• Title/Summary/Keyword: 합성 작용

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The effect of Zn2TiO4 on willemite crystalline glaze (Zn2TiO4가 아연결정유약에 미치는 효과)

  • Lee, Chi-Youn;Lee, Hyun-Soo;Shin, Kyung-Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.2
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    • pp.70-76
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    • 2014
  • $Zn_2TiO_4$, using an anatase form of $TiO_2$ on zinc crystalline glaze, was shown as effective nuclear agent. Thus the effects on glaze were studied with synthesized $Zn_2TiO_4$ at low temperature. First, the chromophore elements were employed in synthesized $Zn_2TiO_4$ then add them in the zinc crystalline glaze. Crystal creation and development of color by $Zn_2TiO_4$ addition on the zinc crystalline glaze were more effective. Addition of $Zn_2TiO_4$, which is developed in low range temperature, is effected as zinc crystalline nuclear in the willemite glaze. When 5 wt% of synthesized $Zn_2TiO_4$ was added to the willemite glaze, nuclear creation increases and steadily retains. Therefore addition of respectively doped $Zn_2TiO_4$ with CoO, NiO, and CuO would increase doped effects in the glaze, various color willemite crystal were obtained.

Bearing Strength of Concrete Column and Steel Beam Composite Joints (콘크리트 기둥과 철골 보 합성골조 접합부에서의 지압강도)

  • Kim, Byong-Kook;Lee, Won-Kyu;Choi, Oan-Chul
    • Journal of the Korea Concrete Institute
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    • v.15 no.3
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    • pp.417-424
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    • 2003
  • A bearing failure in RCS(Reinforced Concrete Column and Steel Beam) system is recognized as one of the distinct joint failure modes for the composite frames. Vertical and transverse reinforcement in addition to concrete are effective for better transfer of vortical forces through concrete bearing. To examine the effect of the vertical bars, tie bars, a U-type detail developed in this study and concrete confinement, local bearing tests were conducted using 22 small-scale concrete block specimens. Test results show that vertical reinforcement and tie bars mainly contribute to the bearing capacity. However larger amounts of tie reinforcement are required than those recommend from ASCE guidelines, to apply the nominal concrete strength as 2 $f_{ck}$ over the bearing area. Cross ties are proved to be highly effective for resisting the vertical forces. Maximum bearing strength can be increased upto 2.5 $f_{ck}$ . An accurate prediction model for bearing strength is proposed for better design of the composite Joint.

Mechanical and Repair Performance of Sprayed Ductile Fiber Reinforced Cememtitious Composite(ECC) (습식스프레이공법으로 타설된 고인성 섬유보강 모르타르(ECC)의 역학적 특성과 보수 성능)

  • Kim, Yun-Yong
    • Journal of the Korea Concrete Institute
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    • v.15 no.3
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    • pp.462-469
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    • 2003
  • This paper presents an experimental study on the potential durability enhancement of infrastructures repaired by a sprayed high ductile fiber-reinforced cementitious composite (ECC). For this study, a PVA-ECC which exhibits sprayable properties in the fresh state and tensile strain-hardening behavior in hardened state was sprayed and tested. The experimental results show that the sprayed ECC exhibits mechanical properties with strain capacity comparable to the cast ECC with the same mix design. During loading, the crack widths of ECC are tightly controlled with an average of 30${\mu}m$. It is also revealed that when sprayed ECC is used as a repair material, ductility represented by deformation capacity at peak load of repaired beams in flexure are obviously increased in comparison to those of commercial prepackaged mortar (PM) repaired beams. In addition to high delamination resistance, the significant enhancement of energy absorption capacity and crack width control in ECC repair system suggest that sprayed ECC can be effective in extending the service life of rehabilitated infrastructures.

The Behavior of Corrugated Steel Pipes on Underground Structures According to the Depth of Cover (파형 강관 지중구조물의 토피고에 따른 거동특성)

  • Yook, Jeong-Hoon;Kim, Nag-Young
    • Journal of the Korean GEO-environmental Society
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    • v.5 no.1
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    • pp.65-73
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    • 2004
  • The analysis of corrugated steel pipes is depending on a second dimension frame analysis or compressed ring model. This is the analysis not to consider the behavior of soil-structure interaction. The behavior of load resistance system is varied according to the depth of cover and the spacing of corrugated steel pipes structure. Therefore, the behavior characteristic of corrugated steel pipes was confirmed through finite element analysis to consider the activity of soil-structure interaction. If soil cover is filled up to the more of optimal depth, behavior of corrugated steel pipes are similar to those of ductile steel pipes according to the earth pressure distribution and effects of traffic loads are decreased. But, If soil cover is filled up to the less of optimal depth, corrugated steel pipes can't behave completely as ductile steel pipes because the passive earth pressure acting on side of corrugated steel pipes is decreased according to the decrement of vertical earth pressure, and the traffic loads influence on the section forces is increased, so that the traffic loads dominated the behavior of corrugated steel pipes.

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Vibration Analysis of Frame Structural Systems by the Receptance Method (Receptance 방법에 의한 골조구조계의 진동해석)

  • S.Y. Han;K.C. Kim
    • Journal of the Society of Naval Architects of Korea
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    • v.28 no.2
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    • pp.174-186
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    • 1991
  • There exist many frame structural systems which may be regarded as a combined structural system composed of beam/bar elements and attachments reducible to damped spring-mass systems. In this paper, analytical methods based on the receptance for the vibration analysis of such a system are presented. For the free vibration analysis and response calculations to point excitations, receptances of a uniform Timoshenko beam and a bar are derived in closed and spectral forms, and the method to obtain the system receptance by synthesizing the receptances of the elements and other subsystems is presented. The system damping property is also obtainable by sysnthesizing the components' damping properties. For calculations of the system responses to support motion, the Support Displacement Transfer Ratio(SDTR) of a uniform Timoshenko beam and a bar conceptually similar to the receptance is defined, and the method of synthesizing them with other subsystems' receptances is also presented. Such a method is very convenient especially in dynamic reanalysis subject to changes of some design variables.

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Pyran and Pyridine as Building Blocks in Heterocyclic Synthesis (이중고리 합성에 블록제로서 이용된 피란과 피리딘)

  • El-Hashash, Maher.A.;El-Sawy, Abdallah.A.;Eissa, Abdelmonem.M.F.
    • Journal of the Korean Chemical Society
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    • v.53 no.3
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    • pp.308-324
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    • 2009
  • The present work is devoted to study the interaction of $\beta$-aroylacrylic acid derivative (3) with malononitrile in (DMF) in the presence of piperidine and/or ammonium acetate, then using the formed compounds as starting materials for synthesizing fused and isolated heterocyclic systems. It has been established that the $\beta$-aroylacrylic acid (3) reacts with malononitrile in (DMF) in the presence of piperidine as a catalyst with the formation of 4H-pyran derivative (4). By changing the catalyst into ammonium acetate, pyridine derivative (5) has been obtained. Also the N-maleamic acid derivatives (19) and (27) have been synthesized via the interaction of (4) and (5) with maleic anhydride. The purpose of this step is to study the behavior of the formed maleamic acid derivatives – as analogies of $\beta$-aroylacrylic acids – towards different active methylene compounds under Michael addition reaction.

Major gene identification for FASN gene in Korean cattles by data mining (데이터마이닝을 이용한 한우의 우수 지방산합성효소 유전자 조합 선별)

  • Kim, Byung-Doo;Kim, Hyun-Ji;Lee, Seong-Won;Lee, Jea-Young
    • Journal of the Korean Data and Information Science Society
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    • v.25 no.6
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    • pp.1385-1395
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    • 2014
  • Economic traits of livestock are affected by environmental factors and genetic factors. In addition, it is not affected by one gene, but is affected by interaction of genes. We used a linear regression model in order to adjust environmental factors. And, in order to identify gene-gene interaction effect, we applied data mining techniques such as neural network, logistic regression, CART and C5.0 using five-SNPs (single nucleotide polymorphism) of FASN (fatty acid synthase). We divided total data into training (60%) and testing (40%) data, and applied the model which was designed by training data to testing data. By the comparison of prediction accuracy, C5.0 was identified as the best model. It were selected superior genotype using the decision tree.

Static Test and Suggestion of Shear Strength Equation on Shear Studs in Composite Bridge (합성형 교량에서 전단연결재에 대한 정적실험 및 강도식의 제안)

  • Yi, Seong-Tae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.2
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    • pp.43-50
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    • 2018
  • In this study, to investigate the shear connection material for the composite of steel plate and bottom plate, design standards and research cases for shear connectors in various countries around the world were analyzed and shear tests were performed on the Push-out specimens with a shear connection, which transmits the horizontal shear force developed on the contact surface between the steel plate and the concrete slab due to various vertical loads acting on the bridge deck. Through Push-out tests of shear studs, of which FRP bar instead reinforcement is placed, the shear stud evaluation formula of the steel strap bottom plate was suggested. The suggested equation suggested in this study has the safety factor of approximately three times compared to allowable strength of highway bridge design criteria. In addition, compared to existing DIN standards and Viest assessment equation, the results showed similar values(approximately, 5% error).

Determination of Capsaicin, Dihydrocapsaicin and Nonivamide by Gas Chromatography (기체크로마토그래피에 의한 캡사이신, 디하이드로캡사이신 및 노니바마이드(PAVA)의 정량)

  • Kim, Sang-Soo;Yoon, Joong-Soo
    • Journal of the Health Care and Life Science
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    • v.9 no.1
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    • pp.141-146
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    • 2021
  • Determination of capsaicin, dihydrocapsaicin and nonivamide in pungent liquids of self-defense spray were studied. The nonivamide having almost same spicy taste with capsaicin have been containing a few amounts in natural products, it had called as synthetic capsaicin or PAVA, have used to flavorings for foodstuffs and incapacitating agents of riot controls. Nowadays, it has been occasionally found that the quality controls of a self-defense sprays were not properly due to flood of illegal self-defense sprays. Thus, the simple analytical method with gas chromatography is developed, it is identified whether the products which have contained synthetic capsaicin were marked like natural materials as well as the pungent ingredients in it obeyed with permissible concentration to human or not was investigated. Finally, the pungent components and amounts in some kinds of self-defense spray were investigated.

Development of Adsorption Process with UiO-66 Particles for Hydrogen Purification Using Statistical Design of Experiment (통계학적 실험계획법을 이용한 수소정제용 UiO-66 흡착제 개발)

  • Lee, Hyun Sik;Kim, Da Som;Park, Ji Won;Yoo, Kye Sang
    • Korean Chemical Engineering Research
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    • v.56 no.6
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    • pp.784-791
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    • 2018
  • UiO-66 particles were synthesized under various synthesis conditions to study the adsorption of carbon dioxide for hydrogen purification. For the purpose, the design and analysis of experiments was performed using statistical design of experiment method. As the synthesis time, temperature and acetic acid amount increased, the crystallinity of UiO-66 particles increased. Especially, the amount of acetic acid was confirmed as an important factor in determining the crystallinity of the particles. The specific surface area of the particles measured by the nitrogen adsorption method also showed a similar tendency. Using the general factor analysis in the experimental design method, the main effects and interactions of major factors were analyzed. In addition, the carbon dioxide adsorption capacity was predicted using a nonlinear regression method. Then, the adsorption performance was shown through surface and contour maps for all ranges.