• Journal of Adhesion and Interface
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• v.8 no.1
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• pp.8-14
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• 2007

Poly(urethane-methyl methacrylate) hybrid emulsions can be controlled with their thermal, mechanical and anti-chemical properties as plastic coating materials. In this study, water dispersed poly(urethane-methyl methacrylate) hybrid emulsions were prepared by prepolymer synthesis and soap free emulsion polymerization. For imparting hydrophilicity on polyurethane prepolymer, 2,2-bis (hydroxymethyl) propionic acid was added to the polyurethane prepolymer with methyl methacrylate monomer and was neutralizated by triethylamine (TEA). After neutralization, the prepolymer mixture was dispersed in the water phase with stable droplets. The synthesis was carried out with chain extension from the ethylene diamine and initiation of methyl methacrylate by soap free emulsion polymerization. Stable poly(urethane-methyl methacrylate) hybrid emulsion was successfully obtained with different synthetic conditions and acrylic monomer contents. Poly(urethane-methyl methacrylate) hybrid emulsion were characterized and compared with tensile strength, viscosity, and adhesion properties.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.25 no.3
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• pp.93-97
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• 2015

To synthesis of high purity micro silver particle, we extracted the silver from the waste by liquid-liquid extraction and used the rapid firing-liquid phase precursor (RF-LPP) method. The silver micro particle was synthesized at $500^{\circ}C$ for 3 hr in air atmosphere by RF-LPP method. As a result of the research, micro silver particle is measured X-ray diffraction (XRD), the main peak is nearly corresponded to the same as JCPDS card (No.87-0719). With using the RF-LPP method, the fine Ag micro particle indicated due to the control of nucleation site and the oxygen contents was decreased by reducing treatment. We expect this research contribute to advance in field of the recycling technology.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.28 no.12
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• pp.941-947
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• 2017

This paper reports a fractional-N phase-locked-loop(PLL) frequency synthesizer that is implemented in a $0.35-{\mu}m$ standard CMOS process and generates a quadrature signal for an FRS terminal. The synthesizer consists of a voltage-controlled oscillator(VCO), a charge pump(CP), loop filter(LF), a phase frequency detector(PFD), and a frequency divider. The VCO has been designed with an LC resonant circuit to provide better phase noise and power characteristics, and the CP is designed to be able to adjust the pumping current according to the PFD output. The frequency divider has been designed by a 16-divider pre-scaler and fractional-N divider based on the third delta-sigma modulator($3^{rd}$ DSM). The LF is a third-order RC filter. The measured results show that the proposed device has a dynamic frequency range of 460~510 MHz and -3.86 dBm radio-frequency output power. The phase noise of the output signal is -94.8 dBc/Hz, and the lock-in time is $300{\mu}s$.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.20 no.11
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• pp.1178-1185
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• 2009

In this paper, a wideband ultra-high speed & high purity discrete frequency synthesizer having minimum 2.5 MHz step size was proposed. To achieve fast and wideband operation, discrete frequencies were synthesized by mixing of 3 different pre-synthesized 16 frequencies made from fixed PLL and frequency dividers. Frequencies with discrete 2.5 MHz step were produced in 710~1,610 MHz. The measured hopping response time was 350 nsec average, output level was 21.5 dBm average with 2.65 dB flatness, spurious and harmonics level were suppressed below -60 dBc, and phase noise was -94 dBc/Hz@100 Hz. Also, a new measurement method for synthesizer response time was described.

• Journal of Korea Multimedia Society
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• v.16 no.5
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• pp.637-646
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• 2013

In order to model a variety of natural trees that are appropriate to outdoor terrains consisting of multiple trees, this study proposes a modeling method of new growth rules(based on the convolution sums of divisor functions). Basically, this method uses an existing growth-volume based algorithm for efficient management of the branches and leaves that constitute a tree, as well as natural propagation of branches. The main features of this paper is to introduce the theory of convolution sums of divisor functions that is naturally expressed the growth or fate of branches and leaves at each growth step. Based on this, a method of modeling various tree is proposed to minimize user control through a number of divisor functions having generalized generation functions and modification of the growth rule. This modeling method is characterized by its consideration of both branches and leaves as well as its advantage of having a greater effect on the construction of an outdoor terrain composed of multiple trees. Natural and varied tree model creation through the proposed method was conducted, and using this, the possibility of constructing a wide nature terrain and the efficiency of the process for configuring multiple trees were evaluated experimentally.

• Journal of Advanced Navigation Technology
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• v.14 no.5
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• pp.710-717
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• 2010

Even though there are 256 possible 1-qudit(1-variable quantum digit) functions in quaternary logic, the most useful functions are 4!=24 ones capable of representing in QGFSOP expressions by possible permuting of 0,1,2, and 3. In this paper, we propose a permutational literal(PL) representation and a QPL(Quaternary PL) gate which use the operands of a multiplicand A and an augend D in $Ax^C$+D(GF4) operation as a control variable of multi-cascaded PLs. And we also present new PL synthesis algorithms to synthesize QGFSOP expressed 24 (1-qudit) functions by applying three PL operators as ab(mutual permutation), + D(addition), and XA (multiplication). Finally architectures, circuits, and a CMOS implementation to realize proposed PL synthesis algorithms for $Ax^C$+D(GF4) functions are presented.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2017.05a
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• pp.88-88
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• 2017

Zn코팅은 우수한 내식성과 경제성을 바탕으로 자동차나 건축자재 등 산업의 전반적인 분야에서 광범위하게 사용되고 있다. 하지만 최근 한정된 Zn의 매장량으로 인한 원자제의 가격상승과 습식 도금과정의 환경오염 물질 배출 문제가 기존 Zn 코팅의 약점으로 지적되고 있다. 따라서 새로운 원소의 첨가로 인한 Zn의 사용량 감소나 친환경적인 공정방법을 적용하는 연구가 대두되고 있다. 최근의 연구 결과에 따르면 Zn-Mg 합금이 다른 Zn계 합금에 비해 내식성이 우수하며, 이와 같은 우수한 내식성은 $Mg_2Zn_{11}$, $MgZn_2$와 같은 Mg-Zn 이원계의 합금상에 의한 것으로 알려져 있다. 따라서 본 연구에서는 친환경적인 비대칭 마그네트론 스퍼터 공정을 활용하여 다양한 공정조건 하에서 Zn-Mg 박막을 합성하여 최적의 공정 조건을 도출하고자 하였다. Zn-Mg 박막 합성 시 Mg타겟의 조성은 3~10 wt.%로 변화하였으며 Zn-Mg 합금 타겟의 온도를 제어하여 박막의 Mg 조성과 타겟 온도가 Zn-Mg 도금강의 내식성 및 밀착성에 미치는 영향을 평가하였다. 합성된 Zn-Mg 박막은 FE-SEM, EDS, XRD를 사용하여 미세조직, 두께, Mg 조성, 합금상 등을 분석하였으며, 염수분무시험 및 0T 굽힘 시험을 활용하여 Zn-Mg 박막의 내식성 및 내식성을 비교 분석하였다. FE-SE및 EDS분석 결과 Zn-Mg 박막의 Mg 조성은 합금 타겟의 조성이 증가함에 따라 증가하였으며, Mg 함량이 증가할수록 미세구조가 치밀하게 변화하였다. 또한 Zn-Mg 박막 합성 중 타겟의 온도가 상승할수록 박막의 치밀도는 감소하였다. XRD분석 결과 박막을 이루는 주요 합금상은 Zn상과 $Mg_2Zn_{11}$상이며 본 연구에서는 증착 조건에 따른 합금상의 큰 변화는 보이지 않았다. 염수분무실험 및 밀착성 평가 결과 박막의 미세조직이 치밀할수록 Zn-Mg 도금강의 내식성은 향상되었으나, 밀착성은 오히려 감소하는 경향을 나타내었다. 이러한 결과는 Zn-Mg 박막이 치밀한 미세구조일수록 부식환경에서의 강판에 대한 보호 효과는 증가하는 반면, 변형 시 박막의 파괴로 인한 박리 현상이 가속되기 때문으로 판단된다.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.10 no.2
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• pp.277-290
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• 1999

A simulation using the finite-difference time-domain method to analyze the electromagnetic interactions between a cellular phone and the human body was conducted, and a synthesis of a bone-equivalent material to make a human head phantom was performed. A test model of the cellular phone was fabricated to measure its reflection coefficient and radiation pattern in the free space. Various effects of the human body on the characteristics of the phone, such as input impedance, reflection coefficient, radiation pattern, and radiation efficiency are analyzed as the distance between the head and the phone antenna varies. When the phone was operated close to the head, the resonant frequency of the antenna decreased by up to 12%. With the output power of 0.6W, as long as the distance was larger than 30mm, the 1-g averaged peak SAR was below the ANSI/IEEE safety guideline, 1.6 W/kg. To synthesize the bone-equivalent material, an epoxy with hardener and a graphite powder were used as basis ingredients, and a small amount of a conducting epoxy was added to control the conductivity of the material. A material having a relative permittivity of 18.04 and a conductivity of 0.347, which are close to those of the bone at 850 MHz, was synthesized.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.24 no.1
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• pp.1-7
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• 2014

Aluminum nitride, which has outstanding properties such as high thermal conductivity and electrical resistivity, has been received a great attention as a substrate and packaging material of semiconductor devices. Since aluminum nitride has a high sintering temperature of 2173 K and its properties depends on the impurity level, it is necessary to synthesize high-purity and nano-sized aluminum nitride powders for the applications. In this research, we synthesized high purity aluminum nitride nanopowders from aluminum using RF induction thermal plasma system. Sheath gas (NH3) flow was controlled to establish the synthesis condition of high purity aluminum nitride nanopowders. The obtained aluminum nitride nanopowders were evaluated by XRD, SEM, TEM, BET, FTIR and N-O analysis.

• Polymer(Korea)
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• v.27 no.1
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• pp.26-32
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• 2003

Poly(vinyl pivalate)(PVPi) telomer containing bifunctional end groups was synthesized through radical telomerization of vinyl pivalate. The number-average molecular weight ($\bar{M}$n) of the synthesized telomers was investigated by GPC, $^1$H-NMR, and viscometric methods. PVPi telomers having a number-average molecular weight ($\bar{M}$n) of 2400~1300 g/mol were obtained. In order to control the molecular weight of telomers, chain transfer constants ($C_s$) of telogen ($CCl_4$) were determined by using the Mayo equation and simulation, which were 1.15, 1.16, and 1.18 at 40, 50, and 6$0^{\circ}C$, respectively. $\bar{M}$n of the synthesized telomers at 6$0^{\circ}C$ were between 5100 and 5400 g/mol at conversion of increasing from 18 to 72%. Those are corresponding to simulation results.