• Title/Summary/Keyword: 흡수폴리머

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Fortification of Rice with Soy Hydrosylate Containing CHP (Cyclo Histidine-Proline) (CHP(Cyclo His-Pro) 함유 대두가수분해물을 이용한 코팅 쌀의 제조)

  • Lee, Hyun Jung;Park, Hyein;Park, Yooheon;Suh, Hyung Joo
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.42 no.3
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    • pp.415-420
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    • 2013
  • A method for coating rice with a novel substance, SHC [soybean hydrolysate with Cyclo Histidine-Proline (CHP)], was developed to produce functional rice for food production. The dip coating and spray coating method was tested to reduce the loss of functionality during the manufacturing of enriched rice. The dip coating method showed a very low absorption rate ($0.079min^{-1}$) of the functional substance compared to control ($0.150min^{-1}$), while the spray-coating method with protective coating materials [a methyl cellulose solution (l%, w/v) containing 5% (w/v) of the SHC] showed relatively adequate absorption characteristics. A light yellowish stain was observed in the rice samples processed by the spray-coating method (b value; surface1 0.69, flour 4.91) compared to raw rice (b value; surface 9.67, flour 4.86). The microscopic appearance of whole kernels and longitudinal sections revealed that cracks formed in all rice samples, regardless of the coating method. In conclusion, spray coating is a potential method for producing SHC-fortified rice with excellent physical characteristics.

Effects of Annealing Temperature on Electromagnetic Wave Absorption Characteristics in FeCuNbSiB Alloy Flakes/Polymer Composite Sheets (FeCuNbSiB 합금 박편/폴리머 복합 시트의 전자파 흡수 특성에 미치는 자성분말 어닐링 온도의 영향)

  • Noh, Tae-Hwan;Lee, Tae-Gyu
    • Journal of the Korean Magnetics Society
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    • v.17 no.5
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    • pp.198-204
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    • 2007
  • The effects of annealing temperature on electromagnetic wave absorption characteristics in $Fe_{73.5}Cu_1Nb_3Si_{15.5}B_7$ (at%) alloy flakes/polymer composite sheets available for quasi-microwave band have been investigated. The composite sheet including the magnetic flakes annealed at $425{\sim}475^{\circ}C$ for 1 h exhibited highest power loss in the GHz frequency range as compared with the sheets composed of the alloy flakes annealed at higher temperature than $475^{\circ}C$ or in as-milled state. Moreover the imaginary part of complex permeability had largest value in the GHz frequency range for the sheets including the flakes annealed at $425{\sim}475^{\circ}C$. The large value of power loss of the sheets including the magnetic flakes annealed at $425{\sim}475^{\circ}C$ was attributed to the high imaginary part of the complex permeability. However, because of its large transmission parameter $S_{21}$, the composite sheet having the magnetic flakes annealed at $525^{\circ}C$ showed low power loss.

Analysis of ${\beta}-(1{\to}3)(1{\to}6)-Glucan$ Produced by Aureobasidium pullulans IMS-822 (Aureobasidium pullulans IMS-822가 생산하는 ${\beta}-(1{\to}3)(1{\to}6)-Glucan$의 특성 분석)

  • Lee, Seog-June;Ahn, Keug-Hyun;Park, Chan-Sun;Yoon, Byung-Dae;Kim, Min-Soo
    • Korean Journal of Microbiology
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    • v.45 no.1
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    • pp.63-68
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    • 2009
  • The exo-polysaccharide producing microorganism, Aureobasidium pullulans IMS-822, was isolated and identified from soil. The viscosity-average molecular weight of exo-polysaccharide was calculated as $8.9{\times}10^5$ by Mark-Houwink equation. The sugar component of exo-polysaccharide was determined as glucose by HPLC analysis. The IR spectra indicated that the exo-polysaccharide has an absorption peak at 890 $cm^{-1}$ for the ${\beta}-configuration$ of D-glucan. The $^{13}C$ NMR signal at ${\delta}$ 86.62 ppm arose from the substituted C-3 of glucose. The signal at ${\delta}$ 72.11 ppm was assigned to C-6 of branched ${\beta}-(1{\to}3)-D-glucosyl$ residues. Viscosity and Congo red reaction indicated that {\beta}-(1{\to}3)(1{\to}6)-glucan$ produced by A. pullulans IMS-822 has a highly ordered hydrogen-bond dependent conformation in aqueous solution, which collapses in strong alkaline solution.

Stacks of Two Different-sized Gold Nanodisks for Biological Imaging

  • Park, Ji-Su;Jeong, Dong-Geun;Lee, Tae-Geol;Wi, Jeong-Seop
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.223.1-223.1
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    • 2015
  • 본 연구에서는 지름이 다른 두 개의 디스크가 적층된 구조를 갖는 금 나노 구조체를 제작하고 그 광학적 특성에 대해 연구하였다. 나노임프린팅을 통하여 패턴된 폴리머 포어 어레이에 금 박막을 증착하고, 포어 내부에 증착된 금 나노구조체를 선택적으로 수거하는 방법을 이용하였다 [1]. 특히 금 증착 시, 빗각으로 증착 (oblique-angle deposition)을 하여 지름이 다른 두 개의 디스크가 적층되어 있는 구조를 형성하는 것이 가능하였다. 증착 각도의 조절을 통해 적층된 두 디스크의 지름 비율을 변화시킬 뿐만 아니라, 2차원 디스크 형태의 나노구조체부터 3차원 디쉬 형태의 구조체도 제작이 가능함을 확인하였다. 제안된 하향식 나노공정을 통하여 합성된 금 나노구조체를 이용하여 광열 전환(photothermal heat conversion)과 광 간섭성 단층 (optical coherence tomography) 측정을 진행하였고, 서로 다른 두 개의 디스크가 적층된 형태의 금 나노구조체는 상용 금 나노로드 (Au nanorod) 보다 높은 광 열 전환 효율을 갖을 뿐 아니라 우수한 OCT 이미징 특성을 보였다. 광열 전환 및 OCT 이미징 실험 결과는 각각 플라즈모닉 나노구조의 광흡수, 광산란 특성에 기반하므로, 본 연구를 통하여 제안된 금 나노구조체는 광흡수 및 광산란을 기반한 바이오이미징 나노프로브로 유용하게 사용될 수 있을 것으로 전망된다.

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The Impact fracture Behaviors of Low Density LD Carbon/Carbon Composites by Drop Weight Impact Test (낙하 충격 시험에 의한 저밀도 2-D탄소/탄소 복합재의 충격파괴거동)

  • 주혁종;손종석
    • Polymer(Korea)
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    • v.26 no.2
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    • pp.270-278
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    • 2002
  • In this study, the fracture behavior by low velocity impact damage and the tendencies of impact energy absorption were investigated. Low velocity impact tests were performed using a mini tower drop weight impact tester, and graphite powder, carbon black and milled carton fiber were chosen as additives. Addition of graphite powder increased the maximum load and maintained the stress long until the total penetration happened. At the content of 9 vol%, they showed the maximum of 42% improvement in impact strength compared composites containing no additives. At the test with low impact energy of 0.4 J, impact energy was consumed by delamination in the composite containing no additives, however, as graphite contents increased, the tendency of failure changed to the penetration of the specimen.

Swelling Behavior of Low Toxic Absorbent Based on Biopolymer (생물고분자로 이루어진 저독성 흡수제의 팽윤거동)

  • Jung, Jin Hee;Kim, Jin;Lee, Ki-Young
    • Polymer(Korea)
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    • v.37 no.4
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    • pp.478-485
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    • 2013
  • In this study, hydrogels with fast swelling and high absorbent properties were prepared using biopolymers approved as a food additive and their swelling properties were characterized. To improve the swelling properties of conventional hydrogels, we formed gas bubbles using a foaming agent in the process of preparing hydrogels and characterized in terms of equilibrium swelling ratio, swelling kinetics and cytotoxicity. In particular, alginate hydrogels observed by a digital microscope have an open-pore channels structure with the sizes of hundreds micrometers. Also, the cell viability of all hydrogels were found to be much higher than that of poly(acrylic acid).

Introduction of Chromophores on the Activated Surface of Poly(2-trialkylstannylthioethyl acrylate) Films (Poly(2-trialkylstannylthioethyl acrylate) 필름의 표면 활성화를 통한 발색단 도입)

  • Yun, Jong Chul;Do, Jung Yun
    • Polymer(Korea)
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    • v.36 no.6
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    • pp.795-802
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    • 2012
  • Surface modification of a hydrophobic acrylic polymer film has been performed through simple chemical treatment to give a reactive surface. 2-Triphenylstannylthioethyl acrylate was polymerized under UV-illumination with various contents of a comonomer. When the polymer film was treated with fluoride ion, thiol functional group (SH) was generated on the film surface, which was observed through infrared absorption spectroscopy. The surface was functionalized by thiol addition reaction to acrylic chromophores. The SH content on the surface was controlled with a comonomer, tris(hydroxymethyl)ethane triacrylate, and examined with UV-Vis absorbance of the chromophore attached film. Similarly, a polymer film from 2-tributylstannylthioethyl acrylate was prepared. Destannylation from the triphenylstannyl and tributylstannyl surface completed after 30 and 5 min, respectively. The SH-exposed surface was modified with an isocyanate attached chromophore within 10 min, while acrylic chromophore required 24 h.

Molecular Interactions of Soaked Nonionic Dye in Ionomer Films (아이오노머 필름에 흡수된 비이온계 염료의 분자간 상호작용에 관한 연구)

  • ;;;;;;Forrest A. Landis;Robert B. Moore
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.671-678
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    • 2001
  • Sodium and zinc salts of poly(ethyaene-co-methacrylic acid) ionomers consist of three phases, i.e. ionic aggregates, amorphous, and crystalline phases. Dye molecules after soaked from the methanol solution are located near the amorphous phase or ionic aggregates within ionomer films. Depending on the location of the molecules in the ionomer film, they are under influence of dispersion forces (ethylene parts), polar forces (acid parts). and ionic dipole (ionic aggregates) interactions. The UV/Vis absorption peak of Nile Red under the dispersion force is found at near 500 nm, for the dye under the polar force effect 525 nm, and 550 and 610 nm for the dyes under $Na^+$ and $Zn^{2+}$ ionization effects, respectively. Since the divalent $Zn^{2+}$ ion has larger ionic dipole than the monovalent $Na^+$ ion, the larger red-shift of the absorption band due to the ionic dipole interaction is observed for $Zn^{2+}$ counter ion.

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Inverse Emulsion Polymerization of Water Absorbent Polymer for Strength Enhancement of Mortars (모르타르 강도 증진을 위한 고분자 흡수제의 역유화 중합)

  • Hwang, Ki-Seob;Jung, Myoung-Geun;Jang, Seok-Soo;Jung, Yong-Wook;Lee, Seung-Han;Ha, Ki-Ryong
    • Polymer(Korea)
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    • v.34 no.5
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    • pp.434-441
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    • 2010
  • Sodium polyacrylate (PAANa) was synthesized by inverse emulsion polymerization method to absorb excess water in concrete. Liquid paraffin was used as a continuous phase. Acrylic acid (AA) was neutralized by aqueous sodium hydroxide solution (8 M). Different amount of N,N'-methylene bisacrylamide (MBA) was used as a crosslinking agent to change crosslinking density of the synthesized PAANa. The size distribution of synthesized particles was measured by particle size analyzer. Swelling ratio of crosslinked PAANa was evaluated from the equation in D. I. water, cement aqueous solution, and $Ca(OH)_2$ aqueous solution. The FTIR spectroscopy was used to characterize $Ca^{2+}$ ion interaction with PAANa. Incorporation of 1.0 wt% PAANa into cement increased compressive and flexural strength approximately 30% and 10%, respectively, compared with those of ordinary portland cement.

Development of Medical Resorbable Composite Materials Interposed in the Poly(glycolic acid) (Poly(glycolic acid)를 심선에 지닌 의료용 흡수성 복합재료의 개발)

  • Lee, Chan-Woo
    • Polymer(Korea)
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    • v.31 no.3
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    • pp.228-232
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    • 2007
  • This purpose of this study is to enhance the hydrolysis of poly (butylene succinate-co-L-lactate) (PBSL) and poly [(R) -3-hydroxybutylate] (PHB), to develop materials with advanced medical absorbability and environmental suitability. The first method involves increasing the bioabsorbability of poly (glycolic acid) (PGA) in the core of the fibrous complex, while the second method involves making a complex fiber containing PBSL and PHB in the outer layer for improving environmental degradability Improvement in the hydrolysis of PBSL and PHB due to glycolic acid occurs by hydrolytic behavior of PGA. The drawing supporting the resulting PBSL/PGA fiber was executed at $65^{\circ}C$, where the orientation is well arranged in crystal form. Obtaining a PHB/PGA complex fiber in the proper crystal orientation at $50^{\circ}C$ was not possible since the arranged crystal orientation was only identified in drawings from temperatures above $50^{\circ}C$. Also, it is necessary to execute a smooth surface to achieve an on-line drawing since unevenness occurs in the fibrous surface from an in-line drawing.