• Title/Summary/Keyword: 표면팽창

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Chemical and Thermal Characterizations of Electron Beam Irradiated Jute Fibers (전자빔 조사된 황마섬유의 화학적 및 열적 특성분석)

  • Ji, Sang Gyu;Cho, Donghwan;Lee, Byung Cheol
    • Journal of Adhesion and Interface
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    • v.11 no.4
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    • pp.162-167
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    • 2010
  • In the present work, the effect of electron beam irradiation on the chemical and thermal characteristics of cellulose-based jute fibers was explored by means of chemical analysis, electron spin resonance analysis, ATR-FTIR spectroscopy, thermogravimetric analysis and thermomechanical analysis. Jute fiber bundles were uniformly irradiated in the range of 2~100 kGy by a continuous method using a conveyor cartin an electron beam tunnel. Electron beam treatment, which is a physical approach to change the surfaces, more or less changed the chemical composition of jute fibers. It was also found that the radicals on the jute fibers can be increasingly formed with increasing electron beam intensity. However, the electron beam irradiation did not change significantly the chemical functional groups existing on the jute fiber surfaces. The electron beam irradiation influenced the thermal stability and thermal shrinkage/expansion behavior and the behavior depended on the electron beam intensity.

An Evaluation of Resistances in Porous Asphalt Concrete Mixtures due to Repeated Cyclic Freeze-Thawing (배수성 아스팔트콘크리트 혼합물의 반복 동결융해 저항성 평가)

  • Jo, Shin Haeng;Kim, Nakseok
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.1D
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    • pp.33-39
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    • 2012
  • More and more pavements are suffering from damage these days due to the below-zero winter temperatures and frequent snowfalls. From this research, the freeze-thawing mechanisms of pavements will be observed, and the freeze-thawing resistance of porous asphalt concrete mixture is to be evaluated according to various assessment methods. The investigation was conducted through applying rigid and flexible pavements to freeze-thawing resistance experiments, which include various experiments such as deformation rate measurements, Lottman tests, repeated cyclic freeze-thawing experiments, stripping resistance tests and so on. Test results revealed that the porous asphalt concrete had less deformations according to temperatures compared to dense-graded asphalt concrete due to the 20% void gap. In addition, according to the freeze-thawing repetition experiments which are effected by moisture, the porous asphalt concrete mixture showed superior resistance to repeated cyclic freeze-thawing compared to other asphalt concrete mixtures due to the drainage and the voids within the specimen.

Synthesis of CO2 Adsorbent with Various Aminosilanes and its CO2 Adsorption Behavior (다양한 아미노실란을 이용한 이산화탄소 흡착제 합성 및 흡착 특성)

  • Jeon, Jae Wan;Ko, Young Soo
    • Applied Chemistry for Engineering
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    • v.27 no.1
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    • pp.80-85
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    • 2016
  • The carbon dioxide adsorption behavior of silica with a large specific surface area and pore volume functionalized with aminosilane compounds via in-situ polymerization and functionalization method were investigated. The organosilanes include amino functional group capable of adsorbing carbon dioxide. Elemental analyzer, in situ FT-IR and thermogravimetric analyzer were used to characterize the sorbents and to determine their $CO_2$ adsorption behavior. Comparison of different aminosilane loading in the support revealed that polyaminosilane functionalization of 70% of the pore volume in the support was better in terms of the adsorption capacity and amine efficiency than that of 100% of the pore volume of the support. Furthermore, the sorbents showed a higher adsorption capacity at an adsorption temperature of $75^{\circ}C$ than at $30^{\circ}C$ due to the thermal expansion of synthesized polyaminosilanes inside the pore of silica. The N-[3-(trimethoxysilyl)propyl]ethylenediamine (2NS) sorbent with 70% of the pore volume functionalized showed the highest adsorption capacity of 9.2 wt% at $75^{\circ}C$.

A study on the measurement of thermophysical properties of ${Al}_{2}{O}_{3}, {Si}_{3}{N}_{4}$ and SiC series by a single rectangular pulse heating (방향파 펄스 가열에 의한 ${Al}_{2}{O}_{3}, {Si}_{3}{N}_{4}$, SiC 계열의 열물성치 측정에 관한 연구)

  • 차경옥;장희석;이흥주
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.1
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    • pp.145-156
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    • 1990
  • In this study, thermophysical properties of the engineering ceramic materials such as $Al_{2}$O$_{3}$, Si$_{3}$N$_{4}$ and SiC were measured b y a single rectangular pulse heating method. The values of thermal diffusivities, specific heats, and thermal conductivities were measured as a function of temperature ranging form room temperature to 1300K. The measured thermal properties of one group of ceramic material were compared with those of other group and discussed in detail in connection with the chemical composition. Thus, some criteria for thermal design with the engineering ceramic materials were proposed.

Variation of the Physical-microstructural Properties of Sandstone and Shale Caused by CO2 Reaction in High Pressure Condition (고압 이산화탄소 반응에 의한 사암과 셰일의 물리적-미세구조적 변화)

  • Park, Jihwan;Son, Jin;Park, Hyeong-Dong
    • Tunnel and Underground Space
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    • v.26 no.4
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    • pp.293-303
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    • 2016
  • Underground $CO_2$ storage technology is one of the most effective methods to reduce atmospheric $CO_2$. In this study, $CO_2$ storage condition was simulated in the laboratory. Sandstone and shale specimens were saturated in 1M NaCl and were reacted at $45^{\circ}C$, 10 atm for 4 weeks. The physical and microstructural properties of rock specimens were measured. Variations on physical properties of shale specimens were bigger than those of sandstone specimens, such as volume, density, elastic wave velocity, Poisson's ratio and Young's modulus. Microstructure were analyzed using X-ray computed tomography. Total number of pores were decreased, and average volume, average area and average equivalent diameter of each pore were changed after $CO_2$ reaction. Swelling and leakage of clay mineral caused by $CO_2$-mineral reaction were the reason of changes. The results of this study can be applied to predict the physical and microstructural changes in underground $CO_2$ storage condition.

Vibration Control of the Continuous System Under White Noise Disturbance (백색잡음가진을 받는 연속체의 진동제어)

  • Paik, Jong-Han;Heo, Hoon
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 1994.10a
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    • pp.116-120
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    • 1994
  • 최근 항공우주 및 생산자동화 분야의 급격한 발달에 따라 정밀도와 효율성을 향상시키기 위해 저중량, 고강도 구조물이 요구된다. 그러나 경량화 추세로 인해 수반되는 구조물의 유연성 증가로 외력에 대한 구조응답의 진폭이 커지고 구조물의 피로 수명이 단축되어 매우 위험한 상황에 이를 수 있다. 이런 바람직하지 않은 진동현상을 제어하기 위해 여러 제어이론을 응용한 진동억제시스템의 연구가 활발하며, 신소재인 압전재료의 개발로 새로운 방향이 제시되고 있다. 압전재료는 유연한 구조물에 부착되어 압전재료의 수축, 팽창 운동에 의해 발생된 에너지를 부착된 구조물에서의 제어력으로 사용되어, 진동 혹은 자세 및 형상 제어에 활용되고 있다. 압전재료에 대한 연구로는 Crawley, de Luis3가 보의 표면 혹은 내부에 압전세라믹을 부착하여 액튜에이터로 사용하는 경우 집중모멘트를 가하는 역할을 함을 밝혔고, Hanagud, obal은 압전재료를 센서와 액튜에이터로 사용해 복합재료 보에 대한 최적 진동제어 알고리즘을 개발, 그 성능에 대한 효과를 조사하였고 임의의 위치에 부착된 센서 및 액튜에이터를 고려한 복합재료 보의 운동방정식을 유한요소법을 이용 유도하였으며 변위율 피드백(rate feedback)과 모달피드백(modal feedback) 제어기를 적용하여 진동제어 효과를 고찰하였다. 그리고 Tomas, James, Hubbard는 압전필름을 액튜에이터로 사용해 복합재료 보에 Liapunov 제어기와 변위율 피드백 제어기를 사용하여 능동감쇠기를 설계하였고, Lee, Chaing, Sullivan은 압전필름을 센서와 액튜에이터로 사용해 평판에 변위율 피드백 제어기를 적용한 능동감쇠기를 설계하고 실험적으로 수행하였다. Base가 백색잡음가진을 지속적으로 받을 때 보끝의 움직임이 최소가 되도록 제어하고자 연구를 수행 중인 바 그 결과로소 본 논문에서는 적용시켰고 F-P-K 방정식을 이용해 확률영역으로 변환하여 LQR 제어기와 pole allocation 제어기를 시스템에 적용시켜 우수한 특성을 갖음을 제어 시뮬레이션의 결과를 통해 입증하였다.

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Functionally Gradient Materials (FGMs) for Improved Thermo-mechanical Properties (열.기계적 특성 향상을 위한 경사기능 재료 (FGM))

  • 박성용;김진홍;김문철;박찬경
    • Journal of Powder Materials
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    • v.11 no.1
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    • pp.8-15
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    • 2004
  • The basic concept of functionally gradient materials (FGM) is to fabricate materials type having possibilities of applications in various fields by changing their intrinsic properties with continuous gradient. The present communication has reviewed the developments and applications of various FGMs designed for improved thermo-mechanical properties, in which the thermal protective and wear resistant materials are especially focused. Effects of thermo-mechanical properties and limits of FGMs designed for high temperature applications were mainly understood in terms of residual stress evolved from the design and fabrication. In addition, FGMs applied in structural parts were also introduced and discussed in terms of typical fabrication method for FGMs.

Effects of GTR and Unexpanded Expancel Powders on Thermal Conducting Characteristics of Rigid Polyurethane Foams (GTR 및 미발포 Expancel이 경질우레탄폼의 열전도특성에 미치는 영향)

  • Ahn, Won-Sool
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.6
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    • pp.2846-2851
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    • 2012
  • Effects of ground tire rubber(GTR) and unexpanded $Expancel^{(R)}$ powders on the thermal conducting characteristics of rigid polyurethane foams(PUFs) were studied. Sub-micron sized GTR powders and $Expancel^{(R)}$ powders were used as the foam nucleating agents to improve the thermal insulating properties of the rigid PUFs. As the results, while the thermal conductivities of the GTR filled-PUF samples were increased linearly with GTR contents, those of $Expancel^{(R)}$ filled-PUF samples were decreased a little bit. It was considered from the results that GTR powders might predominantly play a role as the extending fillers. On the other hand, $Expancel^{(R)}$ powders could act as the foam nucleating agents based on the polar surface, showing smaller cell sized PUF with improved insulating characteristics.

Shape Optimization of S-tube for Heat Exchanger Used in High Temperature Environment Using FE Analysis and DOE (유한요소법과 실험계획법을 이용한 고온 열교환기용 S-관의 형상 최적화)

  • Jeong, Ho-Seung;Cho, Jong-Rae
    • Journal of Advanced Marine Engineering and Technology
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    • v.36 no.4
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    • pp.497-503
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    • 2012
  • The aim of this study was to optimize S-tube shape of heat exchanger in term of reducing the size of tube bundle and improving the mechanical properties such as the thermal stress and resonance. The geometric parameters such as offset length, the straight distance between one end and other end of tube, the tube length in straight portion and fillet radius was assessed as a valid parameters. The structural analysis was performed to estimate the structural characteristics. Main effect analysis was performed to investigate the main effect for the various geometric parameters. The response surface methodology was employed to establish mathematical approximation models as a function of the geometric parameters of the S-tube. Also, The optimization was performed to optimize geometric parameters of S-tube using the regression equations and optimization tool. The optimized tube shape has been proposed. Those could be used in the heat exchanger design used in high temperature.

Measurement of Coating Removal Rate of Accelerated Dry Ice Snow Impact (가속 드라이아이스 snow impact에 의한 도막 제거속도의 측정)

  • Na, Young Min;Kim, Hotae;Kim, Sun-Geon
    • Clean Technology
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    • v.10 no.4
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    • pp.177-187
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    • 2004
  • Dry ice snow jet was produced by high-pressure expansion of liquid carbon dioxide and subsequent acceleration by carrier gas flow. Removal mechanism for coating was not so different from that for contaminating particles on the surface. The removal of coating was quantitatively described by Hutchings' equation. The two parameters obtained from the plot, were used to predict the removal rate or the specific coating area removed by a unit mass of carbon dioxide. Their values also enhanced the reliability of the experimental data and enabled the experimental errors corrected. Hutchings' plots obtained with various values of either stand-off distance or nozzle length tends to meet apparently at a single unique point at which the scar-size enlargement by focusing jet plume was balanced with that by spreading it.

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