• Title/Summary/Keyword: 표면변색

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A new method for obtaining the silica-polyaniline core-shell hybrid functional coating using the hydrolysis and condensaion reaction of TEOS (TEOS의 가수분해 및 축합반응을 이용한 실리카-폴리아닐린 core-shell 하이브리드 기능성 박막의 습식 코팅 방법)

  • Lee, Heung-Ryeol;Kim, Ho-Hyeong;Kim, Gyun-Tak;Hwang, Tae-Jin
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2009.10a
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    • pp.109-110
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    • 2009
  • 실리카와 폴리아닐린의 core-shell 복합체 나노입자를 실리카 나노입자 분산용액을 이용하여 제조하였다. 제조된 복합체 나노입자를 전기변색박막의 소재로 이용하기 위하여 알코올 용액에 분산하였고, 분산된 용액에 Tetraethoxysilane (TEOS)를 소량의 HCl 용액과 함께 첨가하여 코팅 용액을 제조하였다. 코팅 용액을 인듐주석산화물(ITO) 박막이 도포된 유리 기판위에 도포하고 열처리 하여 매우 높은 부착력을 갖는 전기변색박막을 얻을 수 있었다.

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Weathering Characteristics according to Seawater Immersion of the Magai Wareiishi Jizo (Buddhist Statue Carved on Rock Surface) in Hiroshima, Japan (일본 히로시마현 마애화령석지장(磨崖和靈石地藏)의 해수 침수에 의한 풍화특성)

  • Lee, Sun Myung;Lee, Myeong Seong;Chun, Yu Gun;Lee, Jae Man;Morii, Masayuki
    • Journal of Conservation Science
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    • v.28 no.4
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    • pp.329-341
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    • 2012
  • Magai Wareiishi Jizo (Buddhist statue carved on rock surface) is close to shoreline and a part of rock block is periodically immersed by seawater. Rock material of the Wareiishi-jizo statue is composed mainly of medium or coarse-grained biotite granite and very durable. However, physical properties of the rock have been changed according to the complex interactions of the salt solution and surrounding environment. Exfoliation of the rock surface is a serious condition by salt crystallization. Exfoliation (14.6%) is concentrated on the upper part of the rock block with mainly boundary of seawater as the center. On the other hand, lower part of the rock block show black layers by contaminants deposition. In addition, brown discoloration and biological contaminants is overlapped. Rock surface show high discoloration rate of 50.5% (black discoloration, 29.2% > yellow discoloration, 14.1% > brown discoloration, 4.4% > green discoloration, 2.9%). Upper part of the rock block had a lot of change in the physical properties than lower part that is immersed by seawater. In particular, surface properties of the rock block was very weak state at the boundary surface of seawater permeation.

Effects of Selected Stabilizers on the Color Deterioration of Crude Pigment Extract from Schizandra fruit (Schizandra Fructus) (여러 가지 안정화 물질이 오미자 색소 추출물의 가열 변색에 미치는 영향)

  • Kim, Hyun-Jung;Cho, Sung-Bin;Chun, Hyang-Sook
    • Journal of the Korean Society of Food Culture
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    • v.18 no.5
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    • pp.475-482
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    • 2003
  • The effects of selected stabilizers and sugars on color deterioration of anthocyanin in Schizandra fructus were examined at $100^{\circ}C$ for $120{\sim}180$ min. Among four test sugars, it was found that fructose accelerated the thermal color deterioration while maltose retarded the color deterioration by 40%. Maltodextrin and ${\gamma}$-cyclodextrin showed the highest stabilizing effect on the thermal color deterioration of crude pigment extract from Schizandra fructus(CPES) containing 2 mg% of anthocyanin. Addition of maltodextrin or ${\gamma}$-cyclodextin at 5% retarded thermal color deterioration of CPES. In gel system, 5% of maltodextrin also retarded the color deterioration by $15{\sim}20%$ during storage at $25^{\circ}C\;and\;35^{\circ}C$.

Development of Energy Harvesting Hybrid system consisted of Electrochromic Device and Dye-Sensitized Solar Cell using Nano Particle Deposition System (나노 입자 적층 시스템(NPDS)을 이용한 염료 감응 태양전지 - 전기 변색 통합 소자 및 에너지 하베스팅 시스템에 대한 연구)

  • Kim, Kwangmin;Kim, Hyungsub;Choi, Dahyun;Lee, Minji;Park, Yunchan;Chu, Wonshik;Chun, Dooman;Lee, Caroline Sunyong
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.2
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    • pp.65-71
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    • 2016
  • In this study, Antimony Tin Oxide (ATO) ion storage layer and $TiO_2$ working electrode were fabricated using Nano Particle Deposition System. NPDS is the cutting-edge technology among the dry deposition methods. Accelerated particles are deposited on the substrate through the nozzle using NPDS. The thicknesses for coated layers were measured and layer's morphology was acquired using SEM. The fabricated electrochromic cell's transmittance was measured using UV-Visible spectrometer and power source at 630 nm. As a result, the integrated electrochromic/DSSC hybrid system was successfully fabricated as an energy harvesting system. The fabricated electrochromic cell was self-operated using DSSC as a power source. In conclusion, the electrochromic cell was operated for 500 cycles, with 49% of maximum transmittance change. Also the photovoltaic efficiency for DSSC was measured to be 2.55% while the electrochromic cell on the integrated system had resulted in 26% of maximum transmittance change.

Effects of Steel Composition on Heat Resistance and Coatability of Hot-dip Aluminized Sheet Steel (용융 Al 도금강판의 내열성과 밀착성에 미치는 강성분 영향)

  • Bae, Dae-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.04a
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    • pp.40-41
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    • 2007
  • 용융 Al 도금강판의 내열성, 도금성 향상을 위한 실험실적 변수 영향을 고찰하였다. 내열성 향상을 위한 강 성분 변경시험 결과와 용융 도금성(젖음성 : Wettability) 향상을 위한 표면 농화물 등의 관찰 결과를 Fe-SEM, Glossmeter, 광학현미경, GDS 기기 등을 이용하여 측정하였다. 아울러, 용융 Al도금이 가능한 각 원소의 영향을 고찰함으로써 현재 $400^{\circ}C$ 전후에서 변색 없이 사용가능한 수준을 약 $80-100^{\circ}C$ 상승시킴으로써 Alcosta 제품 사용범위 확대에 기여한다.

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Detailed Deterioration Diagnosis and Analysis of Site Environment for the Taean Dongmunri Maaesamjonbulipsang (Rock-carved Standing Triad Buddha Statue), Korea (태안 동문리 마애삼존불입상의 정밀 훼손도 진단과 위치환경 분석)

  • Lee, Sun-Myung;Jun, Byung-Kyu;Shin, Eun-Jeong;Lee, Chan-Hee
    • Journal of Conservation Science
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    • v.27 no.4
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    • pp.381-393
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    • 2011
  • This study focus on the surface deterioration diagnosis based on the material characteristics of Taean Dongmunri Maaesamjonbulipsang(rock-carved standing triad Buddha Statue) and the weathering environment analysis. Rock materials of the triad Buddha is coarse-grained biotite granite which is composed mainly of quartz, K-feldspar, plagioclase, biotite and muscovite. The triad Buddha was serious surface irregularity(13.5%), exfoliation(12.3%) and discoloration(46.6%), and the physical characteristics using ultrasonic velocity appeared fourth grade (0.59, highly weathered). Korean style wooden shelter of the triad Buddha(closed type) maintained high humidity environment (daily mean; 86.6%) than exterior environment, and appeared the possibility of deterioration by freezing-thawing because the temperature showed below zero temperatures in winter. The shelter was changed from closed-type to open-type to relieve the moisture problem recently. But the moisture problem is yet to be solved because surface water flowing along northern wayside is flowed into triad Buddha. Therefore, environmental control will need to stop inflow of water into triad Buddha.

Interpretation of Surface Contamination and Genesis on the Stupa of the State Preceptor Jigwang from the Beopcheonsaji Temple Site in Wonju, Korea (원주 법천사지 지광국사탑의 표면오염 및 성인 해석)

  • Kang, San Ha;Lee, Ju Mok;Lee, Gyu Hye;Kim, Sa Duk;Lee, Chan Hee
    • Journal of Conservation Science
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    • v.34 no.3
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    • pp.211-225
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    • 2018
  • The Stupa of the State Preceptor Jigwang from the Beopcheonsaji temple site in Wonju (National Treasure No. 101) was built in the Goryeo Period (around the 11th century), with very excellent style and techniques. It was returned to the Korea after being taken to Osaka of Japan without notice in 1912, and was severely damaged during the Korean War. Subsequently, the Stupa was restored using restoration materials like mortar, and relocated to the National Palace Museum of Korea. Surface contaminants in the Stupa primarily existed around the restoration materials. Black discoloration, which indicates a high discoloration grade, signified a high possession rate in the north and inner regions of the Stupa, which may be related to the relative moisture maintenance time. Most surface contaminants were calcite and gypsum; the black discoloration area underwent secondary discoloration due to air pollution. Moreover, the stone properties exhibited a relatively low discoloration grade, exhibiting crystallized contaminants that partly covered the rock-forming minerals. Overall, the Stupa deteriorated due to discoloration and being covered by lime materials, which were dissolved as the mortar degraded. Hence, it required contaminants removal, surface cleaning and desalination during conservation treatment, in order to control the rate of physicochemical deterioration by contaminants.

Preparation of $WO_3$ Films by CVD and their Application in Electrochromic Devices (화학기상 증착법을 이용하여 제조된 텅스텐 산화막의 전기변색 소자 응용 연구)

  • Jung, Hun;SunWoo, Changshin;Kim, Do-Heyoung
    • Korean Chemical Engineering Research
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    • v.49 no.4
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    • pp.405-410
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    • 2011
  • A study on chemical vapor deposition(CVD) of $WO_3$ and the electrochromic properties of the CVD $WO_3$ films have been carried out. The crystalinity, purity, and growth rate of the films depending on substrate temperatures are investigated. The highest growth rate is $8{\mu}m/min$ at the substrate temperatures above $300^{\circ}C$ and the estimated activation energy for overall film growth is about 45.9 kJ/mol at the temperatures of $225{\sim}275^{\circ}C$, where the CVD process is controlled by a surface reaction kinetics. The films grown below $275^{\circ}C$ are amorphous, while those deposited above $300^{\circ}C$ are crystalline. The effects of thickness and deposition temperature of the $WO_3$ films on electrochromic activity are also investigated. The coloration efficiency of the films increases with increase in film thickness and decrease in deposition temperature.

Plating Technology of Anti-corrosion for Cost Reduction of Au (Au사용량 감소 고내식성 도금기술동향)

  • Kim, Yu-Sang;Jeong, Gwang-Mi
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2013.05a
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    • pp.144-144
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    • 2013
  • 금도금이 오래전부터 장식용으로서 다양한 미술품에 이용되고 있는 것은 잘 알려져 있지만 공업용으로서도 도전성과 내변색성이 뛰어나기 때문에 커넥터, 반도체 등 전자부품의 접점용 도금으로서 폭넓게 이용되고 있다. 스마트폰, 노트북컴퓨터에 대표되는 최근의 전자기기는 고성능이면서 소형이 요구되며 전자부품도 소형화, 고밀도화가 진행되고 있다.

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