• Title/Summary/Keyword: 탄소동위원소분석

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Geochemical characteristics of a LILW repository I. Groundwater (중.저준위 방사성 폐기물 처분부지의 지구화학 특성 I. 지하수)

  • Choi, Byoung-Young;Kim, Geon-Young;Koh, Yong-Kwon;Shin, Seon-Ho;Yoo, Si-Won;Kim, Doo-Haeng
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.6 no.4
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    • pp.297-306
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    • 2008
  • This study was carried out to identify the characteristics of hydrochemistry controlling groundwater chemical condition in a repository site of Gyeongju. For this study, 12 bore holes of all monitoring bore holes in the study area were selected and total 46 groundwater samples were collected with depth. In addition, 3 surfacewater samples and 1 seawater sample were collected. For water samples, cations and anions were analyzed. The environmental isotopes(${\delta}^{18}O-{\delta}D$, Tritium, ${\delta}^{13}C,\;{\cdot}{\delta}^{34}S$) were also analyzed to trace the origin of water and solutes. The result of ${\delta}^{18}O\;and\;{\delta}D$ analysis showed that surface water and groundwater were originated from precipitation. Tritium concentrations of groundwater decreased with depth but high concentrations of tritium indicated that groundwater was recharged recently. The results of ion and correlation analysis showed that groundwater types of the study area were represented by Ca-Na-$HCO_3$ and Na-Cl-$SO_4$, which was caused by sea spray and water-rock interaction. Especially, high ratio of Na content in groundwater resulted from ion exchange. For redox condition of groundwater, the values of DO and Eh decreased with depth, which indicated that reducing condition was formed in deeper groundwater. In addtion, high concentration of Fe and Mn showed that redox condition of groundwater was controlled by the reduction of Fe and Mn oxides.

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Food Habits of the Glass eel Anguilla japonica in the West Coast Estuaries of Korean Peninsula Determined by Using C and N Stable Isotopes (안정동위원소를 이용한 서해연안 실뱀장어의 먹이 습성)

  • Kim, Jeong Bae;Lee, Won-Chan;Kim, Dae-Jung;Seong, Ki Baik;Choi, Hee-Gu;Choi, Woo-Jeung;Hwang, Hak Bin;Hong, Sokjin;Kim, Hyung Chul;Park, Sung-Eun;Shim, Jeong Hee;Kang, Chang-Keun
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.18 no.4
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    • pp.206-213
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    • 2013
  • Glass eels (Anguilla japonica) are caught in the west coast of Korea on their migratory route from the breeding grounds in the Mariana Trench along the North Equatorial Current and the Kuroshio Current. To identify the food source of natural glass eels, we analyzed the stable C and N isotopes of glass eels caught in April 2012 and investigated possible food sources in the survey area. In particular, with respect to the stable C and N isotopes of particulate organic matter, we extended the surveying area to the northern parts of East China Sea as well as the west coast of Korea. The stable C and N isotope ratios of the glass eels caught in the west coast were found to be $-20.7{\pm}0.1$‰ and $5.0{\pm}0.2$‰, respectively. The stable C and N isotope ratios of the particulate organic matter in the west coast of Korea, in which the glass eels are assumed to eat the particulate organic matter as food source, were estimated to be $-24.0{\pm}0.3$‰ and $2.8{\pm}0.4$‰, respectively. Similar data were obtained from the northern part of the East China Sea, $-24.5{\pm}0.5$‰ and $0.8{\pm}0.3$‰. The stable isotope ratios showed values differing from the stepwise increasing rates up the food web in natural aquatic ecosystem, showing that particulate organic matter in the west coast of Korea and East China Sea was not served as the glass eels food source. This result suggested that the glass eels caught in the west coast might not assimilate nutrition from the marine environment during long migration.

A Study on the Holocene Environments of the Jemin Plain in Gongju, Chungnam Province (충남 공주 제민평야의 홀로세 환경연구)

  • PARK, Ji Hoon;LEE, Ae-Jin
    • Journal of The Geomorphological Association of Korea
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    • v.24 no.2
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    • pp.65-78
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    • 2017
  • In this study, stable carbon isotopic analysis (22 specimens) and magnetic susceptibility analysis (23 specimens) were conducted out on the specimens collected from two points (trench DT1, DT2) in the floodplain of Jemincheon(hereinafter the Jemin plain) to reconstruct the Holocene Environments (Period I, Period II, Period III) of the Jemin plain in Gongju, Chungnam. The results were as follows: In Period I (approximately 7,480~4,940 yrs B.P.) and especially around 7,480~7,320 yrs B.P., it was cool-dry and there were two minor climate fluctuations. This period received a continuous flow of sediments, rather than massive amounts of sediments due to abrupt flooding, and therefore, there was almost no soilization process. Period II(approximately 4,940~2,600 yrs B.P.) was also relatively cool-dry. However, in Period II b, unlike I, the minor climate fluctuations were less pronounced. In this period, flooding and desiccation repeated, inducing soilization processes especially around 3,160 yrs B.P. In Stage III (~360 yrs B.P.), it was warm and humid compared to II b. However, in III a, there was no inflow of sediments due to irregular flooding, and in fact, soilization process was more manifested than during II b due to the impact of the desiccation environment. However, there were some mass movements from Bonghwang Mt. (a.s.l. 147m) caused by heavy rains and typhoon during III b (approximately 360 yrs B.P.), thus moving a large amount of debris (i.e. gravel), which resulted in sedimentation.

Stratigraphical and Sedimentological Studies on Core Sediments from the Southwestern Ulleung Basin, East Sea (울릉분지 남서부 해역의 천부퇴적물에 대한 층서$\cdot$퇴적학적 연구)

  • 박명호;류병재;김일수;정태진;이영주;유강민
    • Economic and Environmental Geology
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    • v.35 no.2
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    • pp.171-177
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    • 2002
  • Two piston-core sediments, obtained from the southwestern margin of the Ulleung Basin in East Sea, are analyzed to investigate the stratigraphy and sedimentary environment of the Late Quaternary. The cores consist mainly of cuddy sediments with silty sands, lapilli tephra and ash layers. The chronostratigraphic correlation with known eruption ages reveals that the core sediments contain the stratigraphic document over the past 46.1 kyr and the sedimentation rates during the last glacial period were relatively higher (12.1-14.9 cm/kyr) than those in pelagic ocean. Several sedimentary facies, mainly affected by turbidity currents, are commonly present in the core interval accumulated during the oxygen-isotope stage 2. Many of horizontal voids, which are thought to have formed by gas expansion, are observed in fore 00GHP-07. The total organic carbon (TOC) contents of the core sediments are noticeably high (average 1 .8%). Particularly, these TOC valuers increased during Termination I, suggesting that dering this time interval the sedimentary environment of the study area was changed to more anoxic.

Hydro-Biogeochemical Approaches to Understanding of Water and Carbon Cycling in the Gwangneung Forest Catchment (수문생지화학적 접근을 통한 광릉 산림 유역의 물과 탄소 순환 이해)

  • Kim, Su-Jin;Lee, Dong-Ho;Kim, Joon;Kim, Sung
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.9 no.2
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    • pp.109-120
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    • 2007
  • The information on flowpath, storage, residence time, and interactions of water and carbon transport in a catchment is the prerequisite to the understanding and predicting of water and carbon cycling in the mountainous landscapes of Korea. In this paper, along with some up-to-date results, we present the principal methods that are currently used in HydroKorea and CarboKorea research to obtain such information. Various catchment hydrological processes have been examined on the basis of the water table fluctuations, the end-member mixing model, the cross correlation analysis, and cosmogenic radioactive isotope activity. In the Gwangneung catchment, the contribution of surface discharge was relatively large, and the changes in the amount, intensity and patterns of precipitation affected both the flowpath and the mean residence time of water. Particularly during the summer monsoon, changes in precipitation patterns and hydrological processes in the catchment influenced the carbon cycle such that the persistent precipitation increased the discharge of dissolved organic carbon (DOC) concentrated in the surface soil layer. The improved understanding of the hydrological processes presented in this report will enable a more realistic assessment of the effects of climate changes on the water resource management and on the carbon cycling in forest catchments.

Determination of Honey Quality by Near Infrared Spectroscopy (근적외선 분광분석법을 이용한 벌꿀의 품질평가)

  • Cho, Hyeon-Jong;Ha, Yeong-Lae
    • Korean Journal of Food Science and Technology
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    • v.34 no.3
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    • pp.356-360
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    • 2002
  • The honey samples harvested in 1996, 1997, and 1998 were used for calibration and validation. NIR spectra were obtained using NIR spectrometer and quartz glass device with gold coating diffuser. Multiple linear regression and partial least square were used for calibrations. The correlation coefficient (RSQ) and standard error of prediction (SEP) obtained for moisture were 0.997 and 0.1%, respectively. The RSQ and SEP for fructose and glucose were 0.926 and 0.951%, and the SEP were 0.54% and 0.52% respectively. The validation results for sucrose, maltose, HMF definition, and acidity of honey were considered to be sufficient for practical use RSQ and SEP for SCIR were 0.950 and $1.08%_{\circ}$, respectively. These results are indications of the rapid determination of purity of the honey through NIR analysis.

The Characteristics of Fish Community and Food Web in Eutrophic Agricultural Reservoir, Jeondae (부영양 농업용저수지인 전대지의 어류군집 및 먹이망 특성)

  • Lee, Eui-Haeng;Chang, Kwang-Hyeon;Seo, Dong-Il;Choi, Jong-Yun;Joo, Gea-Jae;Kim, Mirinae;Shin, Jae Hoon;Son, Misun;Nam, Gui Sook
    • Korean Journal of Environmental Biology
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    • v.32 no.4
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    • pp.319-326
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    • 2014
  • Fish community was investigated in eutrophic Jeondae agricultural reservoir from April to November 2012. The food web structure of major fish species of Jeondae reservoir showed that due to serious organic pollution, the hyper-eutrophic condition with high chemical oxygen demand (COD), chlorophyll-a (Chl-a), total nitrogen (TN) and total phosphorus (TP), as estimated by stable isotope analysis. Total of 679 individuals were collected from the reservoir, and 9 species were identified. Interestingly, Lepomis macrochirus and Hemiculter eigenmanni known as less sensitive to pollution and water quality deterioration, dominated the reservoir, and their relative abundances were 38% and 27%, respectively. Further, the analysis of the stomach contents revealed that main food source of dominant L. macrochirus was high amount of zooplankton, which includes copepoda and cladocera, while Cyprinidae species mainly consumed organic particles with zooplankton preys. Stable isotope analysis also suggested that L. macrochirus, Carassiusauratus, Pseudorasboraparva, and H. eigenmanni are major zooplantivorous group in the Jeondae Reservoir.

Monitoring of Groundwater quality according to groundwater use for agriculture (농업용 지하수 사용에 따른 지하수질 모니터링 평가)

  • Ha, Kyoochul;Ko, Kyung-Seok;Lee, Eunhee;Kim, Sunghyun;Park, Changhui;Kim, Gyoo-Bum
    • Proceedings of the Korea Water Resources Association Conference
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    • 2020.06a
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    • pp.30-30
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    • 2020
  • 본 연구에서는 여름철에 농업용수(벼농사용)로서 집중적으로 지하수를 사용하는 지역에서 시기별 지하수 사용에 따른 지하수 수질변화를 평가하기 위해 수행되었다. 연구지역은 충남 홍성군 양곡리와 신곡리 일부를 포함하는 면적 2.83 ㎢(283.3 ha)에 해당하는 지역이다. 연구지역 지하수 수질의 공간적 분포 및 시간적 변화 특성 평가를 위하여 2019년 2회(7월, 10월)에 걸쳐 지하수 관정(21개소)에 대하여 조사 및 분석을 수행하였다. 지하수 샘플은 현장에서 온도(T), pH, 용존산소(DO) 및 전기전도도(EC), 산화환원전위(Eh) 등을 측정하였고, 실험실에서 주요 양이온 및 미량원소(Ca, Mg, Na, K, Si, Sr), 음이온(F, Cl, Br, NO2, NO3, PO4, SO4), 알칼리도, 용존 유기탄소(DOC)와 용존 유기물(DOM) 등을 분석하였다. 지하수 수질조사 결과, 전체의 14~15개소(67~71%)가 Ca-HCO3 유형으로 분류되었으며, 다음으로는 Ca-Cl 유형이 4~5개소(19~24%)가 관찰되었다. 얕은 심도의 관정에서 상대적으로 심도가 깊은 관정보다 대부분 성분(TDS, Ca, Mg, Na, K, Cl, SO4, HCO3, DOC)에서 높은 농도를 나타내었다. 지하수의 수질자료를 이용하여 다변량통계분석법인 주성분분석(PCA: Principal Components Analysis)과 계층적 군집분석(HCA: Hierachical Cluster Anlaysis)를 수행한 결과, 초기 3개 주요 고유성분(eigenvalue)는 PC1 54.0%, PC2 14.2%, PC3 12.3%로 전체 분산의 88.3%를 설명할 수 있었다. PC1은 Ca, Mg, Na, K, Cl, SO4, DOC가 주요한 영향 인자였으며 PC2는 HCO3, NO3, DO에 영향 받음을 확인하였다. 계층적 군집분석 결과, 연구지역 지하수는 Na-Cl 유형의 C-3 관정을 제외하고는 크게 두 그룹으로 구분되어 졌다. 다변량통계분석의 결과에서도 수리지화학, 동위원소, 용존유기물 등의 특성에서 나타나는 것과 유사한 연구지역의 수질특성을 확인할 수 있었다. 연구지역은 차시기 동안 수질변화는 일부 관정을 제외하고는 유의할 만한 수준으로 관찰되지는 않았고, 지하수 사용에 따른 지하수위 회복도 빠르게 진행되고 있는 것으로 나타났다.

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Application of Stable Isotopic Niche Space to Large River Monitoring: Analysis of Benthic Macroinvertebrates of the Seongchon Wier (안정동위원소비를 활용한 생태지위면적 분석의 수생태계 평가 가능성 분석: 영산강 승촌보의 저서성 대형무척추동물을 대상으로)

  • Seo, Dong-Hwan;Oh, Hye-Ji;Jin, Mei-Yan;Oda, Yusuke;Kim, Hyun-Woo;Jang, Min-Ho;Choi, Bohyung;Shin, Kyung-Hoon;Lee, Kyung-Lak;Lee, Su-Woong;Chang, Kwang-Hyeon
    • Journal of Environmental Impact Assessment
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    • v.27 no.6
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    • pp.685-694
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    • 2018
  • We measured ecological niche space (ENS) using carbon and nitrogen stable isotope ratios of benthic macroinvertebrates to estimate its applicability for large river assessment. In particular, we compared ENSs of selected macroinvertebrates between upper and lower area of Seungchon Weir in Yeongsan River to estimate the impact of weir on biological community. We also measured basic water quality and community indices including benthic macroinvertebrates index (BMI) to estimate their correlations with calculated ENS. ENS was calculated using the Bayesian Stable Isotope in R statistics (package "SIBER"). The results showed that seasonal variations in water quality and community indices were found, but there was no apparent tendency between upper and lower area of the Seungchon Weir in June (before rainy season) and August (after rainy season). However, ENS of benthic macroinvertebrates markedly decreased across the weir in both June and August regardless of changes in water quality. This means the physical change of the stream due to the weir cause decrease of ecological isotopic niche space of benthic macroinvertebrates regardless of water quality, suggesting physical modification by the weir can affect the interaction between habitat condition and macroinvertebrates. Therefore, the ecological isotopic niche space can be a useful supplementary indicator for the river ecosystem assessment.

Rapid bacterial identification using Raman spectroscopy (라만 분광법을 활용한 세균 검측 기술)

  • No, Jee Hyun;Lee, Tae Kwon
    • Korean Journal of Microbiology
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    • v.53 no.2
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    • pp.71-78
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    • 2017
  • Raman microspectroscopy is a promising tool for microbial analysis at single cell level since it can rapidly measure the cell materials including lipids, nucleic acids, and proteins by measuring the inelastic scattering of a molecule irradiated by monochromatic lights. Using Raman spectra provides high specificity and sensitivity in classification of bacteria at the strain level. In addition, a Raman approach coupled with stabled isotope such as $^{13}C$ and $^2H$ is able to detect and quantify general metabolic activity at single cell level. After bacterial detection process by Raman microspectroscopy, interested unculturable cell sorting and single cell genomics can be accomplished by combination with optical tweezer and microfluidic devices. In this review, the characteristics and applications of Raman microspectroscopy were reviewed and summarized in order to provide a better understanding of microbial analysis using Raman spectroscopy.