• Title/Summary/Keyword: 표면활성제

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Optimization of Medium Components for the Production of Crude Biosurfactant by Bacillus subtilis JK-1 (Bacillus subtilis JK-1의 생물계면활성도를 위한 최적 배지 조성)

  • Joo, Myeong-Hoon;Kim, Ji-Yeon
    • Journal of Applied Biological Chemistry
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    • v.54 no.1
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    • pp.7-14
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    • 2011
  • Bacillus subtilis JK-1 showed degradation activity against crude oil, gasoline, kerosene, and light oil, and this strain was used as a crude biosurfactant producing microorganism in this study. To optimize the culture medium for production of crude biosurfactant, the influences of various carbon, nitrogen and mineral sources were assessed. The highest biosurfactant production by B. subtilis JK-1 was observed after 96 h cultivation, containing 1.0% (w/v) soluble starch as a carbon source and 0.5% (w/v) skim milk as a nitrogen source, and carbon to nitrogen concentraion (C/N) ratio was 2.0. For the biosurfactant production 0.1% (w/v) of $KNO_3$ was the most effective mineral source. Comparison of biosurfactant production indicates that B. subtilis JK-1 produces more biosurfactant in the optimum medium established in this study than LB and TSB. Under the optimum medium, the surface tension of culture broth of B. subtilis JK-1 was decreased from 47.3 dyne/cm to 24.0 dyne/cm after cultivation of 48 h.

Preparation and Characterization of Domestic Alkali-Surfactant-Polymer Solution for Enhanced Oil Recovery (국내산 계면활성제를 이용한 오일회수증진용 알칼리-계면활성제-폴리머용액의 제조 및 특성평가)

  • Lee, Sang Heon;Kim, Sang Kyum;Park, Ji Yun;Lee, Do Kyun;Hwang, Soon Choel;Bae, Wisup;Kim, In Won;Rhee, Young Woo
    • Clean Technology
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    • v.19 no.4
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    • pp.481-486
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    • 2013
  • Alkali-surfactant-polymer (ASP) solution was manufactured by using the domestic surfactants for enhanced oil recovery. Domestic surfactants such as linear alkylbenzene sulfonic acid (LAS) and dioctyl sulfosiuccinate (DOSS) were used. This surfactants were purchased from AK chemtech Co., Ltd. (Korea). LAS and DOSS were blended and the ratio of LAS to DOSS are 1:1 and 2:1. Decane was used as a model compound of the crude oil. Surfactant solution and decane were blended to analyze microemulsion. Brine-oil-surfactant are mixed at varying concentration of brine from 0.8 to 3.6 wt.%. Increasing salinity causes the phase transition of microemulsion from water to middle to oil. Also, by measuring the surface tension and interfacial tension using pendent drop tensiometer and Huh's equation optimal ratio of the ASP solution was determined.

Characteristics of Culture Conditions for the Production of Biosurfactant by Bacillus pumilus IJ-1 (Bacillus pumilus IJ-1의 생물계면활성제 생산을 위한 배양 특성)

  • Park, Eunjin;Kim, Jiyeon
    • Journal of Applied Biological Chemistry
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    • v.58 no.1
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    • pp.81-88
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    • 2015
  • To characterize the culture medium for the biosurfactant production by Bacillus pumilus IJ-1, the influences of various carbon, nitrogen and mineral sources were assessed. As a result, the highest biosurfactant production was observed after 96 h cultivation containing 0.5% (w/v) tryptone. The strain was able to grow and produce biosurfactant at 0-10% (w/v) NaCl, in the pH range of 5-10, and at $20-45^{\circ}C$. Optimal culture conditions for the biosurfactant production were at $20^{\circ}C$ and pH 9.0 after 72 h incubation and the surface tension of biosurfactant was 27.0 dyne/cm.

Effects of Diols on the foaming and emulsion properties in surfactant solutions

  • Lee, Giam;Oh, Seong-Geun
    • Journal of the Korean Applied Science and Technology
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    • v.39 no.4
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    • pp.488-498
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    • 2022
  • The effects of 1,3-Butanediol, 1,2-Pentanediol, and 1,2-Hexanediol in surfactant solutions on cmc, surface tension, foaming and emulsifying properties were determined. The addition of diols in aqueous surfactant solution decreased cmc and surface tension, and enhanced the foaming and emulsifying power. This trend is more significant by the longer hydrocarbon chain length of the diols. This property was confirmed because the diol's alkyl chain and the hydrophobic interaction with the surfactant reduce the cohesive force of water and increase the interaction between the head groups of the surfactant at interface. In addition, MIC test was conducted to determine the preservative power of each diol, and as a result, the antibacterial activity was effective in the order of 1,2-HDO > 1,2-PDO > 1,3-BDO. The results of this study show that diol can be applied to cosmetics as an auxiliary surfactant and antibacterial agent.

Air-sparging Technology for Remediation of Specific Aquifer Layer Using Surfactant (계면활성제를 이용한 오염대수층의 선택적 폭기기술)

  • Kim, Heon-Ki;Song, Young-Su;Kwon, Han-Joon
    • Journal of Soil and Groundwater Environment
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    • v.13 no.6
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    • pp.23-30
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    • 2008
  • Air sparging technique has been used for remediation of VOC(volatile organic compound)-contaminated aquifer. The aim of this study was to develop an innovative air sparging technique that enhances the efficiency of air intrusion into a specific horizontal layer of aquifer where the contaminants exist with the help of water-soluble surfactant. A twodimensional physical box model, packed with homogeneous sand, was used for simulating the aquifer in this study. Aqueous solution of anionic surfactant (100 mg/L, sodium dodecylbenzene sulfonate) was used to suppress the surface tension of groundwater. Three sets of experiments were conducted: air sparging experiment without surfactant application, air sparging experiments for box model where the surfactant solution was applied right above the air injection point, and air sparging experiments with surfactant solution layer formed in the middle of the box. It was found that the sparging influence zone was expanded up to five times of that formed by sparging without surfactant application. The size of sparging influence zone was more sensitive to the air flow (injection) rate with surfactant application than that without surfactant. More importantly, injection of air into the target aquifer layer was successful with surfactant application. Findings in this study are expected to provide more options for designing remediation processes using air sparging.

Synthesis and Characterization of Interfacial Properties of Sorbitan Laurate Surfactant (Sorbitan Laurate 계면활성제 합성 및 계면 특성에 관한 연구)

  • Lee, Seul;Kim, ByeongJo;Lee, JongGi;Lim, JongChoo
    • Applied Chemistry for Engineering
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    • v.22 no.1
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    • pp.37-44
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    • 2011
  • The critical micelle concentration (CMC) of sorbitan laurate SP 20 surfactant in this paper was near $7.216{\times}10^{-4}mol/L$ and the surface tension at CMC was about 26.0 mN/m, which showed higher CMC and lower surface tension than those of octylphenol ethoxylate octylphenol ethoxylate (OPE) 10 surfactant. Dynamic surface tension measurement using a maximum bubble pressure tensiometer showed that the adsorption rate at the interface between air and surfactant solution was found to be slower with SP 20 surfactant, presumably due to a low mobility of SP 20 surfactant monomer. The contact angle of SP 20 surfactant solution was observed to decrease with an increase in surfactant concentration and showed a larger value than that of OPE 10 surfactant solution. Half-life time for foams generated with 1 wt% surfactant solution was also larger with SP 20 surfactant, which indicated higher foam stability with SP 20 surfactant. Dynamic behavior study reveals that the solubilization of n-decane oil was much lower with SP 20, which is in good agreement with experimental results of foam stability, contact angle and CMC. Dynamic interfacial tension measurement by a spinning drop tensiometer shows that interfacial tensions at equilibrium condition in both systems were almost the same but the time required to reach equilibrium was longer with SP 20.

Column experiment for contaminated coastal sediment bioremediation using biostimulating agent (연안오염저질의 생물정화를 위한 생물활성촉진제의 효능 평가 : 현장 컬럼실험)

  • Woo, Jung-Hui;Song, Young-Chae;Subah, Bakthavachallam
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2014.10a
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    • pp.83-84
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    • 2014
  • This study evaluated the effectiveness of biostimulating agent in contaminated coastal sediment. The study was conducted via column tests in coastal sea wherein two separate columns were employed for two different polymers used and another column for a blank. The biostimulating agent was made by mixing sea sediment with biostimulants viz acetate, nitrate, sulfate. The biostimulating agent was then rolled into balls, dried and coated with either Cellulose Acetate (CA) or Polysulfone (PS) to control the release of the biostimulants. The pH was around 7.6~8 for 4 months while COD, TP and TN were significantly lower in the column containing biostimulating agents. Heavy metal(Fe, Zn, Cd, Cr, Pb, Cu) was converted to stable forms and PS coated biostimulating agent had a high efficiency of heavy metals distribution.

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Treatment of O/W emulsion using modified ultrafiultration membrane (표면개질 한 UF 막으로 오일/물 에멀젼의 처리)

  • Jeong, Gyeong-Hwan;Lee, Kune-Woo;Kim, Kil-Jeong;Jung, Ki-Jung;Kim, Chul
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1998.10a
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    • pp.134-137
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    • 1998
  • 표면처리 한 UF 막으로 오일/물 에멀젼과 오일-SDS/물 어멜젼을 한외여과 시험하였다. 고분자와 계면활성제를 polysulfon막에 흡착시켜 표면을 처리하였다. 오일-SDS/물 에멀젼의 한외여과는 SDS양을 변화시키면서 수행하였다. 다양한 표면처리 한 막으로 한외여과 실험을 회분식 실험방법으로 수행하였다. 표면처리 안한 막에 대한 오일 에멀젼 한외여과시 fouling의 주요 원인이 오일 에멀젼의 흡착이며, 막의 표면처리와 오일 에멀젼에 계면활성제의 주입으로 뚜렷한 fouling의 저감효과가 있었다.

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The Effects of Surface Coating Material for Aluminum Form on Surface Quality of the Concrete (알루미늄 거푸집 표면코팅재가 콘크리트 표면품질에 미치는 영향)

  • Han, Cheon-Goo;Park, Jae-Soon
    • Journal of the Korea Institute of Building Construction
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    • v.10 no.3
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    • pp.57-64
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    • 2010
  • This study is to analyze the effects of aluminum form surface coating material on surface quality of concrete. When observing the surface quality of concrete affected by the change of aluminum form surface coating material, in general, as the number of use of the coating material increased, the surface quality of concrete decreased and good surface quality was shown in plywood (hereinafter PW). For epoxy (hereinafter EP) resin, when applying form remover, good surface quality was shown. For the surface roughness of concrete by the application form oil of form remover and the number of use of the coating material, as the number of use increased, highest surface roughness value was shown which meant the leveling was bad, but the surface roughness value in EP and PW was the lowest. Just for EP, when applying form remover, surface roughness value was low. For the number of void for concrete by the application of form remover and the number of use of the coating material, In general, the number of void which was generated when applying form oil the remover decreased.

The outcome of surfactant replacement therapy in above nearterm neonates with severe pulmonary disease (준 만삭 이상아에서 폐표면 활성제 보충요법의 성적)

  • Shon, Su-Min;Lee, Bo-Young;Kim, Chun-Soo;Lee, Sang-Lak;Kwon, Tae-Chan
    • Clinical and Experimental Pediatrics
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    • v.50 no.12
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    • pp.1200-1205
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    • 2007
  • Purpose : We performed this study to investigate the outcome of surfactant replacement therapy (SRT) in above nearterm neonates who were required mechanical ventilatory care due to meconium aspiration pneumonia (MAP), respiratory distress syndrome (RDS) or other severe pneumonia (PN). Methods : 48 patients, gestational period ${\geq}36weeks$, who were admitted in NICU of Dongsan Medical Center, Keimyung University between July 1999 and June 2004 were enrolled. They were divided into three groups, MAP group (15 cases), RDS group (27 cases) and PN group (6 cases). All patients were received SRT and evaluated several clinical data (gestational age, oxygen index, duration of ventilator care) and outcome (complications and mortality rate) between pre-SRT and post-SRT. The mean dose of surfactant (modified bovine surfactant, Newfacten, Yuhan Co., Seoul, Korea) was 120 mg/kg. Results : Among each groups, mean pre-SRT OI was higher in MAP group ($21{\pm}3.2$) than other groups, mean duration (days) of ventilatory care and oxygen therapy were similar distributions. Compared with pre-SRT values, significant improvements (P<0.05) in mean values for FiO2 and oxygenation index were documented at 12 hours after SRT. Early complications (persistent pulmonary hypertension of newborm, pneumothorax) and survival rate were lower in MAP group. Within RDS group, earlier SRT (given before 12 hours of life) revealed significantly lower early complication rate than later SRT (given after 12 hours of life) (13.3% vs 58.3%, P<0.05) Conclusion : Our study suggested that SRT seems to be an effective therapy in above nearterm neonates with severe pulmonary disease, and earlier SRT tends to reduce complications in RDS group than later therapy.