Browse > Article
http://dx.doi.org/10.6111/JKCGCT.2014.24.2.070

The effect of Zn2TiO4 on willemite crystalline glaze  

Lee, Chi-Youn (Depart. of Ceramic Art, Hanyang Women's University)
Lee, Hyun-Soo (Depart. of Ceramic Art, Hanyang Women's University)
Shin, Kyung-Hyun (Depart. of Materials Science & Engineering, Myongji University)
Publication Information
Journal of the Korean Crystal Growth and Crystal Technology / v.24, no.2, 2014 , pp. 70-76 More about this Journal
Abstract
$Zn_2TiO_4$, using an anatase form of $TiO_2$ on zinc crystalline glaze, was shown as effective nuclear agent. Thus the effects on glaze were studied with synthesized $Zn_2TiO_4$ at low temperature. First, the chromophore elements were employed in synthesized $Zn_2TiO_4$ then add them in the zinc crystalline glaze. Crystal creation and development of color by $Zn_2TiO_4$ addition on the zinc crystalline glaze were more effective. Addition of $Zn_2TiO_4$, which is developed in low range temperature, is effected as zinc crystalline nuclear in the willemite glaze. When 5 wt% of synthesized $Zn_2TiO_4$ was added to the willemite glaze, nuclear creation increases and steadily retains. Therefore addition of respectively doped $Zn_2TiO_4$ with CoO, NiO, and CuO would increase doped effects in the glaze, various color willemite crystal were obtained.
Keywords
Zinc crystal glaze; Zinc crystal nuclei growth; Willemite; $TiO_2$;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 F.H. Norton, "The control of crystalline glazes", J. Am. Ceram. Soc. (1937) 20217.
2 C.W. Parmelee, "Ceramic Glaze", 3rd Edition, Cahners Publishing Co. Inc., York, PA, USA (1973).
3 E. Kato and H. Takashima, "Study on the structure of zinc opaque glazes", J. Jpn. Ceram. Soc. 15[2] (1965) 69.
4 H.S. Lee, "The effect of nucleating agent on $Zn_2SiO_4$ crystal glaze", J. Kor. Ceram. Soc. 50[2] (2013) 116.   과학기술학회마을   DOI
5 C.Y. Lee and B.H. Lee, "A study of nucleation and growth in zinc crystal glaze by firing conditions", J. Kor. Ceram. Soc. 46[3] (2009) 253.   과학기술학회마을   DOI
6 C.C. Lee, P. Shen and H.Y. Lu, "Formation of willemite from powder mixture with $TiO_2$ addition", J. Mater. Sci. 24[9] (1989) 3300.   DOI
7 V.A. Krapivin and G.A. Demidova, "Crystalline glaze for thin stoneware", Glass and Ceramics. 26[10] (1969) 35.
8 H.H. Ko, H.T. Chen, F.L. Yen, W.C. Lu, C.W. Kuo and M.C. Wang, "Preparation of $TiO_2$ nanocrystallite powders coated with 9 mol% ZnO for cosmetic applications in sunscreens", Int. J. Mol. Sci. 13[2] (2012) 1658.   DOI
9 T. Santhaveesuk, D. Wongratanaphisan, N. Mangkorntong, and S. Choopun, "$Zn_2TiO_4$ nanostructures prepared by thermal oxidation method", Advanced Materials Research 55-57 (2008) 641.   DOI
10 L. Hou, Y. Hou, M. Zhu, J. Tang, J. Liu, H. Wang and H. Yan, "Formation and transformation of $ZnTiO_3$ prepared by sol-gel process", Material Letters 59[2-3] (2005) 197.   DOI
11 Y.V. Kolen'ko, K.A. Kovnir, A.I. Gavrilov, A.V. Garshev, P.E. Meskin, B.R. Churagulov, M. Bouchard, C. Colbeau-Justin, O.I. Lebedev, G. Van Tendeloo and M. Yoshimura, "Structural, textural, and electronic properties of a nanosized mesoporous $Zn_xTi_{1-x}O_{2-x}$ solid solution prepared by a supercritical drying route" J. Phys. Chem. B. 43[109] (2005) 20303.
12 A.W.A. El-Shennawi and A.A. Omar, "The roll of titania and titania mixtures in the nucleation and crystallization of spodumene-willemite-diopside glass", Thermochimica Acta 58[2] (1982) 125.   DOI
13 E. Ozel, H. Yurdakul, S. Turan, M. Ardit, G. Cruciani and M. Dondi, "Co-doped willemite ceramic pigments: Technological behaviour, crystal structure and optical properties", J. Eur. Ceram. Soc. (2010) 3319.
14 H.C. Ns Krpplnn, "Crystal field spectra and geochemistry of transition metal ions in silicate melts and glasses", American Mineralogist 77 (1992) 62.
15 A. Bloise, E. Barrese, C. Apollaro and D. Miriello, "Flux growth and characterization of Ti- and Ni-doped forsterite single crystals", Crystal Research and Technology 44[5] (2009) 463.   DOI
16 B. Karasu and S. Turan, "Effect of cobalt oxide and copper oxide additions to zinc-containing soft porcelain glazes", J. Eur. Ceram. Soc. 22 (2002) 1447.   DOI