• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.52-56
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• 2004

이 연구는 유류에 오염된 토양의 복원과정에서 적용된 열탈착 공법의 타당성과 효율적인 운전을 위해 수행되었다. 여러 열탈착공법 중 로터리킬른을 이용한 저온열탈착 공정을 도입하여 실험하였으며 이와 더불어 토양의 TGA 실험 등을 통해 오염토양의 기본적인 특성을 살펴보았다. 대상 시료는 오염현장에서 채취하였고 sand 와 silt의 두 가지 토양을 가지고 실험하였다. TGA 실험결과 대부분의 유류가 200～30$0^{\circ}C$에서 제거됨을 알 수 있고 40$0^{\circ}C$ 이상에서는 토양내의 유기물질이 탈착됨을 알 수 있었다. 로터리 킬른을 이용한 열탈착 실험에서는 적용온도 30$0^{\circ}C$, 체류시간 7.4분에서 sand 97.4%, silt 94.2%의 제거효율을 40$0^{\circ}C$ 이상에서는 99%이상 탈착되었다.

• Applied Chemistry for Engineering
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• v.17 no.2
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• pp.201-209
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• 2006

Various desorption methods were investigated for an activated carbon and zeolite 13X packed bed after benzene adsorption. Desorption experiments using hot steam, purge gas, and evacuation were performed. As a result, the desorption with hot steam showed the best performance. Hot steam makes the temperature in the adsorption column increase and gives arise to the desorption. Drying process should be accompanied to increase the efficiency because steam vapor prevents the adsorption later. The vacuum desorption showed poor performance and it reveals that temperature swing operation is more effective than pressure swing operation. In the purge gas desorption, good performance was achieved using evacuation.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.3
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• pp.547-556
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• 2000

A study have been conducted for the adsorption and desorption characteristics of Cu ion using manganese nodule as adsorbent. For 100 ppm Cu ion solution, the adsorbed amount of Cu ion was more than 90 % at equilibrium state. Adsorption was equilibrated in 42 hours the adsorption reaction was shown to be first order reaction. For the desorption reaction of Cu ion in the region of solution pH 3.5~9.5, the desorption was completed in the acidic region, but it has been decreased as the pH was raised. Also, the desorption rate was higher in the acidic region compared with alkaline region. The desorbed amount was decreased as the reaction temperature increased, therefore, the desorption reaction was thought to be exothermic. Also, several thermodynamic properties were calculated based on experimental results and compared with theoretically driven values. To see the effect of complexing agent on the desorption of Cu ion, EDTA was introduced and the des orbed amount increased in the presence of EDTA.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2005.11a
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• pp.97-98
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• 2005

본 연구결과 흡${\cdot}$탈착공정에서 완충물질인 Q-vesol 경우 흡${\cdot}$탈착능력은 고농도 benzene일 경우, 85 wt%, 95 wt% 보였으며, 고농도 hexane일 경우 81 wt%, 96 wt%의 흡${\cdot}$탈착효율을 보여 저농도 VOCs 경우 보다 흡${\cdot}$탈착 능력이 우수함 을 알 수 있었다. 그리고 hexane보다 benzene 이 흡착반응이 빠름을 알 수 있었으며 또한 탈착 반응은 현저히 느리다는 것을 본 실험연구 결과 알 수 있었다. 이것은 흡${\cdot}$탈착공정에서 Q-vesol 경우, 완충효과가 우수한 것으로 확인되었다.

• Journal of Korea Soil Environment Society
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• v.4 no.2
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• pp.137-147
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• 1999

Fluidized-bed thermal desorber coupled with a heat pipe was investigated for the remediation of soil contaminated with diesel oils. Thermal gravimetric analysis by Cahn-balance indicated that the desorption of diesel oils from the soil particles was mainly governed by the internal diffusion at low concentration of less than 0.5 wt. % of oils in the soil particles. In fluidized-bed experiments. increase of fluidizing gas velocity reduced the residual oils of the contaminated soils, the increase of soil feed rate decreased efficiency of fluidized-bed desorber. A mathematical model was developed by incorporating Fickian diffusion kinetics into the Kunii-Levenspiel model Simulation results showed reasonable agreement for the performance of fluidized-bed thermal desorber.

• Korean Chemical Engineering Research
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• v.48 no.6
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• pp.768-775
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• 2010

Adsorption dynamics of ethane/ethylene mixture gas and desorption dynamics during the displacement desorption with propane as a desorbent in the column filled with faujasite adsorbent were investigated experimentally and theoretically. The simulation that adopted heat and mass balance and an ideal adsorbed solution theory (IAST) for the multicomponent adsorption equilibrium well predicted the experimental breakthrough curves of the adsorption and desorption. At the adsorption breakthrough experiments, roll-ups of ethane increased as the adsorption pressure increased and the adsorption temperature decreased. During the displacement desorption with propane in the column saturated with ethane/ethylene mixture gas, almost 100% of ethylene was obtained for a certain time interval. The adsorption strength of the desorbent greatly affected the adsorption and re-adsorption dynamics of ethylene. The re-adsorption capacity for ethylene has been greatly reduced when iso-propane, which is stronger desorbent than propane, was used as desorbent. It was found from the simulation that the performance of the displacement desorption process would be superior when the ratio of ${(q_s{\times}b)}_{C_2H_4}/{(q_s{\times}b)}_{C_3H_s}$ was 0.83, that is, the adsorption strengths of ethylene and the desorbent were similar.

• Journal of the Korean GEO-environmental Society
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• v.15 no.12
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• pp.61-69
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• 2014

Carboxymethyl-${\beta}$-cyclodextrin (${\beta}$-CMCD), as a biodegradable surfactant with hydrophobic and hydrophilic properties, has potential advantages of being applicable to the simultaneous treatment of multiple contaminated soils. In this study, the desorption behaviors of r adionuclides such as cobalt (Co), strontium (Sr), and cesium (Cs) from the soil contaminated with them were experimentally investigated and the effectiveness of CMCD as a desorbent was evaluated. The desorption equilibrium of used radionuclides could be achieved within 1~3 hr and the desorption ratio from kaolin was higher than that from natural soil. The addition of CMCD of 2 g/L increased the desorption ratio by 5~20 % and the desorption ratio of used r adionuclides was shown in the order of Co > Cs > Sr. The experimental desorption data were fitted successfully by pseudo-second order kinetic model and the desorption rate of the r adionuclides was shown in the order of Cs > Co > Sr. Hysteresis between adsorption and desorption of the r adionuclides, as shown in the order of Sr > Co > Cs, increased as the desorption rate decreased. Consequently, it could be considered that the desorption rate was one of the significant factors of the hysteresis. The addition of CMCD as desorbent increased the amount of desorbed radionuclides and decreased the hysteresis. However, the CMCD could not completely desorb the radionuclides from soils even though the excess of CMCD was added.

• Clean Technology
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• v.19 no.3
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• pp.347-350
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• 2013

Desorption characteristics for ions adsorbed onto sericite was performed by means of $HNO_3$ solution which was selected as the best desorbing agent in the previous work. Elution of nickel ions adsorbed onto sericite using $HNO_3$ solution was confirmed by means of scanning electron microscopy (SEM) & energy dispersive X-ray spectroscopy (EDX) analysis. Desorption efficiency for nickel ions was 100% at the 20 mM of concentration. Also, nickel ions was completely desorbed within 1.0 of S/L (mg/mL) ratio which is defined as the ratio of adding amount of adsorbent and volume of desorbing agent and desorption process was quickly carried out within 60min. Finally, removal efficiency of reused sericite for nickel ions was constantly maintained until the 4th cycle.

• Clean Technology
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• v.12 no.4
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• pp.217-223
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• 2006

The operating variables of a desorption step were experimentally investigated tor the cycle of the process made up of benzene adsorption, steam desorption, and drying step. The effect of adsorbent regeneration depending on existence and nonexistence of drying step was studied by breakthrough curves obtained in the adsorption step of the second cycle. The duration of drying step was determined by the experimental results. In case that the amount of nitrogen gas was fixed, the regeneration efficiency increased with the amount of steam. However, the effect of steam decreased as the amount of nitrogen increased. Therefore, it would be possible to predict the optimum amount of steam comparing the amount of nitrogen gas with amount of steam in economic view.

• Journal of Korean Society of Environmental Engineers
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• v.38 no.11
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• pp.627-634
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• 2016

We investigated the characteristics of heavy metal desorption and recovery from carbon foam after plating wastewater treatment. The heavy metal desorption depends on solution chemistry because desorption occurred in HCl and $H_2SO_4 $ solution but did not occur in distilled water. Heavy metal desorption efficiency was increased using ultrasonication with desorption solution. The higher ultrasonic power and the longer reaction time improve efficiency. The copper plating rinse solution was treated reliably by carbon foam adsorbent during 200 bed volume. The adsorbed copper was dissolved using desorption solution and recovered by DC power supply. After copper recovery, the reuse efficiency of desorption solution was 84.2%.