• Clean Technology
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• v.27 no.3
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• pp.261-268
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• 2021

Equilibrium, kinetics, and thermodynamics of adsorption of acid black 1 (AB1) by coal-based granular activated carbon (CGAC) were investigated with the adsorption variables of initial concentration of dye, contact time, temperature, and pH. The adsorption reaction of AB1 by activated carbon was caused by electrostatic attraction between the surface (H⁺) of activated carbon and the sulfite ions (SO₃^-) and nitrite ions (NO₂^-) possessed by AB1, and the degree of reaction was highest at pH 3 (97.7%). The isothermal data of AB1 were best fitted with Freundlich isotherm model. From the calculated separation factor (1/n) of Freundlich, it was confirmed that adsorption of AB1 by activated carbon could be very effective. The heat of adsorption in the Temkin model suggested a physical adsorption process (< 20 J mol^-1). The kinetic experiment favored the pseudo second order model, and the equilibrium adsorption amount estimated from the model agreed to that given by the experiments (error < 9.73% ). Intraparticle diffusion was a rate controlling step in this adsorption process. From the activation energy and enthalpy change, it was confirmed that the adsorption reaction is an endothermic reaction proceeding with physical adsorption. The entropy change was positive because of an active reaction at the solid-liquid interface during adsorption of AB1 on the activated carbon surface. The free energy change indicated that the spontaneity of the adsorption reaction increased as the temperature increased.

• Economic and Environmental Geology
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• v.54 no.1
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• pp.61-67
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• 2021

Isotopic compositions of snow or ice have been used to reconstruct paleoclimate and to calculate contribution to streamwater using isotopic hydrograph separation as an end member. During freezing and melting of snow or ice, isotopic fractionation occurs between snow or ice and liquid water. Isotopic evolution during melting process has been studied by field, melting experiments and modeling works, but that during freezing has not been well studied. In this review, isotopic fractionation during equilibrium freezing is discussed using the linear relationship between two stable water isotopes (oxygen and hydrogen) and the Rayleigh fractionation. Snow, evaporated from nearby ocean and condensated, follows the Global Meteoric Water Line (slope of 8), but the melting and freezing of snow affect the linear relationship (slope of 19.5/3.1~6.3). The isotopic evolution of liquid water by freezing observed in the open system during Rayleigh fractionation is also seen in the closed system. The isotopic evolution of snow or ice in the open system where the snow or ice is continuously removed becomes more enriched than the residual liquid water by the fractionation factor. The isotopic evolution of snow or ice in the closed system eventually equals the original isotopic compositions of liquid water. It is expected the understanding of isotopic evolution of snow or ice by freezing to increase the accuracy of the paleoclimate studies and hydrograph separation.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.6A
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• pp.789-798
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• 2008

The stiffness method provides a framework to calculate the structural deformations directly from solving the equilibrium state. However, to use the displacement shape functions leads to approximate estimation of stiffness matrix and resisting forces, and accordingly results in a low accuracy. The conventional flexibility method uses the relation between sectional forces and nodal forces in which the equilibrium is always satisfied over all sections along the element. However, the determination of the element resisting forces is not so straightforward. In this study, a new fiber finite element mixed method has been developed for nonlinear anaysis of steel-concrete composite structures in the context of a standard finite element analysis program. The proposed method applies the Newton method based on the load control and uses the incremental secant stiffness method which is computationally efficient and stable. Also, the method is employed to analyze the steel-concrete composite structures, and the analysis results are compared with those obtained by ABAQUS. The comparison shows that the proposed method consistently well predicts the nonlinear behavior of the composite structures, and gives good efficiency.

• The Journal of Engineering Geology
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• v.23 no.4
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• pp.447-455
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• 2013

A micro-mechanical pipe network model with the shape of a cube was developed to simulate the behavior of fluid flow through a porous medium. The fluid-flow mechanism through the cubic pipe network channels was defined mainly by introducing a well-known percolation theory (Stauffer and Aharony, 1994). A non-uniform flow generally appeared because all of the pipe diameters were allocated individually in a stochastic manner based on a given pore-size distribution curve and porosity. Fluid was supplied to one surface of the pipe network under a certain driving pressure head and allowed to percolate through the pipe networks. A percolation condition defined by capillary pressure with respect to each pipe diameter was applied first to all of the network pipes. That is, depending on pipe diameter, the fluid may or may not penetrate a specific pipe. Once pore pressures had reached equilibrium and steady-state flow had been attained throughout the network system, Darcy's law was used to compute the resultant permeability. This study investigated the sensitivity of network size to permeability calculations in order to find out the optimum network size which would be used for all the network modelling in this study. Mean pore size and pore size distribution curve obtained from field are used to define each of pipe sizes as being representative of actual oil sites. The calculated and measured permeabilities are in good agreement.

• Korean Journal of Soil Science and Fertilizer
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• v.24 no.2
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• pp.109-115
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• 1991

This study examines the effect of submergence on phosphorus adsorption characteristics in Gangseo(paddy soil), Yesan(non-cultivated soil), and Jungdong soil(upland soil). The soils were submerged with glucose sol'n at $28^{\circ}C$ for 17 days. After the submergence, the phosphorus adsorption was conducted at three temperatures(5, 25 and $45^{\circ}C$). The phosphorus adsorption maximum($X_m$) and the equilibrium constant(K) were obtained by Langmuir adsorption isotherm, and the heat of adsorption(${\Delta}H$) was calculated by van't Hoff's equiation. Results obtained are as follows ; 1. The amounts of adsorbed P were increased with temperature, but the effects of temperature on rate of P adsorption were very small in all three soils. 2. By submergence, $X_m$ were increased from 500mg P/kg to 850mg P/kg in Gangseo soil, from 1,850mg P/kg to 3,300mg P/kg in Yesan soil, and from 310mg P/kg to 670mg P/kg in Jungdong soil. But the effects of temperature on $X_m$ were very small in all three soils. 3. Submergence decreased K for Gangseo and Yesan soils, but increased for Jungdong soil. Whereas K were increased with temperature in all three soils. 4. By submergence, ${\Delta}H$ for Gangseo soil was greatly increased (from 2.2 Kcal/mole to 3.5 Kcal/mole), whereas that for Yesan soil changed little (from 5.7 Kcal/mole to 5.5 Kcal/mole). It was 4.4 Kcal/mole in submerged Jungdong soil.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.19 no.6
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• pp.640-646
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• 2008

Design procedure of corrugated horn antenna for the mm-wave frequency range is presented, and hybrid condition in horn is calculated. In this paper, corrugate profiles of horn which satisfy both transition to balanced hybrid condition and fabrication possibility under the mm-wave short wavelength are obtained. Electromagnetic fields inside horn and corrugation are derived by the cylindrical mode theory. Propagation characteristics in the horn are calculated by the mode impedance matching method with boundary conditions, and radiation fields are obtained by the Kirchhoff-Hyugen principle to the horn aperture fields. A mm-wave corrugated horn antenna which operates on $85{\sim}115GHz$ is fabricated by electric forming method. Measurements show that VSWR is under 1.3:1 over whole band and the half power beamwidth on radiation pattern 9.2, 9.16 and 9.02 degree on 85, 100 and 110 GHz are agree well with theoretical calculation.

• Resources Recycling
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• v.23 no.6
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• pp.30-39
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• 2014

The trajectories of PCB(Printed Circuit Board) particles in the corona discharge electrostatic separation was simulated. The PCB particles are prepared by crushing bare board, which disassembled from electronic components, consist mostly of copper and FR-4(Flame Retardant Level-4) Firstly, a model was established for calculating of detachment points of PCB particles from the rotating electrode in separator. The model of detachment points was derived from equilibrium of force such as gravity force, centrifugal force, electrostatic force. The trajectories of particles after detachment was calculated by acceleration derived from time-integrating method of motion equation. In this simulation, particle size, supplied voltage, rotation speed of rotating roll electrode and angle of induction electrode were adopted as variables. While the trajectories of FR-4 particles were affected by all variables, rotation speed of rotating roll electrode was dominant variables affecting trajectories of copper particles.

• Applied Biological Chemistry
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• v.33 no.1
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• pp.18-23
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• 1990

Seven varieties of soybeans(Paldal, Danyeob, Jangbaek, Baegun, Jangyeob and 2 cultivars of Local 1 and Local 2) were investigated to compare the water uptake properties and volume changes during soaking in water. The hydration properties showed that the equilibrated weight increase ratio decreased as the soaking temperature raised to higher than $40^{\circ}C$, while the initial water uptake rate increased upto $80^{\circ}C$. The increase in hydration showed a linear relationship with the square root of the soaking time at $4^{\circ}{\sim}60^{\circ}C$. Local 1 was the highest in water uptake rate constant while Local 2 was the lowest. The activation energy calculated was in the range of $3,246{\sim}4,694\;cal/mole$. The Jangbaek and Local 1 were the highest and the Paldal was the lowest in the rate of volume increase. The activation energy for volume increase was in the range of $3,310{\sim}4,190\;cal/mole$. The z-values calculated from volume change was a little higher than those obtained from weight change.

• Korean Chemical Engineering Research
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• v.43 no.5
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• pp.579-587
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• 2005

Phase separations of Poly(4-vinylphenol)(PVPh)/acetone and PVPh/methyl ethyl ketone solutions were measured using the thermal optical analysis (TOA) method. The phase separations of these system showed the behaviors of LCST-type (lower critical solution temperature). The measured cloud temperatures were lowered with increasing molecular weight of PVPh, and cloud temperatures of PVPh/MEK solutions shifted to higher temperature regions, compared to the PVPh/acetone solutions. Phase equilibria of PVPh/ketone solutions were described with taking account of self-associations of PVPh and cross-associations between PVPh and solvent, by using the PC-SAFT equation of state. PC-SAFT EoS parameters of PVPh and cross-association parameters were determined by simultaneously fitting liquid density data of PVPh and VLE data of the PVPh/acetone system. The estimated parameters of PVPh and cross-association parameters were utilized to calculations of the binodal and spinodal curves, and the calculated binodal curves were in good agreements with the experimental cloud temperatures.

• Journal of the Korean Chemical Society
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• v.30 no.2
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• pp.145-151
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• 1986

Using a new conductometric method, dissociation constants of 3-cyano, 4-cyano, 3-amino and 4-aminopyridine were measured in the temperature range 15 ∼ 40${\circ}C$ and pressure up to 2500bar in aqueous media. This method is convenient to apply to the low dissociative acid and base but have to do tedious extrapolating procedure for the ionic conductance in elaborated temperatures and pressures and have to know any reference dissociation constant. The measured dissociation constants were increased as the temperature increase but decreased as the pressure increase. From the constants, various thermodynamic properties were evaluated and discussed for the dissociation reactions.