• Composites Research
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• v.33 no.6
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• pp.329-335
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• 2020

In this study, the thermo-rheological behaivors of petroleum pitches with different softening points were studied, and a B-stage phenolic resins/petroleum pitches blends were prepared by adding petroleum pitches to the phenolic resins. As a result, the petroleum pitch with different softening points decreased the fluidity of the petroleum pitch as the Quinoline insoluble (QI) content increased and showed the viscous properties of the solid. In addition, the effect of adding petroleum pitches having different softening points on the thermo-rheological properties of phenolic resins was investigated. When petroleum pitch with a high softening point was added, the fluidity of the phenolic resin was reduced, and the hardening behavior was fast. It was possible to control the curing rate and curing behavior of the phenolic resin by adding petroleum pitches of different softening points. Among them, the phenolic resin mixture to which P-Pitch 2 was added has a higher fluidity than other blends under the same curing temperature condition.

• Korean Journal of Food Science and Technology
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• v.45 no.1
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• pp.84-89
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• 2013

We investigated the effects of extracts from dried Platycodon grandiflorum on total phenolic content and growth of cancer cell lines (HT-29 and AGS). Total phenolic contents of acetone/methylene chloride (A+M) extract and methanol (MeOH) fraction were 4.53 and 27.22 TAE mg/100 g, respectively. Among the fractions, n-butanol (n-BuOH) fraction contained the highest phenolic content. Treatments of crude extracts and fractions significantly inhibited the growth of HT-29 and AGS cancer cell lines (p<0.05). Among the fractions, n-BuOH fraction exhibited the highest inhibitory effect and was then sub-fractionated by reverse phase flash column chromatography (rfc). The rfc 1-3 exhibited a higher inhibitory effect on proliferation of both cancer cells. The rfc 1 contained the highest phenol content. Our results showed that n-BuOH fraction possessed a potent inhibitory effect on proliferation of human cancer cells. We suggested that this anticancer activity was partially related to the content of phenolic compounds.

• Journal of the Korean Chemical Society
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• v.24 no.5
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• pp.337-341
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• 1980

Radical formation reaction of phenolic antioxidants were examined MO theoretically. Results show that substitution of electron-donating alkyl groups in phenol increases the rate of phenoxy radical formation when attacked by an electrophilic radical by stabilization of cationic transition state.

• Journal of Adhesion and Interface
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• v.21 no.4
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• pp.156-161
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• 2020

Waterborne pressure sensitive adhesives (PSA) has been received much attentions from both academia and industries as an environmental friendly-technology because it can significantly reduce use of hazardous organic volatile solvents. However, in the process of the mass production of waterborne PSAs, hazardous phenol type amphiphilic compounds have essentially been used as surfactants for the emulsion polymerization. For the reason, tremendous research efforts have been made to develop environment-friendly organic surfactant which can replace the phenol type surfactants. In this study, we verify the potential of a new class of surfactants based on the styrenated phenol derivatives as an alternative to the phenol type surfactants.

• Korean Journal of Materials Research
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• v.6 no.10
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• pp.986-990
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• 1996

본 논문에서는 정속마찰 시험기를 사용하여 공기중에서 핏치/CVI계와 페놀/CVI계 낱소/탄소 복합재료의 마찰특성을 평가하고 상호 비교하였다. 운용조건(마찰거리, 마찰속도, 마찰압력)에 관계없이 페놀/CVI계의 평균 마찰계수가 핏치/CVI계 보다 높은 값을 나타내었다. 마찰거리가 4Km이하 일때는 평균 마찰계수가 불안정한 경향을 나타내고 그 이후에서는 안정한 평균 마찰계수 값을 갖는다. 또한 마찰속도와 마찰압력이 증가할수록 평균 마찰계수는 감소하는 경향을 나타내며, 페놀/CVI계의 평균 마찰계수가 핏치/CVI계 보다 높고 마찰면 온도 상승률과 최대 마찰면 온도도 높다. 마찰계수는 마찰면 온도의 영향을 받으며, 마찰속도와 3kg/$\textrm{cm}^2$이하에서 마찰압력이 커질수록 최대 마찰계수를 갖는 마찰면 온도는 높아진다.

• Proceedings of the Korean Fiber Society Conference
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• 2003.04a
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• pp.432-433
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• 2003

미생물의 침해로부터 인체와 섬유제품을 보호하기 위하여 사용되는 항균 가공제로는 아민 또는 제4급 암모늄계, biguanide계, 알코올계, 페놀계, 알데하이드계 등의 유기계, 금속 이온 무기계, 산화물 및 광 촉매계, 유기 무기계, 천연 화합물 둥이 사용되고 있다[1-2]. 이러한 항미생물 가공제는 우수한 살균력, 섬유제품의 고유한 성질을 변화시키지 않는 특성, 탁월한 세탁 내구성, 인체에 대한 무독성 등의 조건을 가져야 한다[2-3]. (중략)

• Proceedings of the Korean Fiber Society Conference
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• 2003.10b
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• pp.88-91
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• 2003

미생물의 침해로부터 인체와 섬유제품을 보호하기 위하여 사용되는 항균 가공제로는 아민 또는 제4급 암모늄계, biguanide계, 알코올계, 페놀계, 알데하이드계 등의 유기계, 금속 이온 무기계, 산화물 및 광 촉매계, 유기 무기계, 천연 화합물 등이 있다[1,2]. 이러한 항미생물 가공제는 우수한 살균력, 섬유제품의 고유한 성질을 변화시키지 않는 특성, 탁월한 세탁 내구성, 인체에 대한 무독성 등의 조건을 가져야 한다[2,3]. (중략)

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.47 no.6
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• pp.414-421
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• 2019

In this paper, thermomechanical coupled analysis of carbon/phenolic composites structures in reentry environment was performed. The interface of thermomechanical coupled analysis was constructed using commercial software. The governing equations of temperature and displacement fields were considered to simulate change of physical behavior due to pyrolysis and ablation effects. The results of thermomechanical coupled analysis were compared with the results of ablation test using arc-heated wind tunnel. Also, the structural stability of reentry capsule was analyzed using the analysis interface. The excellent ablation characteristics and thermal protection effects of the carbon/phenolic composites were confirmed and the constructed analysis interface can be effectively used to perform thermal protection system design.

• Journal of Soil and Groundwater Environment
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• v.10 no.5
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• pp.45-51
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• 2005

The sorption/desorption characteristics of phenanthrene on the natural manganese oxide (NMD) were investigated in the presence of phenolic compounds. 4-chlorophenol (4-CP) was effectively oxidized by NMD catalyzed reaction and transformed into humic-like macromolecular compound through inter-or cross-coupling reaction between byproducts. As 4-CP was degraded with time, sorbed amount of phenanthrene on NMD was significantly increased, resulting from the formation of oxidative coupling products. These results imply that NMD can be used for simultaneous treatment of phenolic contaminants and polycyclic aromatic hydrocarbons (PAHs) in soils, sediments, or water. Also, sorbed phenanthrene on NMD in the presence of 4-CP showed high degree of desorption resistance, indicating that sequestration process of phenanthrene was ongoing with time.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1999.05a
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• pp.146-149
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• 1999

Langmur-Blodgett (LB) method has a unique characteristic of making molecularly mutilayered aggregation structures. LB method makes the thickness of organic insulation layer controllable at molecular scale in various electronic devices. In this study, the organic materials applicable to crosslinked LB insulation layers of electronic devices have developed and the electrical properties of their LB films have examined such as Brewster angle microscopy(BAM), Scanning Maxwell-stress microscopy(SMM), and Current-voltage(1-V) properties.