• Title/Summary/Keyword: 폴리에틸렌 글리콜

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Determination of Polyol Concentration Affecting to the Transparent Bar Soap Using Design of Experiment Method (실험 계획법을 이용한 투명비누에 영향을 미치는 폴리올 농도 결정)

  • Cho, Wan-Goo
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.1
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    • pp.54-62
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    • 2012
  • In this experiment, the optimum concentration of polyols which were used for making transparent soaps was determined using design of experiment (DOE) method. Dipropylene glycol and 1,3 butylene glycol with short chains enhanced the transparency of soap, however, polyethylene glycol 400, glycerin and diglycerin made the soap opaque. The hardness of soap was increased as increasing the concentration of propylene glycol, diglycerin, dipropylene glycol and polyethylene glycol 400. The hardness, transparency, absorbance of water, and friction solubility could be optimized by controlling the concentration of dipropylene glycol, polyetylene glycol, sugar, and triethanolamine.

Thin-Film Composite (TFC) Membranes with Hydrophilic Ethyl Cellulose-g-poly(ethylene glycol) (EP) Substrates for Forward Osmosis (FO) Application (친수성을 가지는 에틸셀룰로스-폴리에틸렌글리콜 가지형 고분자의 정삼투 복합막 지지층으로의 응용)

  • Yu, Yun Ah;Kim, Jin-joo;Kang, Hyo;Lee, Jong-Chan
    • Korean Chemical Engineering Research
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    • v.54 no.4
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    • pp.510-518
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    • 2016
  • Ethyl cellulose-g-poly(ethylene glycol) (EP) was synthesized by esterification of carboxylic acid functionalized methoxy polyethylene glycol (MPEG-COOH) with ethyl cellulose (EC) in order to develop a hydrophilic substrate for thin-film composite (TFC) membrane in a forward osmosis (FO) system. A porous EP substrate, fabricated by a non-solvent induced phase separation method, was found to be more hydrophilic than the EC substrate due to the presence of polyethylene glycol (PEG) side chains in the EP. Since the EP substrate exhibits smaller water contact angles and higher porosity, the structural parameter (S) of TFC-EP is smaller than that of TFC-EC, indicating that internal concentration polarization (ICP) within porous substrates can occur less when TFC-EP is used as a membrane. For example, the water flux value of the TFC-EP is 15.7 LMH, whereas the water flux value of the TFC-EC is only 6.6 LMH. Therefore, we strongly believe that the TFC-EP could be a promising candidate with good FO performances.

Dehydration of Carrot Slice Using Polyethylene Glycol and Maltodextrin and Comparison with Other Drying Methods (폴리에틸렌 글리콜과 말토덱스트린 첨가에 의한 당근 절편의 탈수, 건조와 기존 건조 방법과의 비교)

  • Kim, Min-Ki;Kim, Min-Hee;Yu, Myung-Shik;Song, Young-Bok;Seo, Won-Joon;Song, Kyung-Bin
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.38 no.1
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    • pp.111-115
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    • 2009
  • Carrots were dried using 30, 50, and 80% polyethylene glycol (PEG) or maltodextrin as a dehydrating agent, and the dried carrots were compared with the freeze dried and hot-air dried in terms of rehydration ratio, color, carotene content, and sensory evaluation. The amount of moisture loss during drying of carrots using PEG or maltodextrin increased with increasing concentration of dehydrating agent. Rehydration ratio as well as carotene content of the PEG-treated carrots were greater than those of freeze-dried or hot-air dried carrots. Regarding color and sensory evaluation of the dried carrots, the PEG-treated and maltodextrin-treated carrots were better than freeze-dried or hot-air dried carrots. These results suggest that drying of carrots using PEG or maltodextrin is a very efficient method because of its good rehydration capacity and minimal destruction of nutrients and cell structure.

A Versatile and Practical Synthesis of 1, 8-Dioxo-octahydroxanthene Derivatives Catalyzed by Polyethylene Glycol (PEG) in Water (수용액에서 폴리에틸렌 글리콜 촉매에 의한 1, 8-Dioxo-octahydroxanthene 유도체의 다용도적이며 실용적인 합성)

  • Chavan, Abhijit P.
    • Journal of the Korean Chemical Society
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    • v.53 no.4
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    • pp.415-421
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    • 2009
  • A convenient and practical synthesis of 1, 8-dioxo-octahydroxanthene derivatives using various aldehydes, 5, 5-dimethyl-1, 3-cyclohexanedione in water was successfully carried out in the presence of polyethylene glycol (PEG) as a catalyst. Simple work-up, clean products, high yields and water as a green solvent are the attractive features of this methodology.

Mediated Electrochemical Oxidation of High Molecular Weight PEGs by Co(III)/Co(II) and Fe(III)/Fe(II) Redox Systems (Co(III)/Co(II) 및 Fe(III)/Fe(II) 산화환원계에 의한 고분자량 폴리에텔렌글리콜류의 매개전해산화)

  • Park, Seung-Cho;Kim, Ik-Seong
    • Applied Chemistry for Engineering
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    • v.16 no.2
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    • pp.206-211
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    • 2005
  • Mediated electrochemical oxidation (MEO) of polyethylene glycols (PEGs) of molecular weight of 1000, 4000 and 20000, was carried out on both platinum (Pt) and titanium-iridium electrodes in 8.0 M nitric acid solution containing 0.5 M Fe(II) and Co(II) ion. The electrochemical parameters such as current densities, kinds of electrode, electrolyte concentration and removal efficiency were investigated in both Fe(III)/Fe(II) and Co(III)/Co(II) redox systems. The PEGs was decomposed into carbon dioxide by MEO in Fe(III)/Fe(II) and Co(III)/Co(II) redox system during 180 min and 210 min at the current density of $0.67A/cm^2$ on the Pt electrode. Removal efficiency of PEGs by MEO was better in Co(III)/Co(II) redox system than Fe(III)/Fe(II) redox system, indicating mediated electrochemical removal efficiency was 100%.

Oxidation of Diphenylmethane Using Polyethylene glycols as Phase Transfer Catalysts (폴리에틸렌글리콜 상이동 촉매를 이용한 디페닐메탄의 산화반응)

  • Lee, Hwa-Soo;Moon, Jeong-Yeol;Park, Dae-Won;Park, Sang-Wook;Shin, Jung-Ho
    • Applied Chemistry for Engineering
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    • v.4 no.4
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    • pp.715-720
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    • 1993
  • Diphenylmethane (pKa=33.4), which is difficult to be oxidized in normal oxidation conditions, was oxidized to produce benzophenone at ambient temperature and atmospheric pressure by using phase transfer catalysts and solid potassium tert-butoxide as base. Quaternary salt such as benzyltriethylammonium chloride, tetrabutyl ammonium bisulfate, tetrabutylphosponium chloride, are ineffective catalysts for this reaction, but 18-crown-6 and polyethylene glycols showed catalytic activity. The conversion of diphenylmethane was increased with increasing chain length of PEG molecules when they are used as phase transfer catalysts both in equal molar and equal weight basis. The conversion of diphenylmethane was increased with the agitation speed, and aprotic solvent like DMF showed higher reaction rate compared with benzene.

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Synthesis and Properties of Poly(ethylene 2,6-naphthalate) Copolymer Containing Poly(ethylene glycol) Groups (폴리에틸렌기를 함유한 폴리에틸렌 나프탈레이트 공중합체의 합성 및 특성)

  • 손준식;지동선
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.167-168
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    • 2003
  • Dimethyl-2,6-naphthalenedicarboxylate(2,6-NDC)와 ethylene glycol(EG)로부터 유도되는 폴리에틸렌 나프탈레이트(PEN)는 폴리에틸렌 테레프탈레이트(PET)보다 열적 및 기계적 특성이 우수한 열가소성 고분자이며[1-2], 폴리에틸렌 글리콜(PEG)은 diol기를 함유한 친수성 고분자로서 의약품 및 기타 가공제로 널리 쓰이는 물질이다. 이미 PET는 이러한 PEC를 PET 합성과정에서 공단량체로 사용해 공중합시킴으로서 친수성을 갖는 PET로 개질하고자 하는 연구[3-4]가 다수 보고되어 왔으나, PEN의 경유는 아직 이에 관한 연구보고가 없는 실정이다. (중략)

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Comparison of the Efficacy of Diluted Polyethylene Glycol and Low-Density (0.1% w/v) Barium Sulfate Suspension for CT Enterography (전산화단층촬영 소장조영술을 위한 희석된 폴리에틸렌 글리콜과 저밀도(0.1% w/v) 바륨 현탁액의 유용성 비교)

  • Yeon Jung Kim;Seung Ho Kim;Tae Wook Baek;Hyungin Park
    • Journal of the Korean Society of Radiology
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    • v.84 no.4
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    • pp.911-922
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    • 2023
  • Purpose To compare small bowel distension and side effects between a diluted polyethylene glycol (PEG) solution and a low-density (0.1% w/v) barium sulfate suspension (LDBSS) for CT enterography (CTE) preparation. Materials and Methods Total 173 consecutive patients who underwent CTE were enrolled in this study. The LDBSS (1 L) was used in 50 patients, and the diluted iso-osmotic PEG solution (1 L) was used in 123 patients. Two blinded radiologists independently scored jejunal and ileal distensions on a 5-point scale. To compare side effects between the two groups, the patients reported whether they had immediate complications after the administration of the oral contrast media. Results For ileal and jejunal distension, the diluted PEG solution showed no difference from the LDBSS for either reader (ileum: reader 1, median, 4; 4, interquartile range, 3-4; 3-4, p = 0.997; reader 2, median, 4; 4, interquartile range, 3.3-4.0; 3-4, p = 0.064; jejunum: reader 1, median, 2; 2, interquartile range, 2-3; 2-3, p = 0.560; reader 2, median, 3; 2, interquartile range, 2-3; 2-3, p = 0.192). None of the patients complained of immediate complications following administration of either of the oral contrast media. Conclusion The diluted PEG solution showed comparable bowel distension compared to LDBSS and no immediate side effects; thus, it can be a useful alternative.