• Transactions of the Korean Society of Mechanical Engineers A
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• v.39 no.7
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• pp.653-657
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• 2015

A numerical investigation to simulate the selective growth of silicon-germanium quantum-dots via local surface diffusivity enhancement is presented. A nonlinear equation for the waviness evolution of film surface is derived to consider the effects of spatially-varying diffusivity, influenced by a surface temperature profile. Results show that the morphology of the initially planar film shapes into an undulated surface upon perturbation, and a steady-state solution describes a fully grown quantum-dot. The present study points toward a fabrication technique that can obtain selectivity for self-assembly.

• Proceedings of the Korean Nuclear Society Conference
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• 1998.05b
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• pp.677-682
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• 1998

영광원전주변 해양에서 조사된 환경방사능 조사결과를 토대로 Cs-137과 Sr-90 방사성물질의 해수와 부유물에서 분포특성과 해양생물로의 전이.농축특성을 분석하였다. 방사성물질의 분포특성 분석은 해양에서 방사성물질의 용해성과 부유물에의 흡착성 평가뿐 아니라 방사성물질의 해양확산을 평가하는데 필수적 요소이다. 지금까지는 방사성물질의 해양확산 평가시 완전 용해성으로 가정하여 단순한 해수유동 특성만을 고려하여 평가하였으나, 흡착성 등 물리화학적 거동특성을 평가함으로써 좀더 사실적인 해양확산을 평가할 수 있다. 평가결과 Cs-137과 Sr-90의 분포특성을 나타내는 분배계수가 각각 8.1$\pm$1.4E-4, 7.4$\pm$2.3E-5 로 나타났다. 이는 두 핵종 모두 용해성이 높고 흡착성이 낮음을 보여준다. 그리고 Cs-137과 Sr-90에 비해 상대적으로 흡착성이 높게 나타나고 있다. 또 전이.농축특성 분석결과는 김에서 Cs-137과 Sr-90의 전이.농축계수가 66과 3, 서대와 병어에서는 122.5와 6, 패류에서는 Sr-90의 전이.농축계수가 6으로 나타났다. Sr-90은 전반적으로 전이.농축계수가 낮게 나타나 생물체에유입되더라도 쉽게 배출돼 축적경향이 매우 낮음을 보여준다. 반면 Cs-137은 Sr-90에 비해 상대적으로 농축특성이 높게 나타나고 있다. 향후 이를 토대로 해역의 고유 환경특성에 맞는 방사성물질의 해양중 거동특성을 고려한 해양확산평가 및 해양감시가 이뤄져야할 것이다.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.545-548
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• 2008

As the corrosion of reinforcing bar in concrete structures exposed to chloride attack is one of main factors to determine the remaining service life, marine concrete structures have to be designed to protect the chloride penetration. Among the durability design methods such as deterministic method and probabilistic method, design method based on the probabilistic theory has been widely studied. However, the most essential material, data of the material properties related to chloride diffusion, are still insufficient. In this paper, the probabilistic distribution of chloride diffusion coefficients and aging coefficients are derived by the experiment and analysis for the chloride coefficients of concrete containing pozzolans, which are generally used in marine structures.

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.6
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• pp.83-90
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• 2017

Concrete structure for nuclear power plant is mass concrete structure with large wall depth and easily permits cracking in early age due to hydration heat and drying shrinkage. It always needs cooling water so that usually located near to sea shore. The crack on concrete surface permits rapid chloride intrusion and also causes more rapid corrosion in the steel. In the study, the effect of age and crack width on chloride diffusion is evaluated for the concrete for nuclear power plant with 6000 psi strength. For the work, various crack widths with 0.0~1.4 mm are induced and accelerated diffusion test is performed for concrete with 56 days, 180days, and 365 days. With increasing crack width over 1.0mm, diffusion coefficient is enlarged to 2.7~3.1 times and significant reduction of diffusion is evaluated due to age effect. Furthermore, apparent diffusion coefficient and surface chloride content are evaluated for the concrete with various crack width exposed to atmospheric zone with salt spraying at the age of 180 days. The results are also analyzed with those from accelerated diffusion test.

• Journal of the Korea institute for structural maintenance and inspection
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• v.27 no.4
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• pp.54-61
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• 2023

In this paper, the compressive strength, pore characteristics, and chloride diffusion coefficient were measured at 28 days of age in order to examine the influence of curing conditions for the chloride diffusion and pores in concrete cured under extreme condition. According to the test results, the compressive strength was improved as the relative humidity increased. Additionally, higher compressive strength was observed when the specimens were cured at 35℃. However, the compressive strength of specimens cured at 45℃ was decreased. Meanwhile, the chloride diffusion coefficient decreased with an increase in curing temperature and relative humidity, indicating a difference compared to the trend observed for compressive strength. On the other hand, the excellent correlation showed between compressive strength and chloride diffusion coefficient, porosity and chloride diffusion coefficient when the concrete cured under water. However, when the concrete cured under extreme condition, this correlation was significantly reduced compared to the water curing case. In contrast, it has been determined that there is no significant correlation between the average pore size and chloride diffusion coefficient, regardless of the curing conditions.

• Proceedings of the Korean Society of Coastal and Ocean Engineers Conference
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• 2000.09a
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• pp.161-165
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• 2000

연안해역으로 유입되는 물질의 이동 및 확산에 관한 예측연구는 수치모형개발과 확산(또는 분산)계수 관측에 중점을 두고 수행되어 왔다. 수치모형의 보정 및 검증을 위한 (오염)물질의 유입량 및 농도관측과 더불어 각종 부표(drogue), 형광물질 등을 이용한 분산계수 측정연구가 다방면으로 수행되어 왔다. (중략)

• Journal of the Korea institute for structural maintenance and inspection
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• v.14 no.3
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• pp.138-143
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• 2010

Recently, as many big marine concrete structures increase, it is necessary that chloride ion diffusion coefficient of concrete shall be evaluated but it will take a long time to evaluate chloride ion diffusion coefficient of concrete. Accordingly, many test methods are suggested to evaluate chloride ion diffusion coefficient in a short period time by the promotion in electro chemical ways but the systematic study for this is insufficient. Therefore, this study evaluates chloride ion penetration and diffusion features by three representative electric promotion tests targeting for three different cements whose ingredients are different and analyzes the correlationship between them. As a result, diffusion features of chloride ion varied according to the cement ingredients and three ingredients cement in which blast furnace slag powder and fly ash are mixed in constant ratio, which shows the most excellent cement diffusion properties. For diffusion properties of chloride ion, the correlationship between test methods are good.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.28 no.1
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• pp.79-83
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• 2015

This paper presents a numerical study on the alignment of ridge-like surface structures evolving on silicon-germanium thin films under localized modulation of surface diffusivity. A situation is considered in which the surface diffusion of film material is selectively promoted such that its morphology is perturbed to periodic patterns. To simulate the growth behavior, a governing equation is formulated taking the surface chemical potential into account, and its solution is numerically sought using a finite-difference method. Results show that an initially planar surface coalesces upon the diffusivity modulation, and the surface structures can be aligned by changing the frequency of modulation condition. This research suggests a bottom-up fabrication technique that can manage the regularity of surface structures for thin film devices.

• Analytical Science and Technology
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• v.9 no.3
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• pp.292-301
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• 1996

The synthesis of poly(ether)tailed bipyridine complex as redox reaction probes has advanced attempts to interpret very slow diffusion and heterogeneous electron transfer. Diffusion coefficients as low as $1.5{\times}10^{-15}cm^2/s$ have been observed for the oxidation of neat $Co(bpy(ppgm)_2)_{3^-}(ClO_4)_2$ with $LiClO_4$ electrolyte. Heterogeneous electron transfer rate constants of materials were found to vary with diffusion coefficient. The decrease in k as the diffusion coefficient decreases was actually caused by the decreasing D. Diffusion coefficient for compound of strong ion pairing anion($ClO{_4}^-$) was much smaller than the diffusion coefficient for compound of weak ion pairing anion($CF_3COO^-$).

• Journal of the Korea Institute of Building Construction
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• v.9 no.6
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• pp.71-78
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• 2009

The analysis of the effect of loading on chloride penetration into concrete is very important. In this study, we confirmed that the chloride penetration rates for plain and BFS concrete were increased by 47% and 89% under compressive stress, respectively. The diffusion coefficient of BFS concrete was lower than for conventional concrete with no BFS, no loads, and under stressed states. Therefore, BFS substitution plays an important role in the repression of chloride penetration even under compressive stress. Under compressive stress,the diffusion coefficient for BFS concrete was higher with increasing stress, and this was also the case for plain concrete. However, BFS concrete was strongly influenced by compressive stress in comparison to plain concrete. We investigated the effect of the difference of specific surfaces on the diffusion coefficient. As a result, the larger specific surface of BFS exhibited a lower diffusion coefficient. This tendency was most pronounced under the high stress conditions.