an inertial measurement unit, a barometric pressure sensor, and a Bluetooth low energy (BLE), and the tags were given to each worker. In addition, the location of workers inside the boiler was measured using a pedestrian dead reckoning (PDR) method and BLE beacons. The location data of the workers tag were transmitted to the integrated database (DB) server through a gateway, and to the administrator monitoring system. The performance of the system was demonstrated inside an actual thermal power plant boiler, and the accuracy and reliability of the system were verified through a number of repeated tests. These results provide insights on designing a new system for monitoring enclosed spaces.

• Journal of Korean Dental Science
• /
• v.12 no.1
• /
• pp.13-19
• /
• 2019

Purpose: The aim of this study was to compare the flexural strength of provisional fixed dental prostheses which was three-dimensional (3D) printed by several build directions. Materials and Methods: A metal jig with two abutment teeth and pontic space in the middle was fabricated. This jig was scanned with a desktop scanner and provisional restoration was designed on dental computer-aided design program. On the preprocessing software, the build angles of the restorations were arranged at $0^{\circ}$, $30^{\circ}$, $45^{\circ}$, $60^{\circ}$, and $90^{\circ}$ and support was added and resultant structure was sliced to a thickness of $100{\mu}m$. Processed restorations were printed with digital light processing type 3D printer using poly methyl meta acrylate-based resin. After washing and post-curing, compressive loading was applied at a speed of 1 mm/min on a metal jig fixed to a universal testing machine. The maximum pressure at which fracture occurred was measured. For the statistical analysis, build direction was set as the independent variable and fracture strength as the dependent variable. One-way analysis of variance and Tukey's post hoc analysis was conducted to compare fracture strength among groups (${\alpha}=0.05$). Result: The mean flexural strength of provisional restoration 3D printed with the build direction of $0^{\circ}$ was $1,053{\pm}168N$; it was $1,183{\pm}188N$ at $30^{\circ}$, $1,178{\pm}81N$ at $45^{\circ}$, $1,166{\pm}133N$ at $60^{\circ}$, and $949{\pm}170N$ at $90^{\circ}$. The group with a build direction of $90^{\circ}$ showed significantly lower flexural strength than other groups (P<0.05). The flexural strength was significantly higher when the build direction was $30^{\circ}$ than when it was $90^{\circ}$ (P<0.01). Conclusion: Among the build directions $0^{\circ}$, $30^{\circ}$, $45^{\circ}$, $60^{\circ}$, and $90^{\circ}$ set for 3D printing of fixed dental prosthesis, an orientation of $30^{\circ}$ is recommended as an effective build direction for 3D printing.

• Tunnel and Underground Space
• /
• v.1 no.2
• /
• pp.181-203
• /
• 1991

The effects of geologic structures such as rock joins and bedding planes on the thermal conductivity of a discontinuous rock mass are studied. The expressions for the equivalent thermal conductivities of jointed rock masses are derived and found to be anisotropic. The degree of anisotropy depends primarily on the thermal properties contrast between the joint phase and surrounding intact rock, the joint density expressed as volume fraction and the inclination angle of the joint. Within the context of 2-dimensional finite element heat transfer scheme, the isotherms around a circular hole are analyzed for both the isotropic and anisotropic rock masses in 3 different thermal boundary conditions. i.e. temperature, heat flux and convection boundary conditions. The temperature in the stratified anisotripic rock mass is greatly influenced by the thermal properties of the rock formation in contact with the heat source. Using the excavation-temperature coupled elastic plastic finite element method, analyzed is the thermo-mechanical stability of a circular opening subjected to 10$0^{\circ}C$ at a depth of 527m. It is found that the thermal stress concentration was enough to deteriorate the stability and form a plastic yield zone around the opening, in contrast to the safety factor greater than 2 resulted form the excavation-only analysis.

• Journal of the Korean Society for Marine Environment & Energy
• /
• v.5 no.3
• /
• pp.10-15
• /
• 2002

The assessment of PIV to measure the mean velocity and turbulence was carried out over a train of fixed two-dimensional dunes. The agreement between the PIV and LDV is good enough even in regions of flow reversals and high shear. Though limited in the wall normal direction field-of-view, PIV provides instantaneous flow fields, which reveal the complex nature of flow over dunes, as well as more sophisticated analyses such as two-point space correlation and quadrant analysis with a reasonable accuracy The present study is expected to be directly applied to more complex flow such as sediment transport.

• Journal of the Korean Society for Heat Treatment
• /
• v.14 no.4
• /
• pp.228-234
• /
• 2001

The present study was an attempt for systematic data conversion between FDM and FEM in order to evaluate the thermal stress distribution during quenching process. It has been generally recognized that FDM is efficient in flow and temperature analysis and FEM in that of stress. But it induced difficulty and tedious work in analysis that one uses both FDM and FEM to take their advantages because of the discrepancy of nodes between analysis tools. So we proposed field data conversion procedure from FDM to FEM in 3-dimensional space, then applied this procedure to analysis of quenching process. The simulation procedure calculates the distributions of temperature and microstructure using FDM and microstructure evolution equations of diffusion and diffusionless transformation. FEM was used for predicting the distributions of thermal stress. The present numerical code includes coupled temperaturephase transformation kinetics and temperature-microstructure dependent material properties. Calculated results were compared with previous experimental data to verify the method, which showed good agreements.

• Journal of The Korean Astronomical Society
• /
• v.48 no.2
• /
• pp.139-154
• /
• 2015

We carry out three-dimensional hydrodynamic simulations of the supernova remnants (SNRs) produced inside molecular clouds (MCs) near their surface using the HLL code (Harten et al. 1983). We explore the dynamical evolution and the X-ray morphology of SNRs after breaking through the MC surface for ranges of the explosion depths below the surface and the density ratios of the clouds to the intercloud media (ICM). We find that if an SNR breaks out through an MC surface in its Sedov stage, the outermost dense shell of the remnant is divided into several layers. The divided layers are subject to the Rayleigh-Taylor instability and fragmented. On the other hand, if an SNR breaks through an MC after the remnant enters the snowplow phase, the radiative shell is not divided to layers. We also compare the predictions of previous analytic solutions for the expansion of SNRs in stratified media with our onedimensional simulations. Moreover, we produce synthetic X-ray surface brightness in order to research the center-bright X-ray morphology shown in thermal composite SNRs. In the late stages, a breakout SNR shows the center-bright X-ray morphology inside an MC in our results. We apply our model to the observational results of the X-ray morphology of the thermal composite SNR 3C 391.

• KIEE International Transactions on Electrophysics and Applications
• /
• v.11C no.2
• /
• pp.6-11
• /
• 2001

Abstract- In this paper, a new Partial Discharge (PD) detection using Pockels cell was proposed and considerable apparent chaotic characteristics were discussed. For this purpose, PD was generated from needle-plane electrode in air and detecte by optical measuring system using Pockels cell, based on Mach-Zehner interferometer, consisting of He-Ne laser, single mode optical fiber, 50/50 beam splitter and photo detector. In addition, the presence of chaos of the PD signals has been investigated by examining their means of qualitative and quantitative information. For the former, return map and 3-dimensional strange attractor have been drawn in order to investigate the presence of chaotic characteristics relevant to PD signals, detected through CT and Peckels sensor respectively, in the normalized time series. The presence of strange attractor indicates the existence of fractal structures in it's phase space. For the latter, several dimension values of strange attractor were verified sequentially. Throughout this paper, it is likely that the chaotic characteristics regarding the PD signals under air are verified.