• Title/Summary/Keyword: 클로로페놀

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Effect of Some Nutrients on the Population of Pentachlorphenol-degrading Bacteria in Soil Suspension (토양현탁액(土壤懸濁液)에 영양원(營養源)의 첨가(添加)가 Pentachlorophenol 분해세균(分解細菌)의 밀도변화(密度變化)에 미치는 영향(影響))

  • Lee, Sang-Bok;Choi, Yoon-Hee;Sato, Kyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.27 no.4
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    • pp.309-314
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    • 1994
  • Population changes of serveral bacterial groups and chemical changes of nutrients applied were compared between soils suspensed with pentachlorophenol(PCP) and amended with different nutrients. The number of total bacteria and Gram-negative bacteria were dramatically increased for 1st week, after remained at its maximum level for a short time, decreased gradually in all treatments for 5th week, the rate of decrease were faster at addition of only PCP than at addition of nutrients and PCP. While, the addition of nutrients in the soil suspension containing PCP suppressed the number of PCP-degrading bacteria. The dissipation of PCP were faster at single addition of PCP than at the combined addition of nutrients with PCP. The nutrients added with PCP were rapidly degraded for 1st week, among the nutrients the rate of degration of glucose was faster than that of glutamic acid or glycine. pH values in the suspension showed which addition of nutrients with PCP caused its changes in comparsion with addition of only PCP where changes was slightly.

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The Protective Effects of an Ethyl Acetate Fraction of Raphiolepsis indica Against Oxidative Stress in HaCaT Keratinocytes (HaCaT 피부 각질세포의 산화적 스트레스에 대한 다정큼나무 에틸 아세테이트 분획물의 세포 보호 효과)

  • Yang, Eun Ju;Kim, Hye-Ran;Chang, Kyung-Soo;Chang, Jeong Hyun
    • Journal of Life Science
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    • v.30 no.8
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    • pp.688-694
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    • 2020
  • In a previous study, the total phenolic content in ethanol extracts of medicinal plants that naturally grow on Jeju Island were analyzed with the extracts of Raphiolepsis indica leaf found to have the highest. The current study was carried out to evaluate the total flavonoid content, radical-scavenging activity, and the protective effect of R. indica extracts and solvent fractions on oxidative stress in HaCaT keratinocytes. More specifically, total flavonoid content and 2-azino-bis 3-ethylbenzthiazoline-6-sulfonic acid (ABTS) radical-scavenging activity were measured to assess anti-oxidative activity, and protective effects against hydrogen peroxide (H2O2) were determined by 3-[4, 5-dimethylthiazol-2-yl]-2, 5-diphenyltetrazolium bromide assay on the HaCaT cells. Of the various fractions analyzed, the ethyl acetate extract of R. indica showed the highest total flavonoid content (149.13 mg/g extracts) and the lowest remaining ABTS. In addition, the ethyl acetate fraction was significantly more resistant against H2O2 than the negative control. Our results therefore suggest that an ethyl acetate fraction of R. indica protects HaCaT cells against oxidative stress and could prove useful for developing functional cosmetic materials.

A Study on the Formation of OH Radical by Metal-supported Catalyst in Ozone-catalytic Oxidation Process (오존촉매산화공정에서 금속 담지촉매에 의한 수산화라디칼 생성연구)

  • Lee, Sun Hee;Choi, Jae Won;Lee, Hak Sung
    • Applied Chemistry for Engineering
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    • v.29 no.4
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    • pp.432-439
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    • 2018
  • Metal catalysts such as Fe, Co, Mn, and Pd supported on the activated carbon (AC) were prepared to improve functional groups for the chemical adsorption and catalytic ozonation. Following ascending orders of the phenol decomposition rate, dissolved ozone decomposition ratio and TOC (total organic carbon) removal from experimental results of advanced oxidation process (AOP) were observed: Fe-AC < AC < Co-AC < Mn-AC < Pd-AC. BET analysis results showed that the physical properties of the metal impregnated activated carbon had no effect on the catalytic ozonation, and the catalytic effect was dependent on the kind of impregnated metal. The ratio of the formed concentration of OH radical to that of ozone (RCT) was measured by using the decomposition outcome of p-chlorobenzoic acid, a probe compound that reacts rapidly with OH radical but slowly with ozone. The measured values of RCT were $5.48{\times}10^{-9}$ and $1.47{\times}10^{-8}$ for the ozone alone and activated carbon processes, respectively, and $2.13{\times}10^{-9}$, $1.51{\times}10^{-8}$, $4.77{\times}10^{-8}$, and $5.58{\times}10^{-8}$ for Fe-AC, Co-AC, Mn-AC, and Pd-AC processes, respectively.

Determination of chlorophenols from the industrial wastewater by GC/MS (GC/MS를 이용한 산업폐수중의 염화페놀류 분석)

  • Myung, Seung-Woon
    • Analytical Science and Technology
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    • v.18 no.4
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    • pp.320-328
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    • 2005
  • The most common five chlorophenols (4-chloro-3-methylphenol, 2,4,5-trichlorophenol, 2,4,6-trichlorophenol, 2,3,4,6-tetrachlorophenol, pentachlorophenol) were determined from the industrial wastewater by GC/MS. The samples were collected from the petrochemical company, textile company and leather making company. The developed analytical method was modified by USEPA Method 3510. The samples were extracted with dichloromethane under pH 2 and pH 5-6, and determined by the GC/MS with SIM mode. There were good linearities (above $R^2=0.9943$) on e ranges of the 0.1 ng/mL~10 ng/mL and 0.5 ng/mL~10 ng/mL, and the limit of detection were between 0.1 ng/mL and 0.5 ng/mL. The absolute recoveries were measured at the concentration of 1, 5, and 10 ng/mL, and the recovery was 71.6~98.9% except for PCP. The relative standard deviation (RSD) was 1.2~14.3% and it gave a good reproducibility for the assay. The bias, which shows the accuracy, was a good although it was a little high values (11.3~22.1%) at the low concentration (1 ng/mL).

Studies on Antioxidant, Anti-inflammation and Tyrosinase Inhibitory Activities of Melissa officinalis Extracts and Their Fractions (레몬밤 추출물과 분획물의 항산화, 항염 및 티로시나제 저해활성 연구)

  • Jeong, Yong Un;Lee, Hwan;Park, Haney;Kim, Kyungmin;Kim, Suyeong;Park, Young Jin
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.44 no.4
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    • pp.465-475
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    • 2018
  • This study was carried out to evaluate the antioxidant, anti-inflammation, and tyrosinase inhibitory activity of Melissa officinalis extracts and their fractions. The total polyphenol contents of the extracts were 33.02-302.76 mg GAE/g and total flavonoid contents were 9.98-325.07 mg CE/g. In 1,1-diphenyl-2-picrylhydrazyl (DPPH) radical scavenging assay, DPPH radical scavenging activity was observed in the extracts and water fractions of M. officinalis and similar to that of ascorbic acid ($30{\mu}M$). In addition, the treatment of chloroform fraction significantly inhibited the production of nitric oxide (NO) in RAW 264.7 cells, indicating that they have anti-inflammatory activity. Tyrosinase inhibitory activity of $200{\mu}g/mL$ of 100% ethanol reflux extract showed better inhibitory activity than arbutin treatment at statistically significant level. As a result, it is considered that M. officinalis can be used as an effective cosmetic ingredient having antioxidant, anti-inflammation, and whitening activity.