• Composites Research
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• v.35 no.2
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• pp.93-97
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• 2022

The application of infrared heating in the hot press forming of the thermoplastic composites is conducive to productivity with high-speed heating. However, high energy, high forming temperature, and high-speed heating derived from infrared heating can cause material degradation and deteriorate properties such as re-melting performance. Therefore, this study was conducted to optimize the process conditions of the hot press forming suitable for carbon fiber reinforced polyetherketoneketone(CF/PEKK) composites that are actively researched and developed as high-performance aviation materials. Specifically, the degradation mechanisms and properties that may occur in infrared high-speed heating were evaluated through morphological and thermal characteristics analysis and mechanical performance tests. The degradation mechanism was analyzed through morphological investigation of the crystal structure of PEKK. As a result, the size of the spherulite decreased as the degradation progressed, and finally, the spherulite disappeared. In thermal characteristics, the melting temperature, crystallization temperature and heat of crystallization tend to decrease as degradation progresses, and the crystal structure disappeared under long-term exposure at 460℃. In addition, the low bonding strength was observed on the degraded surface, and the bonding surfaces of PEKK did not melt intermittently. In conclusion, it was confirmed that the CF/PEKK composite material degraded at 420℃ in the infrared high-speed heating. Furthermore, the spherulite experienced morphological changes and the re-melting properties of thermoplastic materials were degraded.

• Composites Research
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• v.34 no.5
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• pp.290-295
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• 2021

The application of lightweight structural composites to automobiles as a solution in line with global fuel economy regulations to curb global warming is recognized as a megatrend. This study was conducted to provide a technical approach that can respond to the issue of replacing parts that require conductive properties to maximize the application of thermoplastic carbon fiber reinforced plastics (CFRPs), which are advantageous in terms of repair, disposal and recycling. By utilizing the properties of the low-viscosity polymerizable oligomer matrix, it was possible to prepare a thermoplastic CFRP exhibiting excellent impregnation properties while uniformly mixing the conductive filler. Various carbon-based conductive fillers such as carbon black, carbon nanotubes, graphene nanoplatelets, graphite, and pitch-based carbon fibers were filled up to the maximum content, and electrical and thermal conductive properties of the fabricated composites were compared and studied. It was confirmed that the maximum incorporation of filler was the most important factor to control the conductive properties of the composites rather than the type or shape of the conductive carbon filler. Experimental results were observed in which it might be advantageous to apply a one-dimensional conductive carbon filler to improve electrical conductivity, whereas it might be advantageous to apply a two-dimensional conductive carbon filler to improve thermal conductivity. The results of this study can provide potential insight into the optimization of structural design for controlling the conductive properties of thermoplastic CFRPs.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2004.10a
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• pp.189-192
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• 2004

In this study, mode II interlaminar fracture phenomena of carbon fabric/epoxy composite for tilting train were investigated. The end notched flexural specimen containing an artificial crack with the thickness of 12.5fl11l was used. The mode II interlaminar fracture toughness was evaluated through a three point bending test and the fractured surfaces were examined through a scanning electron microscope. The experimental results obtained in this study would be applicable in the design and structural analysis of the composite structures.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.03a
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• pp.228-228
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• 2003

고강성 탄소섬유는 높은 비강도 및 고 강성 특성 때문에 탄소-탄소 복합재료의 가장 우수한 강화재로 각광을 받고 있다. 이 섬유는 미세 결정립의 높은 이방성을 나타내며, 이러한 높은 흑연화 특성은 기계적, 전기적, 전기적 그리고 화학적 특성 등을 좋게한다. 이러한 모든 방면에서의 우수한 특성 때문에 항공우주 재료분야에 의심 없이 가장 우수한 재료로 고려되고 있다. 이렇게 가벼우면서 고온강도가 요구되는 재료로써 탄소재료가 이용되면서 rocket의 nozzle이나 nosecone으로의 응용에는 고온 산화가 중요한 연구주제로 대두되어 왔다. 탄소재료의 산화반응은 결정구조 인자 및 그 배열에 가장 큰 영향을 받는다고 알려져 있는데, 출발원료 및 제조 조건에 따라 그 구조 및 배열이 현격하게 달라진다. 탄소재료의 구조 해석은 주로 TEM과 XRD를 이용해 왔다. 많은 연구자들은 오래 전부터 탄소재료 연구에 TEM에서 얻은 상이 불확실하고 문제가 있다고 보고하였고, 최근 TEM 장치의 발달과 더불어 실제 구조를 얻기가 가능함을 보여주고 있다 그러나 TEM 시편은 여전히 작고 시편으로부터 얻는 정보는 불과 nm 수준이다. 따라서 일반적으로 TEM으로 얻은 정량적인 정보는 불과 특정한 점에서의 정보이기 때문에 여전히 논란의 소지가 많다. XRD는 탄소재료의 미세구조 해석을 위하여 가장 널리 이용되는 분석기기이다.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2006.11a
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• pp.223-225
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• 2006

In this study, the graphite/epoxy prepregs were surface-treated using oxygen plasma, and optimal treatment time was determined measuring the contact angle en the prepreg surface. Interlaminar fracture behavior of surface-treated graphite/epoxy composite was compared with that of regular (untreated) graphite/epoxy composites. The results showed that the contact angle was a minimum when treated for 30 minutes. The interlaminar fracture toughness of surface-treated specimen was improved about 15% compared with that of regular specimen.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.42 no.8
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• pp.629-639
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• 2014

This paper deals with an alternative multi-functional structures by using grid-stiffened composite structure with excellent bending stiffness and lightweight characteristics which is capable of easy embedding of electrical/electronic circuitry into structure. The enhancement of thermal conduction capability is made by the application of pitch-based carbon fiber. The lightweight radiation spot shielding technique is also proposed for multi-functional structures without conventional housing and the effectiveness of selective radiation shielding is validated through the proton irradiation test.

• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.4
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• pp.149-157
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• 2002

This paper is to investigate collapse mechanisms of CFRP(Carbon Fiber Reinforced Plastics)composite tubes and to evaluate collapse characteristics on the change of interlaiminar number and ply orientation angle of outer under static and impact axial compression loads. When a CFRP composite tube is crushed, static/impact energy is consumed by friction between the loading plate and the splayed fronds of the tube, by fracture of the fibers, matrix and their interface. These are associated with the energy absorption capability. In general, CFRP tube with 6 interlaminar number(C-type), absorbed more energy than other tubes(A, B, D-types). The maximum collapse load seemed to increase as the interlaminar number of such tubes increases. The collapse mode depended upon orientation angle of outer of CFRP tubes and loading status(static/impact). Typical collapse modes of CFRP tubes are wedge collapse mode, splaying collapse mode and fragmentation collapse mode. The wedge collapse mode was shown in case of CFRP tubes with 0° orientation angle of outer under static and impact loadings. The splaying collapse mode was shown in only case of CFRP tubes with 90°orientation angle of outer under static loadings, however in Impact tests those were collapsed in fragmentation mode .

• Transactions of the Korean Society of Automotive Engineers
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• v.25 no.1
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• pp.1-10
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• 2017

In reverse engineering, one of the main tasks is reconstructing the mechanical properties of used materials. For an isotropic material, it could be defined by a single tensile test using a coupon extracted from the structure. In contrast, CFRP composites require many tests and complex procedures to define all the material properties because CFRP is an orthotropic material and a stacked laminate. In this paper, the procedure to reconstruct composite material properties is studied by using the classical lamination theory and the test data of three different laminates from a composite structure. A sample reconstruction of composite material properties using a composite car body is introduced to verify the method.

• Transactions of the Korean Society of Automotive Engineers
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• v.25 no.3
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• pp.350-359
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• 2017

This paper presents a new holistic development approach for the carbon continuous-fiber composite frame of an automotive sunroof assembly. The original steel frame has been designed to get higher bending stiffness with its corrugated cross-sectional shape. The new approach uses the prepregs of a fast cure epoxy and PCM manufacturing processing. For higher productivity, the new frames feature a very simple plat cross sectional shape but achieve high bending stiffness through the laminate design. The sandwich structure with a PET foam core was presented. The frames were made of carbon UD laminae covered single carbon fabric on the outer surfaces. The fabrics provide torsional stiffness and also hold the carbon UD fibers floating in the low viscous epoxy resin of prepregs at the curing temperature during processing. The final product yields approximately 18 % savings in weight compared with the original.

• Journal of the Korean Society for Precision Engineering
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• v.22 no.11 s.176
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• pp.99-103
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• 2005

It is generally accepted that fracture toughness of fiber-reinforced polymer composites is affected by strain rate in an atmospheric pressure condition. For a present study, the strain rate effect on the fracture toughness of fiber-reinforced laminated composites in the hydrostatic pressure condition was investigated. For this purpose, fracture tests have been conducted using graphite/epoxy laminated composites applying three steps of the strain rate at 270 MPa hydrostatic pressure condition. The strain rates applied were $0.05\%/sec,\;0.25\%/sec$, and $0.55\%/sec$. Fracture toughness was determined from the work factor approach as a function of applied strain rate. The result showed that fracture toughness decreased as the strain rate increased. Specifically, the fracture toughness decreased $12\%$ as the strain rate increased from $0.05\%/sec$ to $0.55\%/sec$.