• Title/Summary/Keyword: 환경지화학

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A Study on Development of Damage Impact Distance Calculation Formula for Accident Response and Prevention in case of Leakage of Substances Prepared for Evacuation of Residents in Chungju (충주의 주민대피 대비물질 누출사고 시 사고대응·예방을 위한 피해영향거리 산정식 개발 연구)

  • Jeon, Byeong-Han;Kim, Hyun-Sub;Lee, Myeong-Ji;Yun, Jeong-Hyeon;Jung, Woong-Yul;Oh, Seung-Bo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.1
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    • pp.703-712
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    • 2021
  • In this study, a formula was derived to calculate the damage impact distance using the Chemical Accident Response Information System (CARIS) so that local governments can decide on the evacuation and notification of 13 types of substances. The National Institute of Chemical Safety selected 16 out of 97 types of accident preparedness substances in 2018 and called them residents' evacuation preparedness substances. In a chemical accident, local governments should prepare for resident notification, such as emergency disaster texts. Using the CARIS in Chungju, this study modeled the damage-affected distances of 13 types of substances for the evacuation of residents. Under all conditions, the coefficient of determination R2 was 0.99 or higher, representing a range of at least 0.9921 to a maximum 0.9999. The relative standard deviation between the damage impact distance obtained using the calculation formula, and the CARIS result was compared. The minimum separation distance was corrected considering the actual chemical accident response situation, and the range was found to be between 0.58 and 5.97%. The damage impact distance can be calculated at the site using the calculation formula derived from the research, and local governments can determine whether to evacuate or notify residents.

A study on the Rationalization of Safety Management in Chemical Facilities: Focused on Architecture Fire Resistance Standards (화학물질 취급시설의 안전관리 합리화 방안 연구: 건축물 내화기준 중심)

  • Lee, Eun-Byul;Yoo, Byung-Tae
    • Fire Science and Engineering
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    • v.33 no.3
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    • pp.91-97
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    • 2019
  • In Korea, the Ministry of Environment's Chemical Control Act is the basis for hazardous chemical substances and safety management is being carried out. In particular, the standards for the installation and management of facilities are strongly managed. There were problems in the early stages of implementation, conflict with other laws, size of facilities and non-reflection of material properties. In this study, more realistic and reasonable improvement was planned for the fire-resistance standard of buildings among these facilities. We compared the fire resistance standards of buildings in the Korean similar chemical facility safety management ordinance. Key problems were identified through examples of representative complaints concerning the criteria for facilities. Finally, the Chemical Control Act provided an improvement measure to apply the building fire-resistance standard by clarifying the size and chemical of facilities. In the future, the results of this study are expected to be consistent with the basic purpose of the Chemicals Contral Act considering environmental hazards and contribute to the standard of handling facilities of reasonable chemical management laws that can be applied to the industry in reality.

Study on the Management Plan for the Preparation of Chemical Terrorism in Multi-use Facilities (다중이용시설 화학테러에 대비한 관리방안 연구)

  • Yoon, Seong Yong;Kim, Si-Kuk;Hong, Sungchul
    • Fire Science and Engineering
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    • v.33 no.2
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    • pp.68-78
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    • 2019
  • In modern society, the paradigm of terrorism is shifting to the form of soft targets focusing on an unspecified number of people, which is different from previous terrorist tendencies, and frequent attacks using chemicals. Therefore, this study analyzed the evacuation environment and characteristics, manual analysis of a terror response manual, and the domestic chemical management status of multi-use facilities, and proposed the following management measures for chemical terror prevention in multi-use facilities. First, a multi-use facility guideline for prompt onsite response is proposed. Second, an improvement plan is suggested through the analysis of the manual for counter terrorism. Third, integrated management is proposed through the selection of chemicals available for terrorism. Through this, it is expected that an additional improvement plan will be prepared for countermeasures against chemical terrorism in multi-use facilities. In the future, it will be necessary to analyze the problems through cases of foreign countries and take customized countermeasures.

Characteristics of Groundwater Pollution and Contaminant Attenuation at Waste Disposal Sites (폐기물 매립지 주변의 지하수 오염과 오염물질의 지연 특성)

  • 오석영;전효택
    • Journal of the Korean Society of Groundwater Environment
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    • v.3 no.1
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    • pp.37-49
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    • 1996
  • The objectives of this study are to investigate the groundwater and surface water contamination, to interpret the attenuation mechanism of contaminant transport, and to find the appropriate contamination indicator. at the two big landfill sites : Nanjido Landfill and Hwasung Landfill. Leachate from the Nanjido, th, Hwasung and the Kimpo waste disposal sites is characterized by high temperature (31.7-40.1$^{\circ}C$), high electric conductivity (14,650-32,800 ${\mu}$S/cm), somewhat higher pH(7.58-8.45) and low Eh (-119.4-20.4 mV), and is enriched in both major (Na$^{+}$, K$^{+}$, Ca$^{2+}$, Mg$^{2+}$, HC $O_3$$^{-}$, Cl$^{-}$) and minor (Mn, Sr$^{2+}$, Ba$^{2+}$, Li$^{+}$, F$^{-}$, Br$^{-}$) ions. Municipal solid waste leachate and industrial waste leachate are effectively discriminated by the content of S $O_4$$^{2-}$, Fe, and heavy metals. The attenuation mechanism of each component was assessed using the chemical analysis. Cl-normalizing process, WATEQ4F simulation, and preceding flownet analysis. Based on the calculation of Contamination Factor, K, Na, Ca, Mg, B, Zn, HC $O_3$, Cl, F, Br and TOC are effective contamination indicators in the Nanjido landfill site, and K, Na, Ca, Mg, B, S $O_4$, HC $O_3$, Cl, F, Br and TOC in the Habsburg landfill site Particularly, TOC is the best contamination indicator in landfill sites influenced by sea water.

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Distribution of the Sulfur Compounds and Volatile Organic Compounds in Yosu Industrial Area (여수산단주변지역의 황화합물 및 VOCs 농도분포)

  • 서성규;전준민;문정선;윤형선;정경훈
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.11a
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    • pp.310-311
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    • 2002
  • 악취는 인간이 직접 후각으로 느끼는 환경오염의 지표로서 극히 낮은 농도에서도 피해를 유발하여 대기질 전반에 대한 불신을 초래하게 된다. 악취의 주요 발생원으로는 정유공장, 화학공장, 하수처리장, 분뇨 및 축산폐수처리장, 쓰레기 매립지 등으로 발생원이 매우 다양하고 여러 가지 복합된 화합물이 원인이 되어 악취를 유발시키는 것이 특징이다. 우리나라의 주거여건은 주변환경을 충분히 고려하지 못한 개발로 공업지역과 주거지역이 근접 또는 혼재하여 악취오염에 근본적으로 취약한 구조의 도시가 형성된 곳도 있다. (중략)

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Measurements of HCHO during ozone intensive study in Seoul, 2001 (2001년 서울시 오존 집중 측정 시기 HCHO의 측정)

  • 홍상범;김규수;이재훈
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.04a
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    • pp.319-320
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    • 2002
  • 포름알데하이드(HCHO)는 보건학적인 영향과 광화학 스모그 형성과정의 중요한 역할로 인해 많은 연구의 대상이 되어왔다. 포름알데하이드(HCHO)의 도심지 대기 환경에서 가장 중요한 인위적인 발생원은 산업활동 및 자동차의 배기가스이며 식물의 연소과정(biomass burning)에서도 방출되는 것으로 알려져 있다. 또한 대기환경에 존재하는 휘발성 유기화합물들과 OHㆍ과의 광 화학적 산화과정을 통하여 2차적으로 형성된다. 한편, 주요 소멸과정으로는 광분해(photolysis) 과정과 OHㆍ과의 반응이다. (중략)

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마이크로톡스 생물검정법 개량화 연구

  • 이규태;고철환;조병철
    • Proceedings of the Korean Society of Fisheries Technology Conference
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    • 2003.05a
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    • pp.146-147
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    • 2003
  • 우리나라에서의 환경 오염 관리는 BOD, COD를 비롯한 총 20여가지 항목에 대한 이화학적 분석에 기초를 두고 있기때문에 분석 항목에 포함되지 않는 물질에 의한 독성의 영향은 간과되고 있다. 선진국에서는 이러한 한계점을 극복하기 위해 이화학적 분석기법 이외에 생물검정법을 이용하여 유해화학물질에 대한 독성 판별, 수질환경기준, 퇴적물환경기준, 오염진단과 생태계위해도 평가, 오염정화와 환경복원 등에 활용하고 있다. (중략)

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Geochemical Modeling on Water-caprock-gas Interactions within a CO2 Injected in the Yeongil Group, Pohang Basin, Korea (포항분지 영일층군 내 이산화탄소 주입에 의한 물-덮개암-가스 반응에 대한 지화학적 모델링)

  • Kim, Seon-ok;Wang, Sookyun;Lee, Minhee
    • Economic and Environmental Geology
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    • v.54 no.1
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    • pp.69-76
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    • 2021
  • This study is to identify the mineralogical properties of caprock samples from drilling cores of the Pohang basin, which is the research area for the demonstration-scale CO2 storage project in Korea. The interaction of water-rock-gas that can occur due to CO2 injection was identified using geochemical modeling. Results of mineralogical studies, together with petrographic data of caprock and data on the physicochemical parameters of pore water were used for geochemical modeling. Modelling was carried out using the The Geochemist's Workbench 14.0.1 geochemical simulator. Two steps of modeling enabled prediction of immediate changes in the caprocks impacted by the first stage of CO2 injection and the assessment of long-term effects of sequestration. Results of minerlaogical analysis showed that the caprock samples are mainly composed of quartz, K-feldspar, plagioclase and a small amount of pyrite, calcite, kaolinite and montmollonite. After the injection of carbon dioxide, the porosity of the caprock increased due to the dissolution of calcite, and dawsonite and chalcedony were precipitated as a result of the dissolution of albite and k-feldspar. In the second step after the injection was completed, the precipitation of dawsonite and chalcedony occurred as a result of dissolution of calcite and albite, and the pH was increased due to this reaction. Results of these studies are expected to be used as data to quantitatively evaluate the efficiency of mineral trapping capture in long-term storage of carbon dioxide.

Prediction of the Gold-silver Deposits from Geochemical Maps - Applications to the Bayesian Geostatistics and Decision Tree Techniques (지화학자료를 이용한 금${\cdot}$은 광산의 배태 예상지역 추정-베이시안 지구통계학과 의사나무 결정기법의 활용)

  • Hwang, Sang-Gi;Lee, Pyeong-Koo
    • Economic and Environmental Geology
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    • v.38 no.6 s.175
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    • pp.663-673
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    • 2005
  • This study investigates the relationship between the geochemical maps and the gold-silver deposit locations. Geochemical maps of 21 elements, which are published by KIGAM, locations of gold-silver deposits, and 1:1,000,000 scale geological map of Korea are utilized far this investigation. Pixel size of the basic geochemical maps is 250m and these data are resampled in 1km spacing for the statistical analyses. Relationship between the mine location and the geochemical data are investigated using bayesian statistics and decision tree algorithms. For the bayesian statistics, each geochemical maps are reclassified by percentile divisions which divides the data by 5, 25, 50, 75, 95, and $100\%$ data groups. Number of mine locations in these divisions are counted and the probabilities are calculated. Posterior probabilities of each pixel are calculated using the probability of 21 geochemical maps and the geological map. A prediction map of the mining locations is made by plotting the posterior probability. The input parameters for the decision tree construction are 21 geochemical elements and lithology, and the output parameters are 5 types of mines (Ag/Au, Cu, Fe, Pb/Zn, W) and absence of the mine. The locations for the absence of the mine are selected by resampling the overall area by 1 km spacing and eliminating my resampled points, which is in 750m distance from mine locations. A prediction map of each mine area is produced by applying the decision tree to every pixels. The prediction by Bayesian method is slightly better than the decision tree. However both prediction maps show reasonable match with the input mine locations. We interpret that such match indicate the rules produced by both methods are reasonable and therefore the geochemical data has strong relations with the mine locations. This implies that the geochemical rules could be used as background values oi mine locations, therefore could be used for evaluation of mine contamination. Bayesian statistics indicated that the probability of Au/Ag deposit increases as CaO, Cu, MgO, MnO, Pb and Li increases, and Zr decreases.

A Study on Total Hazard Level Algorithm Development for Hazardous Chemical Substances (유해화학물질의 종합위해등급 알고리즘 개발에 관한 연구)

  • 고재선;김광일;정상태
    • Fire Science and Engineering
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    • v.14 no.4
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    • pp.7-16
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    • 2000
  • In the study, three criteria(toxicity, fire & explosion, environment) and damage prediction method for each case was set up, and all these criteria were applied to the subject substance that was selected as hazardous level by integrating all criteria through Algorithm. Particularly, the environment criterion is a comprehensive concept, environment index modeling by combining USCG(United State Coast Guard) & MSDS(Material Safety Data Sheet) environment criteria classifications and the environment part of MFPA's health hazardousnes(Nh). And for damage prediction method of each criterion were adopted and they were applied to hazardous chemical substances in use or stored by chemical substance related enterprises located in each region that made possible to set up total hazard level of used substances(inflammability, poisonousness and counteraction on a unit substance, and hazard level & display modeling on environment) & damage prediction in case of accident & solidity setup(CPQRA: Chemical Process Quantitative Risk Assessment, IAEA: International Atomic Energy Agency, VZ eq: Vulnerable Zone) risk counter. Thus it is deemed that it can be applied to toxic substance leakage that can happen during any chemical processing & storage, application as a tool for prior safety evaluation through potential dangerousness computation of fire & explosion.

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