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A Study on the Phase Transformations of (TiAl)N Films Deposited by TFT Sputtering System (TFT(Two-Facing-Targets) 스퍼터장치에 의해 증착된 (TiAl)N 박막의 상변태에 관한 연구)

  • Han, Chang-Suk
    • Journal of the Korean Society for Heat Treatment
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    • v.18 no.5
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    • pp.281-287
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    • 2005
  • Titanium aluminium nitride((TiAl)N) film is anticipated as an advanced coating film with wear resistance used for drills, bites etc. and with corrosion resistance at a high temperature. In this study, (TiAl)N thin films were deposited both at room temperature and at elevated substrate temperatures of 573 to 773 K by using a two-facing-targets type DC sputtering system in a mixture Ar and $N_2$ gases. Atomic compositions of the binary Ti-Al alloy target is Al-rich (25Ti-75Al (atm%)). Process parameters such as precursor volume %, substrate temperature and Ar/$N_2$ gas ratio were optimized. The crystallization processes and phase transformations of (TiAl)N thin films were investigated by X-ray diffraction, field-emission scanning electron microscopy. The microhardness of (TiAl)N thin films were measured by a dynamic hardness tester. The films obtained with Ar/$N_2$ gas ratio of 1:3 and at 673 K substrate temperature showed the highest microhardness of $H_v$ 810. The crystallized and phase transformations of (TiAl)N thin films were $Ti_2AlN+AlN{\rightarrow}TiN+AlN$ for Ar/$N_2$ gas ratio of 1:3, $Ti_2AlN+AlN{\rightarrow}TiN+AlN{\rightarrow}Ti_2AlN+TiN+AlN$ for Ar/$N_2$ gas ratio of 1:1 and $TiN+AlN{\rightarrow}Ti_2AlN+TiN+AlN{\rightarrow}Ti_2AlN+AlN{\rightarrow}Ti_2AlN+TiN+AlN$ for Ar/$N_2$ gas ratio of 3:1. The above results are discussed in terms of crystallized phases and microhardness.

Optical properties of the $A1_{0.15}$$Ga_{0.85}$N/GaN thin film ($A1_{0.15}$$Ga_{0.85}$N/GaN 박막의 광학적 특성)

  • 정상조;차옥환;서은경;김영실;신현길;조금재;남승재
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.6
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    • pp.553-557
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    • 1999
  • In order to investigate the optical properties of the $Al_XGa_{1-X}N/GaN$ thin film grown by metalorganic chemical vapor deposition (MOCVD) method, the photoluminescene (PL), photocurrent (PC) and persistent photoconductivity (PPC) measurements were carried out at room temperature. The band gap of the $A1_x$$Ga_{1-x}$N/GaN was determined to 3.70 eV by the PL and PC measurements. The PC measurement on the light illumination from the top of the $A1_x$$Ga_{1-x}$N/GaN thin film provides peaks at 3.70, 3.43, and around 2.2 eV. The PC spectrum by the illumination passing through from the substrate of the sample can be shown at 3.43 eV together with a broad tail band from the GaN band edge to around 2.23 eV. The photocurrent quenching and anomalous PPC decay observed in PPC measurements indicate that metastable electron states are fomed in the band gap of GaN layer to trap electrons which can be tunneled the potential barrier for long recovery time.

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Comparison of Chlorine, Chlorine Dioxide and Ozone as Disinfectants in Drinking Water (정수소독공정에 이용되는 염소, 이산화염소, 오존 소독제의 비교, 고찰에 관한 연구)

  • Lee, Yoon-Jin;Lee, Sun-Jong;Lee, Dong-Chan;Kim, Hyun;Lee, Hwan;Lee, Cheol-Hyo;Nam, Sang-Ho
    • Journal of Environmental Health Sciences
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    • v.28 no.3
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    • pp.1-8
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    • 2002
  • The experiments for the characterization of inactivation were performed in a series of batch processes with the total coliform as a general indicator organism based on chlorine, chlorine dioxide and ozone as disinfectants. The water sam-ples were taken from the outlet of settling basin in a conventional surface water treatment system that is provided with the raw water drawn from the mid-stream of the Han River. The inactivation of total coliform was experimentally ana-lyzed for the dose of disinfectant contact time, pH, Temperature and DOC. The nearly 2.4,3.0,3.9 log inactivation of total coliform killed by injecting 1 mか1 at 5 minutes for chlorine, chlorine dioxide and ozone. For the inactivation of 99.9%(3 log), Disinfectants required were 1.70, 1.00 and 0.60 mか1 for chlorine, chlorine dioxide and ozone, respec-tively. The higher the pH is, the poorer the disinfections effects are in the range of pH 6-9 by using chlorine and ozone. But the irfluence of pH value on killing effects of chlorine dioxide is weak. The parameters estimated by the models of Chick-Watson, Hom, and Selleck from our experimental data obtained for chlorine are: log(N/ $N_{0}$ )=-0.16 CT with n= 1, log(N/ $N_{0}$ )=-0.71 $C^{0.87}$T with n$\neq$1, for Chicks-Watson model, log (N/ $N_{0}$ )= -1.87 $C^{0.47}$ $T^{0.36}$ for Hom model. For chlorine dioxide are: log(N/ $N_{0}$ )= -1.53 CT with n = 1, log(N/ $N_{0}$ )= -2.29 $C^{0.94}$T with n$\neq$1,, for Chicks-Watson model, log(N/ $N_{0}$ )= -3.64 $C^{0.43}$ $T^{0.24}$ for Hom model and for ozone are: log(N/ $N_{0}$ )= -2.59 CT with n = 1, log(N/ $N_{0}$ )= -2.28 $C^{0.36}$T with n$\neq$1, for Chicks-Watson model, log(N/ $N_{0}$ )= -4.53 $C^{0.26}$ $T^{0.19}$ for Hom model.19/ for Hom model.

A CHARACTERIZATION OF GAMMA DISTRIBUTION BY INDEPENDENT PROPERTY

  • Lee, Min-Young;Lim, Eun-Hyuk
    • Journal of the Chungcheong Mathematical Society
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    • v.22 no.1
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    • pp.1-5
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    • 2009
  • Let {$X_n,\;n{\geq}1}$ be a sequence of independent identically distributed(i.i.d.) sequence of positive random variables with common absolutely continuous distribution function(cdf) F(x) and probability density function(pdf) f(x) and $E(X^2)<{\infty}$. The random variables $\frac{X_i{\cdot}X_j}{(\Sigma^n_{k=1}X_k)^{2}}$ and $\Sigma^n_{k=1}X_k$ are independent for $1{\leq}i if and only if {$X_n,\;n{\geq}1}$ have gamma distribution.

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Totally umbilic lorentzian surfaces embedded in $L^n$

  • Hong, Seong-Kowan
    • Bulletin of the Korean Mathematical Society
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    • v.34 no.1
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    • pp.9-17
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    • 1997
  • Define $\bar{g}{\upsilon, \omega) = -\upsilon_1\omega_1 + \cdots + \upsilon_n\omega_n$ for $\upsilon, \omega in R^n$. $R^n$ together with this metric is called the Lorentzian n-space, denoted by $L^n$, and $R^n$ together with the Euclidean metric is called the Euclidean n-space, denoted by $E^n$. A Lorentzian surface in $L^n$ means an orientable connected 2-dimensional Lorentzian submanifold of $L^n$ equipped with the induced Lorentzian metrix g from $\bar{g}$.

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Interpretation and Prospection of Influenza Virus through Swine-origin Influenza Virus (신종플루 바이러스를 통한 인플루엔자 바이러스의 해석 및 전망)

  • Chang, Kyung-Soo
    • Korean Journal of Clinical Laboratory Science
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    • v.42 no.1
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    • pp.1-15
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    • 2010
  • Swine influenza virus (SIV) or swine-origin influenza virus (S-OIV) is endemic in swine, and classified into influenza A and influenza C but not influenza B. Swine influenza A includes H1N1, H1N2, H3N1, H3N2 and H2N3 subtypes. Infection of SIV occurs in only swine and that of S-OIV is rare in human. What human can be infected with S-OIV is called as zoonotic swine flu. Pandemic 2009 swine influenza H1N1 virus (2009 H1N1) was emerged in Mexico, America and Canada and spread worldwide. The triple-reassortant H1N1 resulting from antigenic drift was contained with HA, NA and PB1 of human or swine influenza virus, PB2 and PA polymerase of avian influenza virus, and M, NP and NS of swine influenza virus, The 2009 H1N1 enables to transmit to human and swine. The symptoms and signs in human infected with 2009 H1N1 virus are fever, cough and sore throat, pneumonia as well as diarrhea and vomiting. Co-infection with other viruses and bacteria such as Streptococcus pneumoniae can occur high mortality in high-risk population. 2009 H1N1 virus was easily differentiated from seasonal flu by real time RT-PCR which contributed rapid and confirmed diagnosis. The 2009 H1N1 virus was treated with NA inhibitors such as oseltamivir (Tamiflu) and zanamivir (Relenza) but not with adamantanes such as amantadine and rimantadine. Evolution of influenza virus has continued in various hosts. Development of a more effective vaccine against influenza prototypes is needed to protect new influenza infection such as H5 and H7 subtypes to infect to multi-organ and cause high pathogenicity.

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Theoretical study for the molecular structures and spectroscopic properties of various boron hydrides (BnHn, BnHn+1, BnHn+2, n = 3-6) (수소화붕소[BnHn, BnHn+1, BnHn+2 (n = 3-6)]의 분자구조 및 분광학적 성질에 대한 이론 연구)

  • Kim, Si-Jo;Song, Mi-Sun;Kim, Seung-Joon
    • Journal of the Korean Chemical Society
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    • v.54 no.4
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    • pp.387-394
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    • 2010
  • The theoretical calculations for $B_nH_n$, $B_nH_{n+1}$, $B_nH_{n+2}$ (n = 3-6) have been considered at the B3LYP level of theory with the 6-311G$^*$ basis set. The optimized geometries, harmonic vibrational frequencies, and binding energies are evaluated to elucidate the thermodynamic stability and spectroscopic properties. The harmonic vibrational frequencies for the molecules considered in this study show all real numbers implying true minima and the binding energies are corrected using zero-point vibrational energies (ZPVE). The binding energies and average energies due to increasing of BH monomer are predicted.

The Interaction of Gallium Bromide with n-Propyl Bromide in Nitrobenzene and 1,2,4-Trichlorobenzene (니트로벤젠溶液 및 1,2,4-트리클로로벤젠溶液內에서의 브롬화갈륨과 n-브롬화프로필과의 相互作用)

  • Oh Cheun Kwun;Young Cheul Kim;Dong Sup Lee
    • Journal of the Korean Chemical Society
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    • v.24 no.4
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    • pp.302-309
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    • 1980
  • The solubilities of n-propyl bromide in nitrobenzene and in 1,2,4-trichlorobenzene have been measured at 19, 25 and $40^{\circ}C$ in the presence and absence of gallium bromide. When gallium bromide does not exist in the system, the solubility of n-propyl bromide in nitrobenzene is greater than in 1,2,4-trichlorobenzene, indicating a stronger interaction of n-propyl bromide with nitrobenzene than with 1,2,4-trichlorobenzene. In the presence of gallium bromide, 1: 1 complex $n-C_3H_7Br\cdotGaBr_3$ is formed in the solution. The instability constant K of the complex was evaluated. $$n-C_3H_7Br\cdotGaBr_3 \rightleftarrows n-C_3H_7Br + \frac{1}{2Ga_2Br_6 }$$The change of enthalpy, free energy and entropy for the dissociation of the complex were also calculated. It seems that the stabilities of the complex, gallium bromide with alkyl bromide, are relatively concerned with the stabilities of the alkyl ion.

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A RESULT ON AN OPEN PROBLEM OF LÜ, LI AND YANG

  • Majumder, Sujoy;Saha, Somnath
    • Bulletin of the Korean Mathematical Society
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    • v.58 no.4
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    • pp.915-937
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    • 2021
  • In this paper we deal with the open problem posed by Lü, Li and Yang [10]. In fact, we prove the following result: Let f(z) be a transcendental meromorphic function of finite order having finitely many poles, c1, c2, …, cn ∈ ℂ\{0} and k, n ∈ ℕ. Suppose fn(z), f(z+c1)f(z+c2) ⋯ f(z+cn) share 0 CM and fn(z)-Q1(z), (f(z+c1)f(z+c2) ⋯ f(z+cn))(k) - Q2(z) share (0, 1), where Q1(z) and Q2(z) are non-zero polynomials. If n ≥ k+1, then $(f(z+c_1)f(z+c_2)\;{\cdots}\;f(z+c_n))^{(k)}\;{\equiv}\;{\frac{Q_2(z)}{Q_1(z)}}f^n(z)$. Furthermore, if Q1(z) ≡ Q2(z), then $f(z)=c\;e^{\frac{\lambda}{n}z}$, where c, λ ∈ ℂ \ {0} such that eλ(c1+c2+⋯+cn) = 1 and λk = 1. Also we exhibit some examples to show that the conditions of our result are the best possible.