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Determination of Rare Earth Elements by Inductively Coupled Plasma Mass Spectrometry with Introduction of Organic Phase Using Ultrasonic Nebulizer (초음파 분무기를 이용한 유기상의 주입에 의한 희토류 원소의 유도결합 플라스마 질량분석법적 정량)

  • Lee, Sang Hak;Son, Bum Mok
    • Analytical Science and Technology
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    • v.15 no.2
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    • pp.127-134
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    • 2002
  • Analytical method to determine rare earth elements which were extracted to organic phase by inductively coupled plasma mass spectrometry(ICP-MS) was investigated. Organic phase which had extracted rare earth elements was directly aspirated into ICP-MS by ultrasonic nebulizer(USN) in order to reduce solvent load to the plasma. Then, the count rate increased when MIBK(methyl isobutyl ketone) was added to EtOH(ethanol) but decreased when 0.03 M HEH(2-ethylhexyl-2-ethylhexyl phosphonic acid, $P_{507}$, PC88A) was added to solvent which mixed MIBK with EtOH. The optimal temperatures of desolvation system were -10 $^{\circ}C$ for the condenser and 150 $^{\circ}C$ for the heating tube. The optimal nebulizer flow rate which gave maximum count rate and minimum reflect power was 0.7 L/min. The optimal pH and extraction time were 4.3 and 10 min for MIBK-0.03 M HEH system. Detection limits which were obtained through calibration curves at the range of 0.2 ${\sim}$ 20 ng/mL were 0.02 ${\sim}$ 0.05 ng/mL under the optimal experimental conditions.

Numerical Analysis of the Non-Isothermal Heat Transfer in Solids Conveying Zone of a Single Screw Extruder (단축압출기 고체수송부에서의 비등온 열전달 현상에 관한 수치 해석)

  • Ahn Young-Cheol
    • Polymer(Korea)
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    • v.29 no.6
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    • pp.549-556
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    • 2005
  • Effects of the dimensionless variables on the heat transport phenomena in the extrusion process of a single screw extruder have been studied numerically. Based on the understanding of the solids conveying related to the geometrical structure and characteristics of the screw, the heat balance equation for the solids conveying zone was established and normalized. The finite volume method and power-law scheme were applied to derive a discretized equation and the equation was solved using the alternating direction iterative method with relaxation. Effects of the dimensionless parameters, Biot and Peclet numbers, that define the heat transfer characteristics of the solids conveying zone have been investigated with respect to the temperature of the feeding zone and the length of the solids conveying zone. As the Biot number is increased, the heat loss by cooling dominates to decrease the temperature of the barrel but it has little effects on the temperature of the solids bed and the length of the solids conveying zone. On the other hand, if the Peclet number is increased, the convection term dominates to decrease the temperature of the solids bed and it results in an increase in the length of the solids conveying zone.

An Enzyme-linked Immunosorbent Assay Strip Sensor for the Detection of Legionella Pneumophila (Legionella Pneumophila 검출을 위한 효소면역측정 스트립 센서)

  • Kim, Young-Kee;Park, Sojung
    • Applied Chemistry for Engineering
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    • v.25 no.5
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    • pp.544-547
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    • 2014
  • In this study, an enzyme-linked immunosorbent assay (ELISA) and immuno-chromatographic technique were combined to fabricate immuno-strip sensors for the detection of Legionella pneumophila. The immuno-strip sensor was manufactured with four different membranes. A nitrocellulose membrane was used to immobilize capture antibody and generate signals due to the high affinity to antibodies, and glass fiber membranes were used as a conjugate release pad and a sample application pad. A cellulose membrane was used as an absorption pad to induce sample flow by the capillarity. Colorimetric signals produced by sandwich immuno-reaction and enzyme reaction could be analyzed qualitatively and quantitatively within 30 min. Under the given experimental conditions, sensor signals with L. pneumophila samples were observed qualitatively by naked eyes and measured quantitatively in a range of $1.3{\times}10^3-1.3{\times}10^6CFU/mL$ with a digital camera and home-made image analysis software.

A Study on Heat Transfer Characteristics for Removal of Absorption Heat in Absorption Process of Ammonia-Water Bubble Mole (암모니아-물 기포분사형 흡수과정에서의 흡수열 제거를 위한 열전달 특성 연구)

  • Lee, Jae-Cheol;Lee, Ki-Bong;Chun, Byung-Hee;Lee, Chan-Ho;Ha, Jong-Joo;Kim, Sung-Hyun
    • Clean Technology
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    • v.7 no.4
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    • pp.273-280
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    • 2001
  • An absorber is a major component in the absorption refrigeration systems and its performance greatly affects the overall system performance. In this study, experimental analyses on heat transfer characteristics for removal of absorption heat in ammonia-water bubble mode absorber were performed. Heat transfer coefficients were estimated as the variations of input gas flow rate, solution flow rate, temperature, concentration, absorber diameter and height, and input flow direction. The increase of gas and solution flow rate affects positively in heat transfer. However, the increase of solution temperature and concentration affects negatively. Moreover, under the same Reynolds Numbers, countercurrent flow is superior to cocurrent flow in heat transfer performance. In addition, from these experimental data, empirical correlations which can explain easily the characteristics of heat transfer are derived.

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A Study on Safe Electronic Commerce Activation Plan (안전한 전자상거래 활성화 방안에 관한 연구)

  • Park, Sun-Ae;Choi, Seong-Wook;Kim, Bong-Hyun
    • Proceedings of the Korea Contents Association Conference
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    • 2006.11a
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    • pp.741-744
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    • 2006
  • The e-commerce introduction at the Internet in base accept the renovation dimension from the organised side because of follow of the business in order to the big change. So when I considering the e-commerce introducing the problem easy to originate from the efficiency and expectation without radical preparation. Each commodities over the dimension of Internet information search it is using the various transaction of service as a matter of bank, securities, education, game that many business on the alternation of e-commerce and commerce tool the essentiality. Therefore the transactions at the Internet e-commerce under hold specific gravity and rule in the future with the propection increase the interest concern about the security skill. A study on this paper presentation through the planning method about the analysis on the objective which e-commerce follow the inflection of efficiency strategy and induction the plan on the penetration's revitalization about Internet e-commerce.

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An Evaluation of Korean Accessibility Standards Supporting the People with Disabilities (실내환경에서 장애인의 접근.이동성을 지원하는 국내법규 평가)

  • 천진희;정회란
    • Archives of design research
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    • v.12 no.3
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    • pp.167-176
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    • 1999
  • This article analyzed the recent Korean accessibility standard supporting the people with disabilities. This is the basic study to make the interior environment more comprehensible and safer for the physically handicapped. Researcher selected the interior elements related to the mobility and accessibility for the physically handicapped. Then the '98 Korean accessibility standard code called 'Pyunui Chungjin Pup' were compared with the previous Korean building code and two other guidelines for evaluations. Result showed that 'Pyunui Chungjin Pup' addressed more obligatory items in facilities used by people with disabilities. That contributed to develope the accessible environments and to offer the independent activity in the society for the disabilities. However dimensions of 'Pyunui Chungjin Pup' showed the minimum standard. Also it did not provide the sufficient design considerations to make up the sufficient design considerations to make up the other types of disabilities including sensory limitations, or cognitive function limitations. Hereafter, the quality of accessibility guideline should be raised with further study.

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Estimating Profitability of Private Finance Investment Using Real Option : Quantifying Value of Overturn Share Ratio and Minimum Revenue Guarantee (실물옵션에 의한 민간투자사업 사업타당성 평가 : 초과수익분배비율 및 최소수입보장비율 가치 정량화)

  • Jung, Woo-Yong;Koo, Bon-Sang;Han, Seung-Heon
    • Proceedings of the Korean Institute Of Construction Engineering and Management
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    • 2008.11a
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    • pp.606-609
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    • 2008
  • Traditionally, the feasibility of the private investment is determined by NPV(Net Presented Value) based on DCF(Discounted Cash Flow) and the volume of government's subsidiary without quantifying the effect of overturn share ratio and MRG(Minimum Revenue Guarantee), these variables which can seriously effect on the economic feasibility. One of the most important reasons why these variables are not underestimated is that the quantifying methods are insufficiently or so complicatedly studied to apply practically the real project. Therefore, this study suggests the modified binominal option model to estimate the overturn share ratio and MRG and estimates how much these variables impact the private investment. Also, these results are helpful to estimate how much the government's subsidiary can be reduced.

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Analytic study on arsenic content in plastic materials (플라스틱 소재의 비소 함유량 분석에 관한 연구)

  • Lee, Jae-In;Choi, Zel-Ho;Choi, Ki-In;Ko, Byung-Rae;Choi, In-Suk;Cho, Hun-Sik
    • Analytical Science and Technology
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    • v.25 no.6
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    • pp.402-409
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    • 2012
  • Quantitative analytical condition for arsenic in plastic materials by the flow injection-hydride generation-inductively coupled plasma-atomic emission spectrometry was studied. The plastic samples were dissolved by wet-acid digestion method and microwave-acid digestion method. The reproducibility and accuracy in this method was verified using of certified reference materials(CRMs) CRM-EC680k and CRM-EC681k. The analyical results agrees with certified value within the range of uncertainty. The results of CRM-EC680k wer 4.1~4.3 mg/kg (certified value $4.1{\pm}0.5$ mg/kg), and the results of CRM-EC681k were 28.9~30.6 mg/kg (certified value $29.1{\pm}1.8$ mg/kg).

Object Feature Extraction and Matching for Effective Multiple Vehicles Tracking (효과적인 다중 차량 추적을 위한 객체 특징 추출 및 매칭)

  • Cho, Du-Hyung;Lee, Seok-Lyong
    • KIPS Transactions on Software and Data Engineering
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    • v.2 no.11
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    • pp.789-794
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    • 2013
  • A vehicle tracking system makes it possible to induce the vehicle movement path for avoiding traffic congestion and to prevent traffic accidents in advance by recognizing traffic flow, monitoring vehicles, and detecting road accidents. To track the vehicles effectively, those which appear in a sequence of video frames need to identified by extracting the features of each object in the frames. Next, the identical vehicles over the continuous frames need to be recognized through the matching among the objects' feature values. In this paper, we identify objects by binarizing the difference image between a target and a referential image, and the labelling technique. As feature values, we use the center coordinate of the minimum bounding rectangle(MBR) of the identified object and the averages of 1D FFT(fast Fourier transform) coefficients with respect to the horizontal and vertical direction of the MBR. A vehicle is tracked in such a way that the pair of objects that have the highest similarity among objects in two continuous images are regarded as an identical object. The experimental result shows that the proposed method outperforms the existing methods that use geometrical features in tracking accuracy.

Explicit Equations of Normal Depth for Drainage Pipes (하수관 등류수심 양해법 산정식)

  • Yoo, Dong-Hoon;Rho, Jung-Soo
    • Journal of Korea Water Resources Association
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    • v.38 no.7 s.156
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    • pp.527-535
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    • 2005
  • The computation of normal depth is very important for the design of channel and the analysis of water flow. Drainage pipe generally has the shape of curvature like circular or U-type, which is different from artificial triangular or rectangular channel. In this case, the computation of normal depth or the derivation of equations is very difficult because the change of hydraulic radius and area versus depth is not simple. If the ratio of the area to the diameter, or the hydraulic radius to the diameter of pipe is expressed as the water depth to the diameter of pipe by power law, however, the process of computing normal depth becomes relatively simple, and explicit equations can be obtained. In the present study, developed are the explicit normal depth equations for circular and U-type pipes, and the normal depth equation associated with Hagen (Manning) equation and friction factor equation of smooth turbulent flow by power law is also proposed because of its wide usage in engineering design.