• Journal of the Korean Chemical Society
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• v.27 no.6
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• pp.419-423
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• 1983

Amounts of alkylbenzene sulfonate (ABS) in the mixtures of anionic and nonionic detergents were determined by nuclear magnetic resonance (NMR) method. In the NMR spectrum of anionic and nonionic detergents, benzene group showed peaks overlapping at 6.5∼8ppm, but after sampling, benzene group showed two doublet at 7∼8ppm. Calibration curve was obtained by relative ratio of area for benzene group in anionic detergent to that for methyl group in acetic acid(acetic acid was used as the internal standard).

• Korean Journal of Food Science and Technology
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• v.43 no.3
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• pp.348-360
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• 2011

To verify the volatile compounds contributing to coffee off-flavor, medium roasted Colombian, Sumatra, Ethiopian and light and dark roasted Colombian bean coffees were sequentially and studiously over extracted. Eight espresso samples and eight filter-dripped samples were analyzed by gas chromatography/mass spectrometry with the solidphase microextraction method and evaluated by sensory tests. In total, 67 compounds were detected, and desirable aroma decreased sharply, while off-flavors increased rapidly after 30 mL of espresso and 200 mL of drip coffee. Percent peak area of 4-ethylguaiacol revealed a linear increase during extraction and was highly correlated with increasing off-flavor, suggesting that it could be an indicator of over extraction. Considering the odor activity value, guaiacol and 4- vinylguaiacol were also contributory compounds to off-flavors.

• Journal of Korea Soil Environment Society
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• v.5 no.2
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• pp.23-31
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• 2000

The objective of this study was to develop an effective separation and quantification method for kerosene and diesel in a mixed petroleum fuel (gasoline, kerosene, and diesel) contaminated environmental samples. This investigation was directed to prove the hypothesis that if the source of petroleum fuels were identical, the peak-area ratios of a reference n-alkane to other n-alkane peaks should be a constant even at the different concentrations. In addition, experimental recovery rates were determined to select the reference peaks of kerosene and diesel for peak area ratio measurements. The experimental results showed that the peak area ratios were constant among the samples having different concentrations when the ratios were calculated from areas of $C_{l3}$, $C_{l4}$, and $C_{15}$ peaks for kerosene and $C_{l6}$ and $C_{l7}$ peak for diesel as reference n-alkane peaks. The recovery rates were evaluated by comparing the relative peak area ratios of each reference peaks after making pairs of the kerosene and diesel reference peaks in the samples contained a known amount of gasoline, kerosene, and diesel. The recovery rates(%) Were 107.0$_{{\pm}20.6}$/86.6/ sub $\pm$15.9/ for kerosene- $C_{13}$/diesel- $C_{16}$, 99.6$\pm$$_{17.2}$/86.6$_{{\pm}15.9}$ for kerosene- $C_{14}$/diesel- $C_{16}$, 73.9/$\pm$14.4//86.6$_{{\pm}sub 15.9}$ for kerosene- $C_{15}$ /diesel- $C_{16}$, 109.4$_{{pm}0.8}$/75.9$_{{pm}4.7}$ for kerosene- $C_{13}$/diesel- $C_{17}$, 107.4$_{{pm}7.9}$/75.9$_{{pm}4.7}$ for kerosene- $C_{14}$/diesel- $C_{17}$, and 95.7$_{{pm}4.6}$ /75.9/$\pm$14.6//75.9$_{{pm$}4.7}$ for kerosene- $C_{15}$ /diesel- $C_{17.}$ The above experimental results confirm that all of the reference peak pairs of kerosene and diesel are applicable to the quantitative analysis for the mixed fuel contaminated samples, but the kerosene- $C_{15}$ /diesel- $C_{l7}$ peaks are recommended since the pair has a lower standard deviation than the other pairs.s..s.s.s..s..s.s.s.s.s.

• Journal of Korea Multimedia Society
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• v.12 no.4
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• pp.473-482
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• 2009

Reconstructed 3D data from computer vision includes necessarily a noise or an error. When these data goes through a mesh process, the different 3D mesh data from original shape comes to make by a noise or an error. This paper proposed the method that smooths a noise effectively by noise analysis in reconstructed 3D data. Because the proposed method is smooths a noise using the area ratio of the mesh, the pre-processing of unusable mesh is necessary in 3D mesh data. This study detects a peak noise and Gaussian noise using the ratio of 3D volume and 2D area of mesh and smooths the noise with respect of its characteristics. The experimental results using synthetic and real data demonstrated the efficacy and performance of proposed algorithm.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.03a
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• pp.227-227
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• 2003

흑연(graphite), 석탄(coal), 숯(char), soot(검댕이) 등의 탄소로 이루어진 재료들은 비정질부터 완전한 흑연결정까지 다양한 구조를 나타낸다. 이러한 탄소재료의 구조의 출발물질 뿐 아니라 열처리에 따라 강한 영향을 받는다 이러한 구조는 여러 구조인자에 의해 특성화되는데, 구조인자로는 층간거리 d, 결정립 크기 Lc 그리고 결정립 직경 La이다. 이런 구조 인자의 지식은 흑연화, 탄소화, 가스화 등과 같은 다양한 공정을 이해하는데 매우 중요하다. 많은 연구자들은 XRD, Raman 분광, 고분해능 TEM 등과 같은 여러 기술을 통하여 이러한 구조인자에 대한 해석을 시도하였다. 그 중 XRD는 정량적 분석에 있어서 가장 많이 이용되는 기술이다. XRD 회절피크의 위치로부터 층간거리 d를 구할 수 있으며, 결정립 크기 Lc 및 결정립 직경 La는 피크의 line 퍼짐(반가폭)으로 직접 구할 수 있다. 한편 섬유상 흡착제로 이용되는 등방성 탄소섬유는 이산화탄소 또는 수증기에 의해 쉽게 활성화되어 최고 약 2,500 $m^2$/g의 고 비 표면적을 얻을 수 있다. 이렇게 활성화 후 고 비표면적을 나타내는 이유는 좁은 분포를 나타내는 미세기공의 기공구조 때문에 발생하는 것으로 알려져 있다.

• Korean Journal of Mineralogy and Petrology
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• v.33 no.4
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• pp.427-437
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• 2020

Manganese nodules, which are evaluated as potential metal resources, have been found in the Arctic Ocean as well as in the abyssal plains of the Pacific and Indian Oceans. Manganese nodules exhibit strong variations in the morphology, internal texture, chemical composition and mineralogy as they grow. The relationship between the texture and chemical elemental composition during the growth process is well documented, but the mineral composition variation during the growth process is not. Because the manganese oxide minerals in nodules are fine-grained and poorly crystalline, quantitative analysis for the mineral composition is challenging for the bulk nodule sample. This study investigated the internal texture and Mn-oxide mineral composition of manganese nodules obtained from the East Siberian Sea. Semi-quantitative analysis was attempted for three main Mn-oxide minerals constituting the manganese nodules (i.e., todorokite, buserite and birnessite) using the peak area ratio of X-ray diffraction analysis graphs. In the East Siberian Sea manganese nodules, birnessite is more abundant than buserite or todorokite, and no correlation is found between the mineral composition and the internal texture. Instead a correlation is found between the relative content of todorokite and the lamellae depth. The todorokite content tends to increase from the surface to the core of the nodules, which can be attributed to a recrystallization process or difference in the growth rate within the nodule. This study shows that semi-quantitative analysis of manganese oxide minerals using the peak area ratio is useful in the mineralogical study of manganese nodules.

• Journal of Food Hygiene and Safety
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• v.35 no.3
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• pp.225-233
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• 2020

By the standards and specifications for hygiene products, three test methods for formaldehyde are specified for each item type of hygiene product. After derivatization using acetylacetone and 2,4-dinitrophenylhydrazine (2,4-DNPH), formaldehyde is analyzed by spectrophotometer and high-performance liquid chromatography (HPLC). Validation of the three test methods was performed on tissue, diaper lining and waterproof layer, and panty liner products. The results of linearity (R²), limit of detection (LOD), limit of quantification (LOQ), recovery rate (%) and reproducibility (%), showed that all three methods are suitable for analyzing formaldehyde in hygiene products. After derivatization with 2,4-DNPH and cetylacetone, formaldehyde was analyzed at 0, 3, 6, 9, 24 and 48 hours by HPLC. Formaldehyde derivatized with 2,4-DNPH showed no statistically significant change in formaldehyde peak area over time (P>0.05). But, acetylacetone-derivatizated formaldehyde showed a negative correlation coefficient (r) over time (P<0.01). We investigated the residual amounts of formaldehyde in 205 hygiene products distributed in Busan. Among 74 disposable diaper products tested, 73 had low concentrations of formaldehyde (0.13-29.87 mg/kg). Moreover, formaldehyde was not detected in any of 78 tissue, 27 disposable paper towel, 12 disposable dishcloth, 7 paper cup, one brand of paper straw and 6 disposable napkin products.

• The Korean Journal of Rheology
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• v.2 no.1
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• pp.46-52
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• 1990

배추의 조직감 특성을 기계적으로 측정하는 방법을 수립하기 위하여 여러 가지 형 태의 탐침에 의한 침투 및 절단시험에서 나타난는 힘-거리 곡선을 비교분석하였으며 그 결 과를 배추잎의 미세구조와 관능적특성과 연관하여 해석하였다. 배추잎의 침투심험에서 탐침 의 선단각, 선단면적 및 둘레에 따라 힘-거리 곡선의 형태는 크게 달라지며 선단면적과 둘 레가 커질수록 파열력이 크게 증대되었다. 절단시험에서는 표피와 내부유관속 조직을 절단 하는 세 개의 특징적인 피크를-나타내었다. 배추잎의 염장에 의하여 침투시험의 최대 변형 력은 크게 감소된 반면 파열력은 크게 증대되어 최대 변형력에 대한 파열력의 비(a/c) 는 증가되었으며 이것은 탐침의 선단면적과 둘레가 큰경우에 더욱 두드러지게 나타났다. 염장 에 의하여 탄성한계까지의 변형거리가 커졌으며 최초 변형에서의 탄성치(a/l)는 감소하는 경 향을 나타내었다. 절단시험에서는 염장에의하여 외피의 절단력이 상대적으로 증가하였다. 배 추 및 절인배추의 아삭아삭한 정도는 침투시험의 최대변형력과 a/l의 변화와 밀접한 관계가 있으며 질긴 정도는 침투시험의 파열력과 a/c 절단시험의 절단력과 관계가 있으며 아작아작 한 정도는 침투시험의 a/c와 관계가 있는 것으로 판단되었다.

• Resources Recycling
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• v.17 no.6
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• pp.79-88
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• 2008

This study is the previous stage for the mass production technology development of the nano-sized tin oxide powder by the recycling of the wasted tin metal, and nano-sized tin oxide powder with the average particle size below 50 nm is prepared from the tin chloride solution by the spray pyrolysis process. As the reaction temperature increases from 800 to 850, the average particle size of the generated powder increases from 20 to 30 nm. As the reaction temperature increases to 900, the droplet type is composed of the particles with the average size of the 30 nm. while the average size of the independent particles increases up to $80{\sim}100$ nm and the surface microstructure becomes more solid. Until $900^{\circ}C$, as the reaction temperature increases, the XRD peak intensity increases, while the specific surface area decreases. When the reaction temperature increases to 950, most of the powder appears with the independent type and the average particle size decrease down to 70 nm. The XRD peak intensity greatly decreases and the specific surface area increases almost twice.

• Proceedings of the Korea Water Resources Association Conference
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• 2008.05a
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• pp.897-908
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• 2008

황강에는 1989년 합천다목적댐과 본댐 하류 6.5km 지점에 조정지댐이 건설되었는데 조정지댐의 건설 목적은 본댐에서 피크 발전에 의해 방류되는 유량을 하류로 조절방류하기 위한것이다. 황강은 두댐의 건설후 하천폭, 하상재료, 식생 및 하천구간내 사주의 형성 등 많은 하천 지형학적 변화가 있었다. 이러한 변화는 댐 건설후 흐름 및 유사이송의 변화에 기인한다. 2002년 합천댐 저수지 퇴사량 조사에 의하면 합천댐은 연간 약 600천$m^3$의 유사를 차단한 것으로 파악되었다. 조정지댐은 연최대피크 방류량을 654.7$m^3/s$에서 126.3$m^3/s$로 감소시켰는데 이는 댐건설전의 19.3%에 해당하는 양이다. 댐건설로 인한 하류 하천의 지형적인 변화를 파악하기 위하여 합천조정지댐 하류로부터 낙동강 합류점까지 45 km에 대하여 조사하였다. 1982, 1993 및 2004년의 항공사진을 분석한 결과 비식생하도폭(non-vegetated active channel width)은 평균 152m 감소되었는데 이는 1982년의 약 53%에 해당한다. 비식생하도의 면적 역시 평균 6.6$km^2$가 감소하였다. 평균 중앙하상재료(D50)의 크기는 1983년 1.07mm에서 2003년 5.72mm로 증가한 반면 평균 하상구배는 1983년 0.000943에서 2003년 0.000847로 감소하였다. 총 하상 세굴깊이는 조정지댐 하류 20km 구간에서 평균 약 2.6m였다. 1차원 유사모형인 GSTAR-1D를 이용하여 예측된 최심하상고는 2013-2015년 사이 (댐건설후 약 25년 후)에 안정된 상태에 도달하는 것으로 나타났다. 합천 조정지댐이 본 댐에서의 피크 방류량을 상당히 감소시키고 있지만 홍수기에 조정지댐 수문의 급격하고 주기적인 개폐로 인하여 하류에 흐름의 펄스를 발생시키고 있다. 이러한 펄스가 하류 하천 지형변화에 미치는 영향을 파악하기 위하여 유사모형과 해석적인 방법을 개발 적용하여 구한 값과 비교 검토 하였다. 결과에 따르면, 일 흐름의 펄스(daily pulse)와 홍수피크(flood peak)는 각각의 평균값이 흐를 때와 비교하여 하천지형변화에 훨씬 큰 영향을 미치는 것으로 나타났다. 일 흐름 펄스와 홍수피크는 각각의 평균값의 21%와 15%의 토사 이송량 (tons/day) 증가를 보여주었다.