• Food Science and Biotechnology
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• v.16 no.6
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• pp.954-957
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• 2007

Gelation mechanism of xanthan-carob mixture (X/C) was investigated based on thermorheological behavior. Three X/C ratios (1:3, 1:1, and 3:1) were studied. Small amplitude oscillatory shear tests were performed to measure linear viscoelastic behavior during gelation. Temperature sweep ($-1^{\circ}C/min$) experiments were conducted. Using a non-isothermal kinetic model, activation energy (Ea) during gelation was calculated. At 1% total concentration, the Ea for xanthan fraction (${\phi}_x$)=0.25, 0.5, and 0.75 were 178, 159, and 123 kJ/mol, respectively. However, a discontinuity was observed in the activation energy plots. Based on this, two gelation mechanisms were presumed-association of xanthan and carob molecules and aggregation of polymer strands. The association process is the primary mechanism to form 3-D networks in the initial stage of gelation and the aggregation of polymer strands played a major role in the later stage.

• Bulletin of the Korean Chemical Society
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• v.34 no.4
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• pp.1096-1100
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• 2013

The kinetic studies on the reactions of O-methyl (1), O-propyl (3) and O-isopropyl (4) phenyl phosphonochloridothioates with substituted anilines and deuterated anilines have been carried out in acetonitrile at $55.0^{\circ}C$. A concerted $S_N2$ mechanism is proposed for the anilinolyses of 1, 3 and 4. The anilinolysis rates of the phosphonochloridothioates are predominantly dependent upon the steric effects over the inductive effects of the two ligands. The deuterium kinetic isotope effects (DKIEs; $k_H/k_D$) are primary normal with 1 and 3, while secondary inverse with 4. Primary normal and secondary inverse DKIEs are rationalized by frontside and backside nucleophilic attack transition state, respectively. The DKIEs of the phosphonochloridothioates do not have any consistent correlations with the two ligands.

• Journal of the Society of Naval Architects of Korea
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• v.32 no.2
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• pp.93-102
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• 1995

A series of test was performed by measuring the failure strength and the failure mode of fiber reinforced composite laminates joint containing two holes in Series or Parallel. $[0^{\circ}/45^{\circ}/90^{\circ}/-45^{\circ}]_s$ laminate with W/d(Side distance ratio) 4.0 and E/d(Edge distance ratio) 3.0 has the full bearing strength and are preferable in case of the good efficiency in two series hole. Comparisons were made between testing results and predicting values of the FEM model. Good agreements were fecund between them except the case of $E/d=2{\sim}3$. In the case of $G_h{\geq}3.0d$ and $G_v{\geq}3.0d$ since the interaction coefficients between two parallel holes and between two series holes were small, holes can be treated as independent. The Acoustic Emission(AE) and SEM method were utilized to find out the initial defects, damage and the fracture mechanism.

• Transactions of the Korean Society of Automotive Engineers
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• v.21 no.3
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• pp.74-81
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• 2013

Due to its accuracy and efficiency, reduced kinetic mechanism of diesel surrogate is widely used as fuel model when applying 3-D diesel engine simulation. But for the well-developed prediction of diesel surrogate reduced kinetic mechanism, it is important to know some meaningful factors which affect to ignition delay time. Meanwhile, ignition delay time consists of two parts. One is the chemical ignition delay time related with the chemical reaction, and the other is the physical ignition delay time which is affected by physical behavior of the fuel droplet. Especially for chemical ignition delay time, chemical properties of each fuel were studied for a long time, but researches on their mixtures have not been done widely. So it is necessary to understand the chemical characteristics of their mixtures for more precise and detailed modeling of surrogate diesel oil. And it shows same ignition trend of paraffin mixture with those of single component, and shorter ignition delay at low/high initial temperature when mixing paraffin and toluene.

• Journal of Advanced Marine Engineering and Technology
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• v.27 no.3
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• pp.447-452
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• 2003

Crevice corrosion is localized form of corrosion usually associated with a stagnant solution on the micro-environmental level. Such stagnant micro environments tend to occur in crevices (shielded areas) such as those formed under gaskets washers insulation material. fastener heads. surface deposits. disbonded coatings. threads. lap joints and clamps. Crevice corrosion is initiated by changes in located electrochemical reaction within the crevice such as a) depletion of inhibitor in the crevice b) depletion of oxygen in the crevice c) a shift to acid conditions in the crevice and d) build-up of aggressive ion species (e.g chloride) in the crevice. In this study. the mechanism of crevice corrosion for Type 430 stainless steel is investigated undercondition that the size of specimen is $15{\times}20\{times}3mm$, in 1N $H_2SO_4$ + 0.05N NaCl solution. and the artificial crevice gap size of 3 x 0.2 x 15 mm. Crevice corrosion is measured under applied potential -300mV(SCE) to the external surface. The obtained result of this study showed that 1) the induced time for initiation of crevice is 750 seconds. 2) potential of the crevice was about from -320mV to -399mV. which is lower than that of external surface potential of -300mV It is considered that potential drop in the crevice is one of mechanisms for the crevice corrosion

• Bulletin of the Korean Chemical Society
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• v.19 no.7
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• pp.776-779
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• 1998

Second-order rate constants have been measured spectrophotometrically for the addition reaction of a series of alicyclic amines to 3-butyn-2-one to yield their respective enamines at 25.0 'C. The reactivity of the amines increases with increasing the basicity of the amines. However, the Bronsted-type plot obtained exhibits a downward curvature as the basicity of the amines increases, i.e. βnuc decreases from 0.3 for low basic amines (pKa < 9) and to 0.1 for highly basic amines (pKa > 9). Such a curvature in the Bronsted-type plot is clearly indicative of a change in the reaction mechanism or transition state structure. From the corresponding reactions run in D2O, the magnitude of kinetic isotope effect (KIE) has been calculated to be about 0.8 for highly basic amines and 1.21 for weakly basic amines. The difference in the magnitude of KIE also supports a change in the reaction mechanism or transition state structure upon changing the basicity of the amines. Furthermore, the small KIE clearly suggests that H+ transfer is not involved in the rate-determining step, i.e. the addition reaction is considered to proceed via a stepwise mechanism in which the attack of the amines to the acetylene is the rate-determining step. The curvature in the Bronsted-type plot has been attributed to a change in the degree of bond formation between the amine and the acetylene.

• The Bulletin of The Korean Astronomical Society
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• v.41 no.1
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• pp.82-82
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• 2016

To find the relationship between solar flares and halo CMEs using stereoscopic observations, we investigate 182 flare-associated halo CMEs among 306 front-side halo CMEs from 2009 to 2013. We have determined the 3D parameters (radial speed and angular width) of these CMEs by applying StereoCAT to multi-spacecraft data (SOHO and STEREO). For this work, we use flare parameters (peak flux and fluence) taken from GOES X-ray flare list and 2D CME parameters (projected speed, apparent angular width, and kinetic energy) taken from CDAW SOHO LASCO CME catalog. Major results from this study are as follows. First, the relationship between flare peak flux (or fluence) and CME speed is almost same for both 2D and 3D cases. Second, there is a possible correlation between flare fluence and CME width, which is more evident in 3D case than 2D one. Third, the flare fluence is well correlated with CME kinetic energy (CC=0.63). Fourth, there is an upper limit of CME kinetic energy for a given flare fluence (or peak flux). For example, a possible CME kinetic energy ranges from 1030.6 to 1033 erg for a given X1.0 class flare. Our results will be discussed in view of the physical mechanism of solar eruptions.

• Journal of Information Technology Services
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• v.21 no.5
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• pp.107-127
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• 2022

Personal broadcasting utilizing Vtuber, a virtual creator made of 2D or 3D avatars, has recently appeared and is growing in popularity. Vtuber is a virtual person who broadcasts on the Internet using 2D or 3D avatars with real-time motion capture and computer graphics technologies. While the personal broadcasting industry utilizing Vtuber is proliferating, related studies have mainly concentrated on technical issues. Therefore, in this study, the antecedent factors that form the technical characteristics and virtual creator characteristics of Vtuber personal broadcasting are derived using the Stimulus-Organism-Response (S-O-R) model. Then the effect of these factors on viewer pleasure and satisfaction, which lead to increased paid sponsorship is to be examined. Furthermore, we investigate how this influencing mechanism fluctuates based on the avatar type (2D vs. 3D). This study contributes to empirical examinations of viewers' paid sponsorship intention in Vtuber personal broadcasting through the S-O-R model. It also offers insights that technological or virtual creator characteristics could improve viewers' pleasure, satisfaction, and even paid sponsorship.

• Bulletin of the Korean Chemical Society
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• v.35 no.6
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• pp.1706-1712
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• 2014

The OH($X^2{\Pi}$, ${\upsilon}^{\prime\prime}=0,1$) internal state distribution following the reaction of electronically excited oxygen atom ($O(^1D_2)$) with cyclo-$C_3H_6$ has been measured using laser-induced fluorescence, and compared with that following the reaction of $O(^1D_2)$ with $C_3H_8$. The overall characteristics of the OH internal energy distributions for both reactions were qualitatively similar. The population propensity of the ${\Pi}(A^{\prime})$ ${\Lambda}$-doublet sub-level suggested that both reactions proceeded via an insertion/elimination mechanism. Bimodal rotational population distributions supported the existence of two parallel mechanisms for OH production, i.e., statistical insertion and nonstatistical insertion. However, detailed analysis revealed that, despite the higher exoergicity of the reaction, the rotational distribution of the OH following the reaction of $O(^1D_2)$ with $C_3H_8$ was significantly cooler than that with cyclo-$C_3H_6$, especially in the vibrational ground state. This observation was interpreted as the effect of the flexibility of the insertion complex and faster intramolecular vibrational relaxation (IVR).

• The Bulletin of The Korean Astronomical Society
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• v.37 no.1
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• pp.85.2-85.2
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• 2012

In this paper, we introduce the 3D modeling of the coronal magnetic field in the solar active region by extrapolating from the 2D observational data numerically. First, we introduce a nonlinear force-free field (NLFFF) extrapolation code based on the MHD-like relaxation method implementing the cleaning a numerical error for Div B proposed by Dedner et al. 2002 and the multi-grid method. We are able to reconstruct the ideal force-free field, which was introduced by Low & Lou (1990), in high accuracy and achieve the faster speed in the high-resolution calculation (512^3 grids). Next we applied our NLFFF extrapolation to the solar active region NOAA 10930. First of all, we compare the 3D NLFFF with the flare ribbons of Ca II images observed by the Solar Optical Telescope (SOT) aboard on the Hinode. As a result, it was found that the location of the two foot-points of the magnetic field lines well correspond to the flare ribbon. The result indicates that the NLFFF well capture the 3D structure of magnetic field in the flaring region. We further report the stability of the magnetic field by estimating the twist value of the field line and finally suggest the flare onset mechanism.