• Title/Summary/Keyword: 회분식 실험

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A Study on the Monodispersed Silica Fine Particles Prepared by Using Batch-Semibatch Mixed Process (회분과 반회분의 혼합형 공정에 의해 생성된 단분산 실리카 미립자에 관한 연구)

  • Kim, Ki Do;Kim, Hee Taik
    • Applied Chemistry for Engineering
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    • v.10 no.8
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    • pp.1180-1185
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    • 1999
  • Modispersed silica fine particles were produced from the hydrolysis of $Si(OC_2H_5)_4$ by using batch-semibatch mixed systems. Four types of mixed process, i.e., batch-batch, batch-semibatch, semibatch-batch, semibatch-semibatch, were used in order to measure mean particle size, particle size distribution, yield, and packing density. As a result of the test, silica particles prepared by semibatch-semibatch process were larger than those prodeced from any other systems in particle size and yield. On the other hand, silica particles prepared by batch-semibatch process were better than those produced from any other systems in particle size distribution and packing density. Especially, it was found that particle size of $SiO_2$ prepared by semibatch-batch process decreased with increasing the reaction time. Therefore, batch-semibatch process was a successful method for controlling the size, i.e., a narrow distribution of a particle size which ranges to several microns.

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Sonolysis of Trichloroethylene in a Continuous Flow Reactor with the Multi Ultrasound Irradiation (연속식 다중 초음파 반응조에서 TCE의 초음파 분해)

  • Lee, Min-Ju;Oh, Je-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.6
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    • pp.419-427
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    • 2009
  • To test applicability for continuous flow treatment of ultrasound technology, sonolysis of TCE aqueous solution using 584 kHz multi irradiation reactor was performed under batch and continuous flow conditions. Under batch condition (3 and 4 sides irradiation, 600 W), first order degradation rate constant of TCE was higher under 4 sides than 3 sides irradiation conditions, while the generation of $H_2O_2$ and chloride was similar under both irradiation conditions. Under continuous flow condition with 4 sides irradiation, removal efficiencies of TCE in steady-state were decreased from 83 to 48% with increasing flow rate from 67 to 300 mL/min at 600 W, and were increased from 14 to 75% with increasing acoustic power from 100 to 600 W at 100 mL/min. Removal efficiency of TCE in groundwater was decreased 10% compared to in distilled water at 100 mL/min and 600 W.

촉매를 이용한 삼중수소수의 탈삼중수소반응

  • 정흥석;이한수;강희석;백승우;안도희;송명재;손순환
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.05b
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    • pp.787-791
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    • 1995
  • 중수형 원자력발전소의 중수는 중성자 흡수반응에 따라 그 일부가 삼중수소화 된다. 삼중수소의 제거반응에 효율적인 고분자 백금촉매를 제조하여 회분식 반응기에서 탈삼중수소 반응실험을 수행하였다. 기액접촉반응탑내에서 고분자 촉매는 탈삼중수소 반응에 유효한 활성이 있음을 확인하였다.

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Removal of Total Phosphate by Bipolar Packed Bed Electrolytic Cell (충전복극전해조에 의한 총 인 제거)

  • Kim, Eun-Hee;Park, Seung-Cho
    • Applied Chemistry for Engineering
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    • v.19 no.4
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    • pp.366-369
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    • 2008
  • To evaluate the performance of a bipolar packed bed cell (BPBC) filled with granular aluminium, the experiments were carried out in two groups as batch and continuous processes. In a batch process, removal efficiency of total phosphate (T-P) was 88% in case of electrolytic treatment of phosphate solution, T-P 10 mg/L at 6 V during 3 h by BPBC filled with granular aluminium. In a continuous process, residual T-P concentration was about 2 mg/L in case of electrolytic treatment of phosphate solution, 10 mg/L at 6 V, HRT 3 h by BPBC filled with granular aluminium. Break-through point was observed after running for 120 h at hydraulic retention time (HRT) of 3 h.

pH 조절에 의한 A. pullulans의 pullulan 생산성에 대한 영향

  • Kim, Jeong-Hwa;Hui, Ju-Yi;Kim, Mi-Ryeong;Lee, Ji-Hyeon;Kim, Seong-Gu
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.287-290
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    • 2000
  • The pullulan production and morphological change of Aureobasidium pullulans ATCC 42023 were investigated in shake-flasks and in 2.5L batch fermentor. In shake-flasks, maximum pullulan production was obtained with $11.98g/{\ell}$ when initial pH was 6.5. The batch fermentation was performed in the medium with pH control ranged pH 2.5-7.5. The maximum pullulan production of $13.31g/{\ell}$ was obtained with pH 4.5. However, the cell growth was the highest at pH 6.5.

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Correlation between Redox Potential and State Variables in Batch Cultures for Ornithine Production. (오르니틴 생산을 위한 회분식 배양에서 산화환원전위와 상태변수들간의 상관관계)

  • 이태호;나정걸;장용근;정봉현
    • Microbiology and Biotechnology Letters
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    • v.26 no.2
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    • pp.167-172
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    • 1998
  • In batch cultures of Brevibacterium ketoglutamicum for the L-ornithine production in which the pH and dissolved oxygen concentration were regulated constant, the profiles of redox potential were observed in parallel with the profiles of state variables such as cell, glucose, and ornithine concentrations. It was found that the redox potential had a close relationship with cell concentration and was also affected by ornithine concentration. The effects of ornithine and glucose on redox potential were examined in a separate series of experiments. Based on the experimental results, a correlation of redox potential to glucose, cell and ornithine concentrations has been proposed. The proposed correlation can be used for on-line estimation of ornithine concentration from on-line data of redox potential, glucose concentration, and cell concentration.

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Effect of pH on production of gellan by Pseudomnas eldoea ATCC 31461

  • Im, Seong-Mi;Lee, Ji-Hyeon;Kim, Seong-Gu
    • 한국생물공학회:학술대회논문집
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    • 2002.04a
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    • pp.201-204
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    • 2002
  • The gellan was extracellular polysaccharide produced by Pseudomonas elodea A TCC 31461 at aerobic condition. Gellan provides various functionalities such as gelling, suspending, stabilizing, emulsifying and binding properties in aqueous systems. In this study, the effect of pH on the cell growth and the gellan production were evaluated in shake- flasks and in 5 ${\ell}$ batch fermentor. In the shake-flasks culture, maximum gellan production was obtained with 1.66g/ ${\ell}$ when initial pH was 7.0. The batch fermentation was performed in the medium pH control ranged pH 5.5-8.5. The maximum gellan production of 1.97g/l was obtained with constant pH 6.0.

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Two-Stage Fed-Batch Culture of Candida magnoliae for the Production of Erythritol using an Industrial Medium (산업용 배지를 이용한 Candida magnoliae의 2단계 유가식 배양에서 에리스리톨의 생산)

  • 박선영;서진호;유연우
    • KSBB Journal
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    • v.18 no.4
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    • pp.249-254
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    • 2003
  • Experiments were carried out to select an industrial nitrogen source and optimize erythritol production by Candida magnoliae in fed-batch culture. Among the industrial nitrogen sources tested, light steep water (LSW) was found to be the best nitrogen source for producing erythritol, based on erythritol yield and raw material price. The maximum erythritol concentration obtained a 131.6 g/L, with a 52.6% yield and 0.52 g/L-hr productivity from a 250 g/L glucose and 43.3 mL/L LSW in batch culture. Two-stage fed-batch culture was chosen to improve the volumetric productivity and the yield of erythritol. High cell density culture in cell growth stage was achieved by batch type culture containing 100 g/L glucose and 500 mL/L LSW. The cell concentration was 71.0 g/L after 23 hours of culture. Erythritol productivity was decreased by increasing glucose concentration in the production stage. But 37.3% of the maximum erythritol yield was obtained with 185.5 g/L of erythritol and 1.66 g/L-hr of productivity when 820 g of glucose powder was directly added to a concentration of 450 g/L glucose in production stage.

Removal of As(III) and As(V) in Aqueous Phases by Fe and Mn Oxides Coated Granular Activated Carbon (철 및 망간 산화물로 코팅된 입자활성탄을 이용한 수용액 중 As(III) 및 As(V)의 제거)

  • Lee, Hee-Yong;Yang, Jung-Seok;Choi, Jae-Young;Lee, Seung-Mok
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.8
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    • pp.619-626
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    • 2009
  • The objective of this study was to evaluate the efficiency of Fe and Mn oxides coated granular activated carbons (FMOCGs) for the removal of arsenite and arsenate by oxidation and adsorption mechanisms using surface characterization and batch adsorption experiments. Within four manufactured adsorbents, Fe and Mn contents of FMOCG-1 was the highest (178.12 mg Fe/g and 11.25 mg Mn/g). In kinetic results, As(III) was removed by oxidation and adsorption with FMOCGs. Removal of arsenic by FMOCGs increased as pH value of the solution decreased. The adsorption isotherm results were well fitted with Langmuir isotherm. Adsorption amount of As(V) onto FMOCGs was higher than that of As(III) and the maximum adsorption capacities of FMOCGs for As(III) and As(V) were 1.38~8.44 mg/g and 2.91~9.63 mg/g, respectively.

Oxidation Reaction Characteristics of Waste Slurry in the Wet Desulfurization Process Using Mg(OH)$_2$ Absorbent (Mg(OH)$_2$를 이용한 습식탈황에서 폐슬러리 산화반응특성 연구)

  • 박영성;이은덕;김근범;이형근
    • Journal of Energy Engineering
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    • v.9 no.2
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    • pp.123-129
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    • 2000
  • Mg(OH)$_2$를 흡수제로 이용한 습식탈황에서 페슬러리에 대한 산화반응 특성을 고려하였다. SO3-2 전환율 (MgSO3 폐슬러리의 산화반응 전환율) 과 산소의 물질전달특성을 고찰하기 위해 회분식 및 연속식 실험을 수행하였따. 3리터 용량을 갖는 직사각형모양의 아크릴 반응기에서 공기/슬러리 공급비(20-60) , 수리학적 체류시간(HRT)(1-3hr), SO3-2 유입농도(1000-3000ppm)등의 변화조건에서 실험이 행하여졌다. 실험결과 SO3-2 전환율은 공기공급량과 체류시간에 비례하여 증가하였다. 또한 슬러리 공급에 대한 최적공기공급비 0.02ι/(ι.ppm)에서 MgSO3 폐슬러리는 90%이상 산화되었다.

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