• Title/Summary/Keyword: 탈이온수

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Effects of Low Pressure and Atmospheric Pressure Plasma Treatment on Contact Angle of Polycarbonate Surface (저압 및 대기압 플라즈마 처리를 통한 폴리카보네이트의 접촉각 변화특성 비교)

  • Won, Dong Su;Kim, Tae Kyung;Lee, Won Gyu
    • Applied Chemistry for Engineering
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    • v.21 no.1
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    • pp.98-103
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    • 2010
  • The effect of plasma treatment on surface characteristics of polycarbonate (PC) films was investigated using low pressure plasma and atmospheric pressure plasma with oxygen and argon. Untreated PC has a contact angle of $82.31^{\circ}$ with de-ionized water which reduced to $9.17^{\circ}$ as the lowest value after being treated with a low pressure plasma treatment with oxygen. Increase of delivered powers such as RF and AC with a high frequency and gas flow rates was not effective to reduce contact angles dramatically but gave the trend of reducing gradually. The surface of PC treated with plasma shows a low contact angle but the contact angle increases rapidly according to the exposure time in air ambient. Oxygen plasma was more effective to generate the polar functional group regardless of the type of plasma. Conclusively, a low plasma treatment with oxygen is more recommendable when the hydrophilic surface of PC is required.

Characteristics of Electroosmotic Pump with Cylindrical Porous Glass Frits (원통형 다공성 유리막을 이용한 전기삼투 펌프의 연구)

  • Kwon, Kil-Sung;Kim, Dae-Joong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.6
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    • pp.619-624
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    • 2012
  • In this study, we demonstrated the operation of an electroosmotic pump with cylindrical porous glass frits and evaluated its long-term operation. The performance of this electroosmotic pump was characterized in terms of maximum flow rate, current, and pressure using deionized water and 1 mM borate buffer. The maximum flow rate, current, and pressure linearly increase with voltage. The maximum flow rate is normalized by the pumping area and voltage for comparison of the performance between the electroosmotic pumps with cylindrical and planar frits. The normalized maximum flow rate of the cylindrical-type pump is higher than that of the planar-type pump because of their different geometries. The cylindrical-type electroosmotic pump has five times better performance than the planartype electroosmotic pump for a given pump package volume. It can operate stably for over 3 hours.

The $Pb^{2+}$ Ion Affinitive Membrane Electrode Based on New Calix[4]arene Ionophore (새로운 캘릭스[4]아렌 유도체를 이용한 $Pb^{2+}$ 이온 친화성 막전극)

  • Kim, Eun Jin;Kim, Min Kyu;Nam Gung, Mi Ok;Paek, Kyung Soo;Yun, Young Ja
    • Journal of the Korean Chemical Society
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    • v.42 no.5
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    • pp.531-538
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    • 1998
  • The ion selective membrane electrode made of calix[4]arene-based host 1 as ionophore, poly (vinyl chloride) (PVC) as matrix and dioctylsebacate (DOS) as a plasticizer was studied. The potential responses of this membrane electrode to alkali, alkaline earth and transition metal cations were investigated. Especially this membrane electrode was turned out to be affinitive for $Pb^{2+}$ in the deionized water. It was observed that the response was linear in the concentration range from $1.0 \times 10^{-1} M to 1.0 \times 10^{-6} M of Pb^{2+}$ and its slope (26.5 mV/decade) was near to the sub-Nernstian response in deionized water. Also, the potential was maintained constantly in the range of pH $4.00 \sim 12.00$, which supports the potential usage as $Pb^{2+}$ affinitive electrode in the deionized water.

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Influence of D.I. Water Pressure and Purified $N_2$ Gas on the Inter Level Dielectric-Chemical Mechanical Polishing Process (탈이온수의 압력과 정제된 $N_2$ 가스가 ILD-CMP 공정에 미치는 영향)

  • Kim, Sang-Yong;Seo, Yong-Jin;Kim, Chang-Il;Chung, Hun-Sang;Lee, Woo-Sun;Chang, Eui-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.04b
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    • pp.31-34
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    • 2000
  • It is very important to understand the correlation of between inter layer dielectric(ILD) CMP process and various facility factors supplied to equipment system. In this paper, the correlation between the various facility factors supplied to CMP equipment system and ILD CMP process were studied. To prevent the partial over-polishing(edge hot-spot) generated in the wafer edge area during polishing, we analyzed various facilities supplied at supply system. With facility shortage of D.I. water(DIW) pressure, we introduced an adding purified $N_2(PN_2)$ gas in polishing head cleaning station for increasing a cleaning effect. DIW pressure and PN2 gas factors were not related with removal rate, but edge hot-spot of patterned wafer had a serious relation. We estimated two factors (DIW pressure and PN2 gas) for the improvement of CMP process. Especially, we obtained a uniform planarity in patterned wafer and prohibited more than 90% wafer edge over-polishing. In this study, we acknowledged that facility factors supplied to equipment system played an important role in ILD-CMP process.

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Inverse Emulsion Polymerization of Water Absorbent Polymer for Strength Enhancement of Mortars (모르타르 강도 증진을 위한 고분자 흡수제의 역유화 중합)

  • Hwang, Ki-Seob;Jung, Myoung-Geun;Jang, Seok-Soo;Jung, Yong-Wook;Lee, Seung-Han;Ha, Ki-Ryong
    • Polymer(Korea)
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    • v.34 no.5
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    • pp.434-441
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    • 2010
  • Sodium polyacrylate (PAANa) was synthesized by inverse emulsion polymerization method to absorb excess water in concrete. Liquid paraffin was used as a continuous phase. Acrylic acid (AA) was neutralized by aqueous sodium hydroxide solution (8 M). Different amount of N,N'-methylene bisacrylamide (MBA) was used as a crosslinking agent to change crosslinking density of the synthesized PAANa. The size distribution of synthesized particles was measured by particle size analyzer. Swelling ratio of crosslinked PAANa was evaluated from the equation in D. I. water, cement aqueous solution, and $Ca(OH)_2$ aqueous solution. The FTIR spectroscopy was used to characterize $Ca^{2+}$ ion interaction with PAANa. Incorporation of 1.0 wt% PAANa into cement increased compressive and flexural strength approximately 30% and 10%, respectively, compared with those of ordinary portland cement.

Study of the Internal Flow and Evaporation Characteristic Inside a Water Droplet on a Vertical Vibrating Hydrophobic Surface (수직 진동을 이용한 가열된 고체표면 위 증발하는 액적의 내부유동 제어연구)

  • Park, Chang-Seok;Lim, Hee-Chang
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.1
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    • pp.37-46
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    • 2017
  • Thermal Marangoni flow has been observed inside droplets on heated surfaces, finally resulting in a coffee stain effect. This study aims to visualize and control the thermal Marangoni flow by employing periodic vertical vibration. The variations in the contact angle and internal volume of the droplet as it evaporates is observed by using a combination of continuous light and a still camera. With regard to the internal velocity, the particle image velocimetry system is applied to visualize the internal thermal Marangoni flow. In order to estimate the internal temperature gradient and surface tension on the surface of a droplet, the theoretical model based on the conduction and convection theory of heat transfer is applied. Thus, the internal velocity increases with an increase in plate temperature. The flow directions of the Marangoni and gravitational flows are opposite, and hence, it may be possible to control the coffee stain effect.

Study on the Pattern of Internal Flow inside a water droplet placed on Vibrating Hydrophobic Surface (진동하는 소수성 표면 위에 놓인 액적의 모드별 내부유동 패턴변화에 관한 연구)

  • Kim, Hun;Shin, Young Sub;Lim, Hee Chang
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.4
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    • pp.329-335
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    • 2014
  • This study aimed to understand the internal flow characteristics of a liquid droplet subject to periodic forced vibration. In order to predict the resonance frequency of a droplet, a high-speed camera and macro lens were used to capture internal flow characteristics of a droplet placed on a vibrating hydrophobic surface. Results showed that the droplet assumed a variety of shapes depending on the resonance mode of free droplet, particularly in modes 2, 4, 6, and 8. In addition, the induced internal vortex flow inside the droplet was also observed in each mode. Typically, the induced flow moved upwards along the axis of symmetry and downwards along the surface of the droplet, that is, from the apex to the contact line in modes 2 and 4, after which it broke into a smaller vortex. On the other hand, the large-scale vortex always remained steady in modes 6 and 8. The speed of the flow in mode 4 was always greater than that in mode 2, but those in modes 6 and 8 were similar.

The Effect of Draw Solution Concentration on Forward Osmosis Desalination Performance Using Blended Fertilizer as Draw Solution (유도용액으로 혼합비료를 사용한 정삼투식 해수담수화에서 담수화 성능에 대한 유도용액 농도의 영향)

  • Jeong, Namjo;Kim, Seung-Geon;Kim, Dong Kook;Lee, Ho-Won
    • Membrane Journal
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    • v.23 no.5
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    • pp.343-351
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    • 2013
  • This study is to investigate the effects of the draw solution concentration on forward osmosis desalination performance using blended fertilizer as draw solution. As the concentration of blended fertilizer solution (draw solution) increased, the water permeate flux increased nearly linearly, but PR (performance ratio) was reduced. Using sea water and deionized water as the feed solution, respectively, at the blended fertilizer solution of 600 g/L $H_2O$, the PR obtained were 5.39 and 6.50, respectively. And as the concentration of blended fertilizer solution increased, the reverse solute flux for nitrogen (N), phosphorus (P), and potassium (K) increased nearly linearly, but specific reverse solute flux for them was reduced. The reverse solute flux and specific reverse solute flux became higher in the order of N > K > P.

Impedance Change of Aluminum Pad Coated with Epoxy Molding Compound for Semiconductor Encapsulant (반도체 패키지 봉지재용 에폭시 수지 조성물이 코팅된 알루미늄 패드의 임피던스 변화)

  • 이상훈;서광석;윤호규
    • Journal of the Microelectronics and Packaging Society
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    • v.7 no.3
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    • pp.37-44
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    • 2000
  • The corrosion behavior of aluminum pad coated with epoxy molding compound (EMC) was investigated using electrochemical impedance spectroscopy (EIS). The impedance change was evaluated by the absorption of deionized water (DI water) to EMC coating and the interface between EMC and aluminum. During the absorption a decrease in resistance and thus an increase in capacitance of EMC as well as the interface of EMC/Al could be observed. Up to about 170 hours of absorption the EMC was saturated with the water molecules and ions generated from EMC. Subsequently the ionic water was penetrated to the interface and finally the corrosion of aluminum was occurred by the Dl water and ions. From measuring the adhesion strength with the Dl water absorption it was expected that the saturation of water and ions in the interface decreased the adhesion strength. The higher filler content of EMC should be necessary to inhibit the corrosion of aluminum electrode in microelectronic packages.

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Development of Polymeric Human Jelly Phantom for Hyper-Thermic Therapy by High Frequency Magnetic Field (고주파 자기장을 이용한 온열요법 치료용의 젤리형 고분자 모의인체)

  • Choi, Chang-Young;Kim, Byung-Hun;Hwang, Young-Jun;Kim, Oh-Young
    • Polymer(Korea)
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    • v.32 no.1
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    • pp.90-93
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    • 2008
  • We developed a variety of polymeric jelly phantoms that can be used in hyperthermia using an electromagnetic wave as an auxiliary cancer therapy. Particularly, using an appropriate material composed of polyethylene, deionized water, and sodium chloride, jelly phantoms for brain was prepared. Also, their electrical properties were characterized by measuring the dielectric constant and conductivity. As the results, overall electrical values of the phantoms decreased with increasing the amount of the components of the materials, excepted for sodium chloride. Additionally, storage characteristics of the phantoms showed a sustainable stability up to 6 months. Based on the experimental results, it can be proposed that jelly phantoms containing a ferro-magnetic particle could be a potential material for cancer therapy following the further study on the temperature elevation effect and the evaluation of electromagnetic properties of the materials.