• Korean Chemical Engineering Research
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• v.60 no.3
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• pp.327-333
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• 2022

In this study, silicon/carbon nanotube/carbon (Si/CNT/C) composites for anode were prepared to improve the volume expansion of silicon used as a high-capacity anode material. Si/CNT were prepared by electrostatic attraction of the positively charged Si and negatively charged CNT and then hydrothermal synthesis was performed to obtain the spherical Si/CNT/C composites. Poly(vinylidene fluoride) (PVDF), polyacrylic acid (PAA), and styrene butadiene rubber (SBR) were used as binders for electrode preparation, and coin cell was assembled using 1.0 M LiPF₆ (EC:DMC:EMC = 1:1:1 vol%) electrolyte and fluoroethylene carbonate (FEC) additive. The physical properties of Si/CNT/C anode materials were analyzed using SEM, EDS, XRD and TGA, and the electrochemical performances of lithium-ion batteries were investigated by charge-discharge cycle, rate performance, dQ/dV and electrochemical impedance spectroscopy tests. Also, it was confirmed that both capacity and rate performance were significantly improved using the PAA/SBR binder and 10 wt% FEC-added electrolyte. It is found that Si/CNT/C have the reversible capacity of 914 mAh/g, the capacity retention ratio of 83% during 50 cycles and the rate performance of 70% in 2 C/0.1 C.

• Composites Research
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• v.36 no.2
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• pp.132-139
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• 2023

A linerless composite propellant tank was designed and manufactured by using the carbon fiber-reinforced composite materials which have superior strength-to-weight ratio in order to reduce weight of the tank. In this research, we designed a sub-scale composite propellant tank with a diameter of 800 mm to withstand an MEOP of 1.7 MPa. We manufactured the boss of the tank by using the same composite materials to reduce the thermal expansion difference between the boss and the secondary-bonded composite layers of the barrel in the cryogenic environment. We used the collapsible mandrel to manufacture the tank without any liner. The mandrel was made from epoxy-based composite tooling prepregs to reduce weight of the mandrel. We manufactured the test tanks by laying up the carbon fiber fabric prepregs manually on the mandrel and then applying the autoclave cure process. We performed a proof test, a helium tightness test, a repeated pressurization test, and a burst test in room temperature. The test results demonstrate that the proposed design and manufacture process satisfies all strength requirements as well as an anti-leakage requirement.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.5
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• pp.618-625
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• 2018

With the passing of time, exposed concrete structures are affected by a range of environmental, chemical, and physical factors. These factors seep into the concrete and have a deleterious influence compared to the initial performance. The importance of identifying and preventing further performance degradation due to the occurrence of deterioration has been greatly emphasized. In recent years, evaluations of the target life have attracted increasing interest. During the freezing-melting effect, a part of the concrete undergoes swelling and shrinking repeatedly. At these times, chloride ions present in seawater penetrate into the concrete, and accelerate the deterioration due to the corrosion of reinforced bars in the concrete structures. For that reason, concrete structures located onshore with a freezing-melting effect are more prone to this type of deterioration than inland structures. The aim of this study was to develop a high performance mortar mixed with a mineral admixture for the durability properties of concrete structures near sea water. In addition, experimental studies were carried out on the strength and durability of mortar. The mixing ratio of the silica fume and meta kaolin was 3, 7 and 10 %, respectively. Furthermore, the ultra-fine fly ash was mixed at 5, 10, 15, and 20%. The mortar specimens prepared by mixing the admixtures were subjected to a static strength test on the 1st and 28th days of age and degradation acceleration tests, such as the chloride ion penetration resistance test, sulfuric acid resistance test, and salt resistant test, were carried out at 28 days of age. The chloride diffusion coefficient was calculated from a series of rapid chloride penetration tests, and used to estimate the life time against corrosion due to chloride ion penetration according to the KCI, ACI, and FIB codes. The life time of mortar with 10% meta kaolin was the longest with a service life of approximately 470 years according to the KCI code.

• Journal of Korean Tunnelling and Underground Space Association
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• v.19 no.1
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• pp.11-27
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• 2017

The road network system of major domestic urban areas such as city of Seoul was rapidly developed and regionally expanded. In addition, many kinds of life-lines such as electrical cables, telephone cables, water&sewerage lines, heat&cold conduits and gas lines were needed in order for urban residents to live comfortably. Therefore, most of the life-lines were individually buried in underground and individually managed. The utility tunnel is defined as the urban planning facilities for commonly installing life-lines in the National Land Planning Act. Expectation effectiveness of urban utility tunnels is reducing repeated excavation of roads, improvement of urban landscape; road pavement durability; driving performance and traffic flow. It can also be expected that ensuring disaster safety for earthquakes and sinkholes, smart-grind and electric vehicle supply, rapid response to changes in future living environment and etc. Therefore, necessity of urban utility tunnels has recently increased. However, all of the constructed utility tunnels are cut-and-cover tunnels domestically, which is included in development of new-town areas. Since urban areas can not accommodate all buried life-lines, it is necessary to study the feasibility assessment system for utility tunnel by urban patterns and capacity optimization for urban utility tunnels. In this study, we break away from the new-town utility tunnels and suggest a quantitative assessment model based on the evaluation index for urban areas. In addition, we also develop a program that can implement a quantitative evaluation system by subdividing the feasibility assessment system of urban patterns. Ultimately, this study can contribute to be activated the urban utility tunnel.

• Magazine of the Korea Concrete Institute
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• v.7 no.3
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• pp.199-210
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• 1995

We could say that the concrete filled steel tube structure is superior in the vlew of various structure properties as to promote improvement of structural capacity to dtmonstrate heterogeneous material properties interdependently. The compressive strength is increased by putting to tri axial stress because lateral expansion of concrete 1s confined by the steel tube, when concrete conflned by steel tube fall under centric axial load. Also, it have an advantage that decreasr of load carrying capacity 1s small, not occuring section deficiency due to protect falling piienornonon by co~nprrssion fallurc of concrete. So this study investigated for structural behaviors yroprrtiex of concwir. confined by steel tube throughout a series of experlmerit with kcy parxncter, such as diameter-to-thickness(D / t) ratio, strength of concrete as a study on properties of structural behaviors of confined concrete confined by circular steel tube( tri axial stress). Frorn the expcrment results, the obtained results, are surnrnarised as foliow. (1) The restraint effect of concrete by steel tube was presented significantly as the D /t ratio of steel tube and the strength of filled concrete decrease, and the confined concrete by circular steel tube was increased respectively twice as much as 4-7 in deformation capacity at the ultimate strength ,compared with those of non-confined concrete, so expected to increase flexible effect of concrete. (2) The emprical formula to predict the ultimate capacity of confined concrete by steel tube and concrete filled steel tube column using restraint coefficient of concrete were proposed.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.33 no.5
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• pp.1765-1775
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• 2013

The application of FRP wire as a mean of improving strength and ductility capacity of concrete cylinders under axial compressive load through confinement is investigated experimentally in this study. An experimental investigation involves axial compressive test of three confining amounts of FRP wire and three concrete compressive strengths. The effectiveness of FRP wire confinement on the concrete microstructure were examined by evaluating the internal concrete damage using axial, circumferential, and volumetric strains. The axial stress-strain relations of FRP wire confined concrete showed bilinear behavior with transition region. It showed strain-hardening behavior in the post-cracking region. The load carrying capacity was linearly increased with increasing of the amount of FRP wire. The ultimate strength of the 35 MPa specimen confined with 3 layer of FRP wire was increased by 286% compared to control one. When the concrete were effectively confined with FRP wire, horizontal cracks were formed by shearing. It was developed from sudden expansion of the concrete due to confinement ruptures at one side while the FRP wire was still working in hindering expansion of concrete at the other side of the crack. The FRP wire failure strains obtained from FRP wire confined concrete tests were 55~90%, average 69.5%, of the FRP wire ultimate uniaxial tensile strain. It was as high as any other FRP confined method. The magnitude of FRP wire failure strain was related to the FRP wire effectiveness.

• Economic and Environmental Geology
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• v.45 no.2
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• pp.79-88
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• 2012

The increased brightness and focused X-ray beams now available from laboratory X-ray sources facilitates a variety of powder diffraction experiments not practical using conventional in-house sources. Furthermore, the increased availability of 2-dimensional area detectors, along with implementation of improved software and customized sample environmental cells, makes possible new classes of in-situ and time-resolved diffraction experiments. These include phase transitions under variable pressure- and temperature conditions and ion-exchange reactions. Examples of in-situ and time-resolved studies which are presented here include: (1) time-resolved data to evaluate the kinetics and mechanism of ion exchange in mineral natrolite; (2) in-situ dehydration and thermal expansion behaviors of ion-exchanged natrolite; and (3) observations of the phases forming under controlled hydrostatic pressure conditions in ion-exchanged natrolite. Both the quantity and quality of the in-situ diffraction data are such to allow evaluation of the reaction pathway and Rietveld analysis on selected dataset. These laboratory-based in-situ studies will increase the predictability of the follow-up experiments at more specialized beamlines at the synchrotron.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.5
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• pp.431-439
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• 2013

A cooling system is adopted to control the thermal load from the avionic equipments in an aircraft for stable operation. In this study, an avionic cooling system was designed and manufactured by adopting a vapor compression cycle with a closed-loop air-circulation system to investigate the operating characteristics of an alternative refrigerant. The performance characteristics of a cooling system adopting R236fa as an alternative refrigerant were experimentally determined by varying the refrigerant charging amount, expansion valve opening, and compressor rotation speed. The experimental results were analyzed and compared with those of a cooling system adopting R124 as a refrigerant. The possibility of the adoption of R236fa as an alternative refrigerant was verified, and design solutions were suggested to improve the system efficiency.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.2
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• pp.719-725
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• 2017

Frozen milk products are commonly made in small refrigeration machines. R-502 has long been used as a refrigerant for soft ice cream machines, but it is being replaced with R-404A due to the issue of ozone layer depletion. However, R-404A has high global warming potential, so it also needs to be replaced. In this study, a mixture of R-290 and R-32 was considered as a new refrigerant. An optimization and performance evaluation of the mixture were conducted for a freezer volume of 2.8 liters. The focus of the optimization was the appropriate refrigerant charge and the opening of the expansion valve. At the optimized conditions, ice cream was produced in 6 minutes and 24 seconds with the mixture, and the COP was 0.83. For R-404A, the ice cream production time was 6 minutes and 22 seconds, and the COP was 0.90. The results may be used for the design of food refrigeration machines and to optimize other refrigeration cycles.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.2
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• pp.697-703
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• 2017

This paper examines the flexure behavior of FRP-concrete composite structure that can replace conventional reinforced concrete structure types. In order to investigate the structural performance and behavioral characteristics in numerical analysis means, ABAQUS, a general purpose finite element analysis program, was utilized for nonlinear finite element analysis, and the various variables and their influences were analyzed and compared with experimental results to suggest values optimized to this composite structure. The concrete damage plasticity model and Euro code for concrete were used. In the implicit finite element analysis, the convergence was ambiguous when geometrical and material nonlinearity were large, so the explicit finite element analysis used in this study was deemed to be appropriate. From the comparison with the experiment about concrete damaged plasticity model, 20mm for the mesh size, $30^{\circ}$ for the dilation angle, $100Nmm/mm^2$ for the value of fracture energy, 0.667 for Kc value, and the consideration of damage parameter were suggested believed to be appropriate. The numerical model suggested in this study was able to imitate the ultimate load and cracking pattern very well; therefore, it is expected to be utilized in research of various new material composite structures.