• Applied Chemistry for Engineering
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• v.10 no.3
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• pp.456-460
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• 1999

The YHB radial distribution functions of a linear gas molecule CO were calculated by a computer within the Stockmayer molecular potential molel, which assumed thc CO molecule as a simple dipolar molecule. To examine the validity of the obtained YHB radial distribution of CO gas molecule, the density dependent pressures of CO at several temperatures were also calculated. The calculated pressures showed a good agreement with literially known experimental CO pressure data. The temperatures examined were 273, 298, and 373 K and the densities were up to $0.013/{\AA}^3$ (maximum pressure = 1000 atm). Since the calculated pressures showed a good agreement with the experimental values, the obtained YHB radial distribution functions of CO molecule seemed good enough to obtain and predict various equilibrium physical and chemical quantities of CO molecule sensitive to density such as pressure. It was also found that in CO gas system the dipole-dipole interaction is effective up to approximately 2.5 molecular diameter.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.29 no.1
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• pp.53-60
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• 2016

This study discusses the thermal insulation capacity of variant of NO96 LNG (liquefied natural gas) cargo containment insulation system. Changing the insulation materials and the insulation layers of conventional GTT NO96 containment system, The thermal resistance and BOR(boil off rate) caused by the heat transfer between cryogenic and environmental temperature is discussed. Therefore, thermal analysis of LNG CCS(cargo containment system) is carried out to determine the insulation capabilities. Also, BOR is evaluated in terms of the total amount of heat invaded into CCS(cargo containment system). Variant of NO96 CCS such as NO96, NO96GW and NO96L3 membrane type during laden voyage is selected for the comparative study. Finite element model for heat transfer analysis is conducted by employing the equivalent thermal resistance model to simplify the complex insulation layers. Finally the results for each variant model are relatively compared and discussed to minimize the BOR.

• The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.8 no.1
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• pp.37-45
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• 1994

A method of optimal active and reactive power control for economic operation in electrical power system is presented in this paper. The major features and techniques of this paper are as follows: 1) The method presented for obtaining the equivalent active power balance equation applying the sparse Jacobian matrix of power flow equation instead of using B constant as active power Balance equation considering transmission loss, and for determining directly optimal active power allocation without repeating calculations. 2) More reasonable and economic profit by minimizing total fuel cost of thermal power plants instead of using transmission loss as objective function of reactive Power control can be achieved. 3) Particularly in reactive power control, computing time can be considerably reduced by using Fuzzy Linear Programming instead of using conventional Linear Programming.

• Journal of Korean Ophthalmic Optics Society
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• v.7 no.2
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• pp.1-11
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• 2002

A mathematical model is proposed to analyze the force; acting on the hard contact lens fitted on the cornea. The model incorporates the nonlinear equations and their numerical solution program, based on the formulations of surface tension force arising from the capillary action in the tear-film layer between the lens and cornea. The model simulates how the adhesion between lens and cornea varies according to the base curves and diameters of the lenses. When the spherical lens is fitted on the spherical cornea it is to rotate downward due to the weight of lens itself until it reaches an equilibrium position along the cornea where the counter(upward) moment caused by net force between the upper and lower portion of the periphery of lens. It is found that both the adhesion and displacement of lens along the cornea, where the gravity of lens balances the capillary-induced upward force, increases rapidly as the base curve of lens increases, i.e., as the lens gets flatter, while the increase in the diameter of lenses has resulted in the less increase in the rotation and adhesion. With the base curve and diameters of lenses being remained constant the increase in surface tension of tear film yields the increase in the adhesion between the cornea and lens while the initial rotation of lens is inversely proportional to the surface tension of the tear film.

• Applied Chemistry for Engineering
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• v.24 no.2
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• pp.184-189
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• 2013

In the present study, batch experiments were carried out for the utilizatioin of activated carbon as a potential adsorbent to remove a hazardous malachite green from an aqueous solution. The effects of various parameters such as temperature, contact time, initial concentration on the adsorption system were investigated. On the basis of adsorption data Langmuir and Freundlich adsorption isotherm model were also confirmed. The equilibrium process was described well by Langmuir isotherm model. From determined separation factor, the activated carbon could be employed as an effective treatment for removal of malachite green. From kinetic experiments, the adsorption process followed the pseudo second order model, and the adsorption rate constant ($k_2$) decreased with increasing both the initial concentration of malachite green and the adsoprtion temperature. Thermodynamic parameters like that activation energy, change of free energy, enthalpy, and entropy were also calculated to predict the adsorption nature. The activation energy calculated from Arrhenius equation indicated that the adsortpion of malachite green on the zeolite was physical process. The negative Gibbs free energy change ($\Delta$G = -3.68~-7.76 kJ/mol) and the positive enthalpy change ($\Delta$H = +26.34 kJ/mol) indicated the spontaneous and endothermic nature of the adsorption in the temperature range of 298~318 K.

• Journal of Korean Society of Environmental Engineers
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• v.39 no.8
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• pp.462-469
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• 2017

Eutrophication and shortage of phosphate ore raise the necessity of phosphate removal and recovery from wastewater treatment plants. Especially, a sludge treatment system containing highly concentrated phosphate should be targeted for phosphate removal and recovery. This study thus aimed to evaluate the capability of the struvite crystallization process for phosphate removal and recovery from a sludge treatment system of a wastewater treatment plant. Analysis on phosphate concentrations and masses in the sludge treatment system revealed that digested sludge and centrate have phosphate concentrations and masses, high enough to adopt the struvite crystallization process. Chemical equilibrium modeling indicated that the struvite crystallization reaction substantially occurred with pH higher than 8 and $Mg^{2+}$ concentration 1.2 times higher than its theoretical requirement. A series of batch tests with digested sludge and centrate indicated that the phosphate removal reaction by struvite crystallization followed a first-order kinetics and reached over 80% removal efficiency at equilibrium. Aeration in the batch tests was found to purge $CO_2$ in sludge or centrate and increase pH up to 8.7, without adding NaOH. Thus, we concluded that the struvite crystallization process could be an efficient and economical process for phosphate removal and recovery from a wastewater treatment plant.

• Journal of the Korean Society for Marine Environment & Energy
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• v.4 no.4
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• pp.21-31
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• 2001

When an oil-spilling accident occurs at sea, it is of the primary importance to predict the amount of oil leakage for the swift response and decision-making. The simplest method of oil-leakage estimation is based on the hydrostatic pressure balance between oil inside the tank and seawater outside of leakage hole, that is the so-called Torricelli equilibrium relation. However, there exists discrepancy between the reality and the Torricelli relation, since the latter is obtained from the quasi-steady treatment of Bernoulli equation ignoring viscous friction. A preliminary experiment has been performed to find out the oil-leaking speed and shape. Soy-bean oil inside the inner tank was ejected into water of the outer tank through four different leakage holes to record the amount of oil leakage. Furthermore, a CFD (Computational Fluid Dynamics) method was utilized to simulate the experimental situation. The Wavier-Stokes equations were solved for two-density flow of oil and water. VOF method was employed to capture the shape of their interface. It is found that the oil-leaking speed varies due to the frictional resistance of the leakage hole passage dependent on its aspect ratio. The Torricelli factor relating the speed predicted by using the hydrostatic balance and the real leakage speed is assessed. For the present experimental setup, Torricelli factors were in the range of 35%~55% depending on the aspect ratio of leakage holes. On the other hand, CFD results predicted that Torricelli factor could be 52% regardless of the aspect ratio of the leakage holes, when the frictional resistance of leakage hole passage was neglected.

• Applied Chemistry for Engineering
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• v.25 no.1
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• pp.96-102
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• 2014

Adsorption of metanil yellow onto granular activated carbon were studied in a batch system. Various operation parameters such as adsorbent dosage, pH, initial concentration, contact time and temperature were optimized. Experimental equilibrium adsorption data were analyzed by Langmuir and Freundlich adsorption isotherm. The equilibrium process was described well by Freundlich isotherm model. From determined separation factor (1/n), adsorption of metanil yellow by granular activated carbon could be employed as effective treatment method. By analysis of kinetic experimental data, the adsorption process were found to confirm to the pseudo second order model with good correlation and the adsorption rate constant ($k^2$) decreased with increasing initial concentration. Thermodynamic parameters like activation energy, change of free energy, enthalpy, and entropy were also calculated to predict the nature adsorption in the temperature range of 298~318 K. The activation energy was determined as 23.90 kJ/mol. It was found that the adsortpion of metanil yellow on the granular activated carbon was physical process. The negative Gibbs free energy change (${\Delta}G=-2.16{\sim}-6.55kJ/mol$) and the positive enthalpy change (${\Delta}H=+23.29kJ/mol$) indicated the spontaneous and endothermic nature of the adsorption process, respectively.

• Clean Technology
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• v.28 no.3
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• pp.249-257
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• 2022

The adsorption equilibria of nitrogen on a region of nanoporous carbonaceous adsorbent with local molecular orientation (LMO) were calculated by grand canonical Monte Carlo simulation at 77.16 K. Regions of LMO of identical size were arranged on a regular lattice with uniform spacing. Microporosity was predominately introduced to the model by removing successive out-of-plane domains from the regions of LMO and tilting pores were generated by tilting the basic structure units. This pore structure is a more realistic model than slit-shaped pores for studying adsorption in nanoporous carbon adsorbents. Their porosities, surface areas, and pore size distributions according to constrained nonlinear optimization were also reported. The adsorption in slit shaped pores was also reported for reference. In the slit shaped pores, a clear hysteresis loop was observed in pores of greater than 5 times the nitrogen molecule size, and in capillary condensation and reverse condensation, evaporation occurred immediately at one pressure. In the LMO pore model, three series of local condensations at the basal slip plane, armchair slip plane and interconnected channel were observed during adsorption at pore sizes greater than about 6 times the nitrogen molecular size. In the hysteresis loop, on the other hand, evaporation occurred at one or two pressures during desorption.

• Journal of the Korean Society for Railway
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• v.12 no.6
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• pp.944-952
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• 2009

This paper presents an analytical model for calculation of crack widths in reinforced concrete structures. The model is mathematically derived from the actual bond stress-slip relationships between the reinforcement and the surrounding concrete, and the relationships summarized in CEB-FIP Model Code 1990 and Eurocode 2 are employed in this study together with the numerical analysis result of a linear slip distribution along the interface at the stabilized cracking stage. With these, the actual strains of the steel and the concrete are integrated respectively along the embedment length between the adjacent cracks so as to obtain the difference in the axial elongation. The model is applied to the test results available in literatures, and the predicted values are shown to be in good agreement with the experimentally measured data.