• Clean Technology
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• v.15 no.4
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• pp.253-257
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• 2009

The waste solution discharged form the LCD(Liquid Crystal Display) manufacturing process contains phosphoric acid, nitric acid, acetic acid and metal ions such Al and other impurities. In this study, vacuum evaporation and diffusion dialysis was developed to commercialize an efficient system for recovering the high-purity phosphoric acid and manufacturing monoammonium phosphate. By vacuum evaporation, almost 99% of nitric and acetic acid was removed. Also, by diffusion dialysis, about 97.5% of Al was removed. Monoammonium phosphate was manufactured from purified phosphoric acid and ammonium hydroxide. In order to get the optimum manufacturing condition, the molar ratio of ammonium hydroxide and phosphoric acid, pH and temperature was controlled. Using this optimum condition, we obtained the recovery rate of monoammonium phosphate of about 90%.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.29 no.3 s.234
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• pp.390-401
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• 2005

In this study, extinction limit extension of unsteady $(CH_{4}+N_{2})$/air diffusion flames was investigated experimentally. A spatially locked flame in an opposing jet burner was perturbed by linear velocity variation, and time-dependent flame luminosity, transient maximum flame temperature and OH radical were measured over time with the high speed camera, Rayleigh scattering method and OH laser-induced fluorescence, respectively. Unsteady flames survive at strain rates that are much higher than the extinction limit of steady flames, and unsteady extinction limits extend as the slope of the strain rate increases or the initial strain rate decreases. We verified the validity of the equivalent strain rate concept by comparing the course of unsteady extinction process and steady extinction process, and it was found that the equivalent strain rate concept represents well the unsteady effect of a convective-diffusive zone. To investigate the reason of the unsteady extinction limit extension, we subtracted the time lag of the convective-diffusive zone by using the equivalent strain concept. Then the modified unsteady extinction limits become smaller than the original unsteady extinction limits, however, the modified unsteady extinction limits are still larger than the steady extinction limits. These results suggest that there exist the unsteady behavior of a diffusive-reactive zone near the extinction limit due to the chemical non-equilibrium states associated with unsteady flames.

• Applied Chemistry for Engineering
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• v.33 no.1
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• pp.96-102
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• 2022

Reactants of PEMFC are hydrogen and oxygen in gas phases and fuel cell overpotential could be reduced when reactants are smoothly transported. Numerous studies to modify cathode flow field design have been conducted because oxygen mass transfer in high current density region is dominant voltage loss factor. Among those cathode flow field designs, a block in flow field is used to forced supply reactant gas to porous gas diffusion layer. In this study, the block was installed on a simple fuel cell model. Using computational fluid dynamics (CFD), effects of forced convection due to blocks on a polarization curve and local current density contour were studied when different air flow rates were supplied. The high current density could be achieved even with low air supply rate due to forced convection to a gas diffusion layer and also with multiple blocks in series compared to a single block due to an increase of forced convection effect.

• Nuclear Engineering and Technology
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• v.13 no.4
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• pp.264-276
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• 1981

A simulation procedure which can represent time-dependent nuclear characteristics of TRIGA Mark-III reactor is developed. CITATION, a multi-group diffusion-depletion program, has been utilized as calculational tool. The group structure employed in this study consists of 7 groups: -3-fast and 4-thermal-which is conventionally utilized in TRIGA type reactor analysis. Three-dimensional nuclear characteristics are synthesized by combining results from two-dimensional plane calculation and two-dimensional cylinder calculation, since direct three-dimensional approach is not yet possible. An effort ia made to develope a method which can extract effective zone and group dependent bucklings by neutron diffusion theory rather than conventional zone and/or group independent Ducklings by neutron transport theory, since neutron leakage is quite high for small core such as research reactors. It is turned out that the method developed in this study gives satisfactory results. The calculation is performed under assumptions that all control rods are fully withdrawn, that no samples are inserted in the irradiation holes and that the core is located in the center of the reactor pool. Burnup-dependent variation of core excess reactivity, time dependent change of Xe-135 poisoning and reactivity worth of rotary specimen rack are calculated and compared with operation records. Neutron flux and power distribution as well as neutron spectrum in each irradiation .facility are presented.

• Journal of the Korean Electrochemical Society
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• v.7 no.1
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• pp.21-25
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• 2004

The electrochemical behaviors of dissolved hydrogen and hydrogen peroxide at a platinum disk electrode were investigated in boric acid solution by potentiostatic polarization method at the temperature of 25 and $200^{\circ}C$. The oxidation of dissolved hydrogen at $25^{\circ}C$ was kinetically controlled reaction, the rate of which depends upon the electron transfer on the electrode surface. As temperature was raised, however, the electrochemical characteristics of dissolved hydrogen were changed from a kinetically controlled reaction to a diffusion controlled one. One notable feature, with dissolved hydrogen at high temperature, is that an abnormal potential range was observed, where the oxidation rate of dissolved hydrogen rapidly decreased just before starting potential of water oxidation. We think it is caused by the deactivation of the electrode that results from the adsorption of hydroxyl ion on the surface of the platinum disk. On the contrary, a definite change with temperature was not identified in the case of the hydrogen peroxide except for the increase in current density that was due to the increasing diffusion coefcient with an increase of temperature.

• Elastomers and Composites
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• v.37 no.1
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• pp.31-38
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• 2002

Polymerization of carboxylated styrene-butadiene latex takes longer time than that of acrylic emulsion due to delocalization of radical in butadiene unit having conjugated double bond. A latex stability is the most important properties owing to use intact without separating polymer from base latex. For reducing polymerization time without decreasing any properties of latex, carbon tetra-chloride which has been used as the most popular chain transfer agent was replaced to combination of tert-dodecylmercaptane and ${\alpha}$-methylstyrene dimer. The replacement yielded reducement or 2 hr in polymerization time. In the increment step, charge amount of acrylic acid was limited to 0.3 part to restrain viscosity enhancement. Just after initial step, addition of 0.1 part acrylamide prevent polymer chain from diffusing between two region followed by giving hardness and final good adhesive force to latex particles.

• Journal of Sensor Science and Technology
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• v.4 no.4
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• pp.70-74
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• 1995

We have observed anisotropic anodisation process for porous silicon formation. The starting material was (100) silicon $n/n^{+}/n$ wafer structured by $n^{+}$-diffusion on n-type substrate and by subsequent n-epitaxial growth. After the top n-silicon epitaxial layer was etched to open the porous silicon layer(PSL) anodisation window, anodisation takes place only to $n^{+}$-buried layer. The process of porous silicon formation on (100) sample was anisotropic, which was evident from that the shapes of the reacted porous silicon layer was all squarelike regardless of the shapes of reaction windows. The experimental results show that the PSL anodisation process does not depend on chemical reaction but does on electrical conduction property, which is hole mobility depending on the crystal direction.

• Applied Chemistry for Engineering
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• v.27 no.3
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• pp.335-341
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• 2016

In this study, impurity effects on diffusive-convection flow fields by physical vapor transport under terrestrial and microgravity conditions were numerically analyzed for the mixture of $Hg_2Cl_2-I_2$ system. The numerical analysis provides the essence of diffusive-convection flow as well as heat and mass transfer in the vapor phase during the physical vapor transport through velocity vector flow fields, streamlines, temperature, and concentration profiles. The total molar fluxes at the crystal regions were found to be much more sensitive to both the gravitational acceleration and the partial pressure of component $I_2$ as an impurity. Our results showed that the solutal effect tended to stabilize the diffusive-convection flow with increasing the partial pressure of component $I_2$. Under microgravity conditions below $10^{-3}g_0$, the flow fields showed a one-dimensional parabolic flow structure indicating a diffusion-dominant mode. In other words, at the gravitational levels less than $10^{-3}g_0$, the effects of convection would be negligible.

• Transactions of the Korean Society of Mechanical Engineers
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• v.19 no.5
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• pp.1269-1279
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• 1995

An experimental study is carried out on turbulent diffusion flames stabilized by a circular cylinder in a divergent duct flow. A commercial grade gaseous propane is injected from two slits on the rod as fuel. Flame stability limits, as well as size and temperrature of recirculation zone, are measured by direct and schlieren photographs to clarify the characteristics and structure of diffusion flames and to assess the effect of various divergent angle of duct. The results of the present study are as follows. Temperature in the recirculation zone decreases with increasing divergent angle. The blow-off velocity in parallel duct is higher than that in divergent duct. Critical blow-off velocity is expected to be about 8-12 degree through blow-off velocity pattern. Regardless of divergent angles, the length of recirculation zone is nearly constant, and this length becomes longer with rod diameter. Pressure gradient has an effect on the eddy structure in shear layer behind the rod. With the increase of divergent angle, large scale eddies by dissipated energy in shear layer are split into small scale eddies, and the flame becomes a typical distributedreacting flame.

• Applied Chemistry for Engineering
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• v.8 no.3
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• pp.395-402
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• 1997

The $SiO_2$ films were prepared by ECR(electron cyclotron resonance) plasma diffusion method, Deal-Grove model and Wolters-Zegers-van Duynhoven model were used to estimate the oxidation rate which was correlated with surface morphology for different orientation of Si(100) and Si(111). It was seen the $SiO_2$ thickness increased linearly with initial oxidation time. But oxidation rate slightly decrease with oxidation time. It was also shown that the oxidation process was controlled by the diffusion of the reactive species through the oxide layer rather than by the reaction rate at the oxide interface. The similar time dependency has been observed for thermal and plasma oxidation of silicon. From D-G model and W-Z model, the oxidation rate of Si(111) was 1.13 times greater than Si(100) because Si(111) had higher diffusion and reaction rate, these models more closely fits the experimental data. The $SiO_2$ surface roughness was found to be uniform at experimental conditions without etching although oxidation rate was increased, and to be nonuniform due to etching at experimental condition with higher microwave power and closer substrate distance.