• Journal of Advanced Marine Engineering and Technology
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• v.38 no.9
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• pp.1087-1093
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• 2014

Stainless steels stabilized with Ti or Nb are largely used in offshore and shipbuilding industries due to its excellent corrosion resistance. In this study, carbide stabilizers, Ti and Nb, were added to stainless steel 304 specimens with different concentrations(Ti: 0.26%, 0.71%, Nb: 0.29%, 0.46%, 0.71%), and their mechanical and electrochemical characteristics were evaluated. Micro-Vickers hardness testing was employed to characterize the mechanical characteristics with alloying elements. Electrochemical evaluation techniques including Tafel analysis, cyclic polarization experiment, galvanostatic experiment were utilized to compare the corrosion characteristics of the specimens. The result of hardness tests revealed that Nb containing specimens showed increasing hardness with increasing alloying contents while adding Ti had little effect on increase in hardness. In the case of electrochemical measurements, the electrochemical characteristics of the specimens were enhanced with increasing Nb contents while they were deteriorated with increasing Ti contents. As a result, different stabilizers and their contents may produce significant differences in electrochemical characteristics, and there such effect must be taken account of in development of stainless steels for marine environment.

• Polymer(Korea)
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• v.29 no.2
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• pp.211-215
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• 2005

Stabilization process is absolutely necessary to convert the precursor fibers into chemically, physically, thermally and structurally stable carbon fibers. Especially, it is critically important for rayon fibers experiencing severe weight loss and thermal shrinkage occurring at the stabilization stage below $400^{\circ}C$. The stabilization of rayon fibers strongly depends not only on stabilization temperature but also on heating rate, chemical pre-treatment, atmosphere, and so on. In the present study, the weight loss, fiber diameter change occurred in the furnace during the stabilization process for rayon fibers produced with various heating rates and in the absence and presence of phosphorous-based flame retardants and the thermal stability of the stabilized fibers were investigated. The result indicates that the weight, diameter and thermal stability of the rayon fibers are significantly affected by the type and amount of the flame retardant used. It is also suggested that the pre-treatment of rayon fibers with a concentration lower than $3\;vol\%$ of phosphoric acid is most desirable for further carbonization process of stabilized rayon fibers.

• Journal of Adhesion and Interface
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• v.11 no.1
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• pp.15-25
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• 2010

In the present study, isothermal stabilization processes for rayon fabrics were performed at two relatively low temperatures $180^{\circ}C$ and $200^{\circ}C$ for a long period of time. The results of weight loss, dimensional shrinkage, X-ray diffraction and scanning electron microscopic observations studied with the rayon fabrics before and after the isothermal stabilization indicated that the chemical and physical changes of rayon precursor fibers proceeded continuously and slowly at the stabilization temperature below $200^{\circ}C$. And the pre-treatment with four different chemical compounds done prior to stabilization process influenced differently the characteristics of rayon fabrics. As a result, it was noticed that under the given stabilization conditions, $H_3PO_4$ and $Na_3PO_4$ played a role in catalyzing the stabilization reaction of rayon fabric whereas $NH_4Cl$ and $ZnCl_2$ played a role in delaying or retarding the reaction. $H_3PO_4$ showed the lowest percent weight loss of the fabric in the second stabilization conducted at $350^{\circ}C$. It was considered that phosphoric acid, which has a function of flame retardant, contributed to retarding somewhat the subsequent reaction even in the second stabilization step.

• Journal of Adhesion and Interface
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• v.14 no.3
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• pp.146-159
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• 2013

In the present study, stabilized rayon fabrics were prepared from fast isothermal stabilization processes, which were carried out within four minutes at $350^{\circ}C$. The effects of ultrasonic cleaning and chemical pre-treatment on the chemical composition, physical characteristics, X-ray diffraction pattern, thermal stability and shape of the stabilized rayon fabrics were investigated extensively. In order to reduce the weight loss and thermal shrinkage of rayon fabrics occurring during the stabilization process, ultrasonic cleaning was first conducted and then chemical pre-treatments using $NH_4Cl$, $Na_3PO_4$, $H_3PO_4$, and $ZnCl_2$ were performed, respectively. The results indicated that both ultrasonic cleaning and chemical pre-treatment influenced the weight loss, thermal shrinkage, microstructure, carbon content, thermal stability and fabric shape of stabilized rayon fabrics. Also the results depended on the fast-stabilization time and the type of chemical pre-treatment agents used.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.7
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• pp.890-899
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• 2014

Austenitic stainless steel is widely used in various industries due to its excellent corrosion resistance. However, Cr carbides precipitation along the grain boundaries after heat treatment or welding may develop Cr depleted zone, which acts as a preferential site for intergranular corrosion attack. To resolve this, carbon stabilizing element such as Ti or Nb are added to suppress formation of Cr carbides. However, there are few reports on corrosion characteristics under seawater environment of the stabilized stainless steel. This study investigated the effects of alloying contents on the electrochemical characteristics in seawater of stainless steel containing stabilizing element(Ti and Nb). To achieve this, the changes on the microstructure due to alloying were observed with microscope, and the electrochemical characteristics were determined by measurement of natural potential and potentiodynamic polarization experiments. The microscopic observation revealed that all specimens had inclusions other than the austenite matrix phase due to the addition of alloying elements. Such inclusions are considered to have different electrochemical characteristics from those of the matrix, and thus a clear distinction was found according to the type of stabilizers and the contents. The results of this study suggest that it is important to consider the effects of alloying contents on the electrochemical characteristics in seawater with the addition of Ti or Nb into austenitic stainless steel.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2015.11a
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• pp.203-203
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• 2015

반도체 제조 공정 중에 CMP(Chemical Mechanical Planarization)는 디바이스의 집적도(degree of integration)에 크게 영향을 미치고 있으므로, 20nm급 이하의 디바이스에서 CMP 공정 안정화는 양질의 소자 특성을 확보하기 위해서는 시급한 문제가 되고 있다. CMP 공정 안정화를 위해서는 여러 가지 해결되어야 할 문제가 있는데, 그 중에서도 W plug 연마 공정 중에 관찰되고 있는 W missing은 전기 배선의 신뢰성에 직접 영향을 주고 있으므로 공정 엔지니어에게는 도전적인 과제이다. 본 연구에서는 W missing 현상을 전기화학적인 입장에서 해석하고 몇 가지 해결책을 제기하고자 한다.

• Journal of the Korean Ceramic Society
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• v.38 no.6
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• pp.593-595
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• 2001

Zinc-phosphate glasses에 B$_2$O$_3$를 도입하여 borate, phosphate, boro-phosphate networks가 혼재되어 있는 highly cross-linked structures를 형성시켜 Phosphate glasses의 화학적 안정화를 검토하였다. Raman 측정 결과 B$_2$O$_3$와 P$_2$O$_{5}$는 잘 혼화된 polynary networks를 이루고 있으며, 이렇게 하여 증진된 구조적 cross-linking에 의하여 xB$_2$O$_3$.(1-x)Zn$_2$P$_2$O$_{7}$ glasses의 T$_{g}$, T$_{d}$는 증가하였고 동시에 CTE는 감소하는 결과를 가져왔다.

• Journal of the Korean Chemical Society
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• v.19 no.3
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• pp.179-185
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• 1975

A new mechanism is proposed for aromatic substitution, involving the formation of pseudo molecular complexes at the transition state. It accounts for the addition reactions of aromatic compounds with double bond reagents such as ozone, somium tetraoxide and carbene as well as all of the features of electrophilic substitution reactions. The pseudo molecular complex has been proved to be formed by quantum-chemical considerations using the simple Huckel method.

• 한국연소학회:학술대회논문집
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• 1997.06a
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• pp.51-60
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• 1997

축대칭 곡면벽 제트 버너를 제작하여 화염의 안정화 특성을 실험적으로 연구하였다. 축대칭 곡면벽 제트 유동은 난류 강도의 증가와 더불어 버너 선단 부근에 재순환 영역을 형성하여 화염의 안정화를 촉진시킴으로서 기존의 튜브 버너에 비하여 화염의 안정화 특성이 향상되었다. 시간적으로 화염의 위치가 변동하는 난류 화염에서 화염의 안정화 특성과 밀접한 관계가 있는 OH 라디칼과 온도를 PLIF와 CARS를 각각 적용하여 측정하였다. 고유속으로 연소시키는 경우에 버너 선단에 형성된 재순환 영역에 OH 라디칼이 상당량 분포하고 있었으며 통계적으로 고온을 유지하였다. 이는 버너 선단에 형성되는 재순환 영역에 고온의 기연 가스가 점화원 역할을 하여 화학 반응이 활발하게 일어나고 있음을 의미한다. 이러한 결과로부터 고속의 출구유속에서 화염 안정화 특성은 재순환 영역에 의하여 영향을 받고 있음을 확인하였다.

• Journal of the Korean Ceramic Society
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• v.40 no.5
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• pp.468-474
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• 2003

Activated carbon fibers were prepared from stabilized PAN fibers by physical and chemical activation to compare their characteristics. In this study, stabilized PAN fibers were activated by physical activation with steam and CO$_2$, and by chemical activation with KOH. The fabricated activated carbon fibers were evaluated and compared such as specific surface area, pore size distribution, pore volume, and amount of iodine adsorption. In the steam activation, a specific surface area of 1635 m$^2$/g was obtained after heat treatment at 990$^{\circ}C$. Otherwise, in the CO$_2$ activation, produced activated carbon fibers had been a specific surface area of 671 m$^2$/g after heat treatment at 990$^{\circ}C$. In chemical activation using KOH, a specific surface area of 3179 m$^2$/g was obtained with a KOH/ stabilized PAN fiber ratio of 1.5 : 1 at 900$^{\circ}C$. Nitrogen adsorption isotherms for fabricated activated carbon fibers showed type I and transformation from type I and II in the Brunauer-Deming-Deming-Teller (B.D.D.T) classification. Increasing specific surface area Increased the amount of iodine adsorption in both activation methods. Because the ionic radius of iodine was smaller than the interior micropore size of activated carbon fibers.